US5200369A
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Glaze compositions
Assignee: COOKSON CERAMICS & MINERALS Ltd
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Filing: 1991-04-09
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Granted: 1993-04-06
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Expires: 2011-04-09
Abstract
Abstract Glaze composition for use on bone china and fine china which is essentially free from lead and cadium comprises, by weight, SiO 2 :35 to 60%, Bi 2 O 3 :5 to 45%, Al 2 O 3 :5 to 20%, B 2 O 3 :1 to 15%, at least one of CaO, MgO, SrO or BaO:2 to 20%, at least one of Li 2 O, Na 2 O, K 2 O:1 to 10%, and certain other optional ingredients, with the proviso that BaO is not contained in an amount of more than 2% by weight.
Inventors
- 👤 John F. Clifford
- 👤 Ivan Wozniak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 21:08
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/062; C03C3/064; C03C3/076; C03C3/089; C03C3/091; C03C8/00; C03C8/02
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
186 words
A transparent glaze composition for use on china and fine china which is essentially free from lead and cadmium and which consists essentially of the following components: ______________________________________
SiO.sub.2 35 to 60%
Bi.sub.2 O.sub.3 5 to 45%
Al.sub.2 O.sub.3 7 to 45%
B.sub.2 O.sub.3 4 to 10%
at least one of
CaO, MgO, SrO or BaO 2 to 20%
at least one of
Li.sub.2 O, Na.sub.2 O, K.sub.2 O
1 to 10%
TiO.sub.2 0 to 10%
ZrO.sub.2 0 to about 2.5%
SnO 0 to 10%
Nb.sub.2 O.sub.5 0 to 5%
Ta.sub.2 O.sub.5 0 to 5%
Sb.sub.2 O.sub.3 0 to 5%
a rare earth oxide 0 to 10%
ZnO 0 to 10%
P.sub.2 O.sub.5 0 to 10%
MoO.sub.3 and/or WO.sub.3
0 to 5%
fluoride ions 0 to 5%
______________________________________ all percentages being percentages by weight based on the total weight of the composition, with the proviso that BaO is not contained in an amount of more than 2% by weight, the glaze composition having a firing temperature of 1100° C.±40° C., and having a coefficient of thermal expansion of 50 to 90×10 -7 ° C. -1 .
Claim 2
Dependent Claim
186 words
A transparent glaze composition for use on china and fine china which is essentially free from lead and cadmium and which consists essentially of the following components: ______________________________________
SiO.sub.2 35 to 60%
Bi.sub.2 O.sub.3 5 to 45%
Al.sub.2 O.sub.3 7 to 45%
B.sub.2 O.sub.3 4 to 10%
at least one of
CaO, MgO, SrO or BaO 2 to 20%
at least one of
Li.sub.2 O, Na.sub.2 O, K.sub.2 O
1 to 10%
TiO.sub.2 0 to 10%
ZrO.sub.2 0 to about 2.5%
SnO 0 to 10%
Nb.sub.2 O.sub.5 0 to 5%
Ta.sub.2 O.sub.5 0 to 5%
Sb.sub.2 O.sub.3 0 to 5%
a rare earth oxide 0 to 10%
ZnO 0 to 10%
P.sub.2 O.sub.5 0 to 10%
MoO.sub.3 and/or WO.sub.3
0 to 5%
fluoride ions 0 to 5%
______________________________________ all percentages being percentages by weight based on the total weight of the composition, with the proviso that BaO is not contained in an amount of more than 2% by weight, the glaze composition having a firing temperature of 1100° C.±40° C., and having a coefficient of thermal expansion of 50 to 90×10 -7 ° C. -1 .
Claim 3
Dependent Claim
20 words
Glaze composition according to claim 1 which comprises from 10 to 25% by weight of Bi 2 O 3 .
Claim 4
Dependent Claim
19 words
Glaze composition according to claim 1 wherein the amount of SiO 2 is from 45 to 60% by weight.
Claim 5
Dependent Claim
28 words
Glaze composition according to claim 1 which fires at a temperature range of from 1060° to 1140° C. and which has a refractive index of at least 1.45.
Claim 6
Dependent Claim
11 words
Glaze composition according to claim 1 which additionally contains a pigment.
References Cited (Backward Citations)
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| 3.5 Years (Year 4) | 1996-04-05 | 1996-10-05 | 1997-04-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-04-05 | 2000-10-05 | 2001-04-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-04-05 | 2004-10-05 | 2005-04-06 | $7700.00 | Window Closed / Lapsed |