US5207941A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Use of water-soluble or water-dispersible grafted proteins as detergent additives
Assignee: BASF SE
•
Filing: 1991-05-10
•
Granted: 1993-05-04
•
Expires: 2011-05-10
Abstract
Abstract Phosphate-free and low-phosphate detergents which contain surfactants as essential constituents also contain from 0.1 to 20% by weight, based on the particular formulation, of water-soluble or water-dispersible grafted proteins obtainable by free radical copolymerization of (A) monoethylenically unsaturated monomers in the presence of (B) proteins in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
Inventors
- 👤 Matthias Kroner
- 👤 Heinrich Hartmann
- 👤 Richard Baur
- 👤 Wolfgang Trieselt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 02:22
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3788; C08; C08F; C08F289/00; C11D3/0005; C11D3/0036
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
146 words
A phosphate-free or low-phosphate detergent comprising: a) a surfactant; and b) 0.1-20% by weight based on the formulation, of a water-soluble or water-dispersible grafted protein obtained by free radical copolymerization of (A) monoethylenically unsaturated monomers selected from the group consisting of esters of a monoethylenically unsaturated C 3-8 carboxylic acids with monohydric or polyhydric C 1-22 alcohols, esters of a monoethylenically unsaturated C 3-8 carboxylic acids with the addition products of 1-50 mol of alkylene oxide with 1 mol of a C 1-22 alcohol, amides of C 3-8 carboxylic acids which are derived from ammonia, C 1-22 alkylamines or C 1-22 dialkylamines, nitriles of carboxylic acids, vinyl ethers of C 1-8 alcohols, vinyl esters of saturated C 1-22 carboxylic acids, N-vinylamides, vinylpyridines, acrylamidopropanesulfonic acid, acrylamidoethanesulfonic acid, N,N-dialkylamino-C 2-4 -alkyl(meth)acrylamides, styrene, alkylstyrene and a mixture thereof; (B) a protein in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
Claim 2
Dependent Claim
146 words
A phosphate-free or low-phosphate detergent comprising: a) a surfactant; and b) 0.1-20% by weight based on the formulation, of a water-soluble or water-dispersible grafted protein obtained by free radical copolymerization of (A) monoethylenically unsaturated monomers selected from the group consisting of esters of a monoethylenically unsaturated C 3-8 carboxylic acids with monohydric or polyhydric C 1-22 alcohols, esters of a monoethylenically unsaturated C 3-8 carboxylic acids with the addition products of 1-50 mol of alkylene oxide with 1 mol of a C 1-22 alcohol, amides of C 3-8 carboxylic acids which are derived from ammonia, C 1-22 alkylamines or C 1-22 dialkylamines, nitriles of carboxylic acids, vinyl ethers of C 1-8 alcohols, vinyl esters of saturated C 1-22 carboxylic acids, N-vinylamides, vinylpyridines, acrylamidopropanesulfonic acid, acrylamidoethanesulfonic acid, N,N-dialkylamino-C 2-4 -alkyl(meth)acrylamides, styrene, alkylstyrene and a mixture thereof; (B) a protein in a weight ratio of (A):(B) of (0.5-90):(99.5-10).
Claim 3
Dependent Claim
25 words
The phosphate-free or low-phosphate detergent of claim 1, wherein said monoethylenically unsaturated monomers are selected from the group consisting of vinyl acetate and n-butyl acrylate.
Claim 4
Dependent Claim
35 words
The phosphate-free or low-phosphate detergent of claim 1, wherein said protein is selected from the group consisting of casein, gelatin, bone glue, or a protein from soybeans, cereals, corn or peas or a mixture thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-05-03 | 1996-11-02 | 1997-05-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-05-03 | 2000-11-02 | 2001-05-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-05-03 | 2004-11-02 | 2005-05-04 | $7700.00 | Window Closed / Lapsed |