US5230935A
Expired / Lapsed
US
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Multilayer composites coextruded with the use of impact-reinforced impervious resin compositions and their use for the manufacture of fuel storage vessels
Assignee: Solvay SA
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Filing: 1992-11-27
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Granted: 1993-07-27
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Expires: 2012-11-27
Abstract
Abstract Multilayer composites coextruded with the use of polyolefins and of impact-reinforced impervious resin compositions based on hydrolysed copolymers of vinyl acetate and ethylene comprising, as an additive improving the impact strength, elastomeric copolymers of ethylene and propylene which are modified by grafting an α,β-ethylenically unsaturated carboxylic acid and, preferably, by maleic anhydride. The coextruded multilayer composites are very particularly suitable for the manufacture of fuel storage vessels combining impact strength and high imperviousness to petrol and to petrol/alcohol mixtures.
Inventors
- 👤 Didier Delimoy
- 👤 Pierre De Longree
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 08:54
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/18; C; C08; C08L; C08L29/00; C08L29/02; C08L29/04; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379; Y10T428/1383; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31928
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
82 words
A coextruded multilayer composite, comprising: a layer of a polyolefin; a layer of an impact-reinforced impervious resin composition consisting essentially of a hydrolyzed copolymer of vinyl acetate and ethylene, and an elastomeric copolymer of ethylene and propylene which is modified by grafting an α,β-ethylenically unsaturated carboxylic acid as an additive in an amount effective for improving impact strength; and an intermediate layer of a polymeric adhesive bonding together the layer of a polyolefin and the layer of an impact-reinforced impervious resin composition.
Claim 2
Dependent Claim
82 words
A coextruded multilayer composite, comprising: a layer of a polyolefin; a layer of an impact-reinforced impervious resin composition consisting essentially of a hydrolyzed copolymer of vinyl acetate and ethylene, and an elastomeric copolymer of ethylene and propylene which is modified by grafting an α,β-ethylenically unsaturated carboxylic acid as an additive in an amount effective for improving impact strength; and an intermediate layer of a polymeric adhesive bonding together the layer of a polyolefin and the layer of an impact-reinforced impervious resin composition.
Claim 3
Dependent Claim
55 words
The coextruded multilayer composite according to claim 1 wherein the modified elastomeric copolymers of ethylene and propylene comprise form 40 to 95 mol % of ethylene-derived monomer units, form 60 to 5 mol % of propylene-derived monomer units and from 0.1 to 1.5% by weight of monomer units derived from an α,β-ethylenically unsaturated carboxylic acid.
Claim 4
Dependent Claim
55 words
The coextruded multilayer composite according to claim 1, wherein the modified elastomeric copolymers of ethylene and propylene comprise from 45 to 85 mol % of ethylene-derived monomer units, from 55 to 15 mol % of propylene-derived monomer units and from 0.6 to 1.2% by weight of monomer units derived from and α,β-ethylenically unsaturated carboxylic acid.
Claim 5
Dependent Claim
23 words
The coextruded multilayer composite according to claim 1, wherein the elastomeric copolymers of ethylene and propylene are modified by grafting with maleic anhydride.
Claim 6
Dependent Claim
28 words
The coextruded multilayer composite according to claim 1, wherein the impervious resin compositions comprise form 5 to 35% by weight of modified elastomeric copolymers of ethylene and propylene.
Claim 7
Dependent Claim
28 words
The coextruded multilayer composite according to claim 5, wherein the impervious resin compositions comprise from 15 to 25% by weight of modified elastomeric copolymers of ethylene and propylene.
Claim 8
Dependent Claim
39 words
The coextruded multilayer composite according to claim 1 wherein they comprise three layers consisting of an outer layer of high density polyethylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.
Claim 9
Dependent Claim
37 words
The coextruded multilayer composite according to claim 1, wherein they comprise three layers consisting of an outer layer of polypropylene, an intermediate layer of polymeric adhesive and an outer layer consisting of an impact-reinforced impervious resin composition.
Claim 10
Dependent Claim
36 words
The coextruded multilayer composite according to claim 1, wherein they comprise essentially two outer layers of high density polyethylene, an internal layer consisting of an impact-reinforced impervious resin composition and two intermediate layers of polymeric adhesive.
Claim 11
Dependent Claim
24 words
In a process of manufacturing a fuel storage vessel the improvement comprising manufacturing said vessel from a coextruded multilayer composite according to claim 9.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-07-26 | 1997-01-25 | 1997-07-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-07-26 | 2001-01-25 | 2001-07-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-07-26 | 2005-01-25 | 2005-07-27 | $7700.00 | Window Closed / Lapsed |