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Use of water-soluble or water-dispersible grafted proteins as detergent additives

Assignee: BASF SE
•
Filing: 1991-05-10
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Granted: 1993-05-04
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Expires: 2011-05-10
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Abstract

Abstract Phosphate-free and low-phosphate detergents which contain surfactants as essential constituents also contain from 0.1 to 20% by weight, based on the particular formulation, of water-soluble or water-dispersible grafted proteins obtainable by free radical copolymerization of (A) monoethylenically unsaturated monomers in the presence of (B) proteins in a weight ratio of (A):(B) of (0.5-90):(99.5-10).

Inventors

  • 👤 Matthias Kroner
  • 👤 Heinrich Hartmann
  • 👤 Richard Baur
  • 👤 Wolfgang Trieselt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:02
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3788; C08; C08F; C08F289/00; C11D3/0005; C11D3/0036

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 146 words
A phosphate-free or low-phosphate detergent comprising: a) a surfactant; and b) 0.1-20% by weight based on the formulation, of a water-soluble or water-dispersible grafted protein obtained by free radical copolymerization of (A) monoethylenically unsaturated monomers selected from the group consisting of esters of a monoethylenically unsaturated C 3-8 carboxylic acids with monohydric or polyhydric C 1-22 alcohols, esters of a monoethylenically unsaturated C 3-8 carboxylic acids with the addition products of 1-50 mol of alkylene oxide with 1 mol of a C 1-22 alcohol, amides of C 3-8 carboxylic acids which are derived from ammonia, C 1-22 alkylamines or C 1-22 dialkylamines, nitriles of carboxylic acids, vinyl ethers of C 1-8 alcohols, vinyl esters of saturated C 1-22 carboxylic acids, N-vinylamides, vinylpyridines, acrylamidopropanesulfonic acid, acrylamidoethanesulfonic acid, N,N-dialkylamino-C 2-4 -alkyl(meth)acrylamides, styrene, alkylstyrene and a mixture thereof; (B) a protein in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
Claim 2
Dependent Claim 146 words
A phosphate-free or low-phosphate detergent comprising: a) a surfactant; and b) 0.1-20% by weight based on the formulation, of a water-soluble or water-dispersible grafted protein obtained by free radical copolymerization of (A) monoethylenically unsaturated monomers selected from the group consisting of esters of a monoethylenically unsaturated C 3-8 carboxylic acids with monohydric or polyhydric C 1-22 alcohols, esters of a monoethylenically unsaturated C 3-8 carboxylic acids with the addition products of 1-50 mol of alkylene oxide with 1 mol of a C 1-22 alcohol, amides of C 3-8 carboxylic acids which are derived from ammonia, C 1-22 alkylamines or C 1-22 dialkylamines, nitriles of carboxylic acids, vinyl ethers of C 1-8 alcohols, vinyl esters of saturated C 1-22 carboxylic acids, N-vinylamides, vinylpyridines, acrylamidopropanesulfonic acid, acrylamidoethanesulfonic acid, N,N-dialkylamino-C 2-4 -alkyl(meth)acrylamides, styrene, alkylstyrene and a mixture thereof; (B) a protein in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
Claim 3
Dependent Claim 25 words
The phosphate-free or low-phosphate detergent of claim 1, wherein said monoethylenically unsaturated monomers are selected from the group consisting of vinyl acetate and n-butyl acrylate.
Claim 4
Dependent Claim 35 words
The phosphate-free or low-phosphate detergent of claim 1, wherein said protein is selected from the group consisting of casein, gelatin, bone glue, or a protein from soybeans, cereals, corn or peas or a mixture thereof.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-03 1996-11-02 1997-05-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-03 2000-11-02 2001-05-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-03 2004-11-02 2005-05-04 $7700.00 Window Closed / Lapsed

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