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US5212227A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic resin compositions

Assignee: NOF Corp
•
Filing: 1990-12-20
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Granted: 1993-05-18
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Expires: 2010-12-20
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Abstract

Abstract There is provided a thermoplastic resin composition which comprises 99 to 1% by weight of a propylene polymer (I), 1 to 99% by weight of a vinyl polymer (II), 0.1 to 100 parts by weight, based on 100 parts by weight of the aforesaid resins (I)+(II), of a multi-phase structure thermoplastic resin (III) which is a graft copolymer comprising 5 to 95% by weight of a propylene polymer and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one kind of vinyl monomer, either of the components being formed with a dispersion phase having a particle diameter of 0.001 to 10 μm.

Inventors

  • 👤 Suehiro Sakazume
  • 👤 Yuichi Orikasa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 11:37
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L51/00; C08L51/06; C08K; C08K7/00; C08K7/02; C08K7/04; C08K7/14; C08L2201/00; C08L2201/06; C08L2205/00; C08L2205/03; C08L2205/08; C08L23/16; C08L25/00; C08L25/02; C08L25/04; C08L51/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 272 words
A thermoplastic resin composition which comprises (I) 90 to 50% by weight of a propylene polymer other than (III), and (II) 10 to 50% by weight of polystyrene other than (III), and (III) 5 to 20 parts by weight, based on 100 parts by weight of the aforesaid resins (I)+(II), of a preformed compatibility agent which is a multiphase structure thermoplastic resin which is a graft copolymer comprising 20 to 90% by weight of a propylene polymer and 80 to 10% by weight of polystyrene or copolymer of styrene and acrylonitrile, one of the components being formed as a dispersion phase having a particle diameter of 0.001 to 10 μm, said graft copolymer being obtained by melting and kneading a graft polymerization precursor (A) which is prepared by copolymerizing styrene or styrene and acrylonitrile with at least one of radical polymerizable peroxides having the formulae (a) or (b) ##STR4## wherein R 1 is a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, each of R 2 and R 7 is a hydrogen atom or a methyl group, R 6 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, each of R 3 , R 4 , R 8 and R 9 is an alkyl group having 1 to 4 carbon atoms, each of R 5 and R 10 is an alkyl group having 1 to 12 carbon atoms, a phenyl group, an alkyl-substituted phenyl group or a cycloalkyl group having 3 to 12 carbon atoms, m is 1 or 2, and n is 0, 1 or 2, in particles of a propylene polymer.
Claim 2
Dependent Claim 272 words
A thermoplastic resin composition which comprises (I) 90 to 50% by weight of a propylene polymer other than (III), and (II) 10 to 50% by weight of polystyrene other than (III), and (III) 5 to 20 parts by weight, based on 100 parts by weight of the aforesaid resins (I)+(II), of a preformed compatibility agent which is a multiphase structure thermoplastic resin which is a graft copolymer comprising 20 to 90% by weight of a propylene polymer and 80 to 10% by weight of polystyrene or copolymer of styrene and acrylonitrile, one of the components being formed as a dispersion phase having a particle diameter of 0.001 to 10 μm, said graft copolymer being obtained by melting and kneading a graft polymerization precursor (A) which is prepared by copolymerizing styrene or styrene and acrylonitrile with at least one of radical polymerizable peroxides having the formulae (a) or (b) ##STR4## wherein R 1 is a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, each of R 2 and R 7 is a hydrogen atom or a methyl group, R 6 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, each of R 3 , R 4 , R 8 and R 9 is an alkyl group having 1 to 4 carbon atoms, each of R 5 and R 10 is an alkyl group having 1 to 12 carbon atoms, a phenyl group, an alkyl-substituted phenyl group or a cycloalkyl group having 3 to 12 carbon atoms, m is 1 or 2, and n is 0, 1 or 2, in particles of a propylene polymer.
Claim 3
Dependent Claim 33 words
A thermoplastic resin composition according to claim 1 wherein the polystyrene or copolymer of styrene and acrylonitrile in the multiphase structure thermoplastic resin (III) has an average polymerization degree of 5 to 10,000.
Claim 4
Dependent Claim 26 words
A thermoplastic resin composition according to claim 1 wherein the propylene polymer is a crystalline polymer or copolymer composed of over 75% by weight of propylene.
Claim 5
Dependent Claim 38 words
A thermoplastic resin composition according to claim 1 in which a thermoplastic elastomer (IV) is blended in an amount of from 1 to 100 parts by weight based on 100 parts by weight of the resin composition (I)+(II)+(III).
Claim 6
Dependent Claim 37 words
A thermoplastic resin composition according to claim 1 in which an inorganic filler is blended in an amount of from 1 to 150 parts by weight based on 100 parts by weight of the resin composition (I)+(II)+(III).
Claim 7
Dependent Claim 18 words
A thermoplastic resin composition according to claim 1 in which the propylene polymer in resin (III) is polypropylene.
Claim 8
Dependent Claim 16 words
A thermoplastic resin composition according to claim 6 in which the propylene polymer (I) is polypropylene.

References Cited (Backward Citations)

US4665131A Cited
US4879347A Cited
US4923956A Cited
US4839423A Cited
US4910254A Cited
US4889888A Cited
US4957974A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-17 1996-11-16 1997-05-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-17 2000-11-16 2001-05-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-17 2004-11-16 2005-05-18 $7700.00 Window Closed / Lapsed

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