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US5200369A Expired / Lapsed US ⏱️ 0.0 years remaining

Glaze compositions

Assignee: COOKSON CERAMICS & MINERALS Ltd
•
Filing: 1991-04-09
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Granted: 1993-04-06
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Expires: 2011-04-09
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Abstract

Abstract Glaze composition for use on bone china and fine china which is essentially free from lead and cadium comprises, by weight, SiO 2 :35 to 60%, Bi 2 O 3 :5 to 45%, Al 2 O 3 :5 to 20%, B 2 O 3 :1 to 15%, at least one of CaO, MgO, SrO or BaO:2 to 20%, at least one of Li 2 O, Na 2 O, K 2 O:1 to 10%, and certain other optional ingredients, with the proviso that BaO is not contained in an amount of more than 2% by weight.

Inventors

  • 👤 John F. Clifford
  • 👤 Ivan Wozniak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 21:08
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/062; C03C3/064; C03C3/076; C03C3/089; C03C3/091; C03C8/00; C03C8/02

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 186 words
A transparent glaze composition for use on china and fine china which is essentially free from lead and cadmium and which consists essentially of the following components: ______________________________________ SiO.sub.2 35 to 60% Bi.sub.2 O.sub.3 5 to 45% Al.sub.2 O.sub.3 7 to 45% B.sub.2 O.sub.3 4 to 10% at least one of CaO, MgO, SrO or BaO 2 to 20% at least one of Li.sub.2 O, Na.sub.2 O, K.sub.2 O 1 to 10% TiO.sub.2 0 to 10% ZrO.sub.2 0 to about 2.5% SnO 0 to 10% Nb.sub.2 O.sub.5 0 to 5% Ta.sub.2 O.sub.5 0 to 5% Sb.sub.2 O.sub.3 0 to 5% a rare earth oxide 0 to 10% ZnO 0 to 10% P.sub.2 O.sub.5 0 to 10% MoO.sub.3 and/or WO.sub.3 0 to 5% fluoride ions 0 to 5% ______________________________________ all percentages being percentages by weight based on the total weight of the composition, with the proviso that BaO is not contained in an amount of more than 2% by weight, the glaze composition having a firing temperature of 1100° C.±40° C., and having a coefficient of thermal expansion of 50 to 90×10 -7 ° C. -1 .
Claim 2
Dependent Claim 186 words
A transparent glaze composition for use on china and fine china which is essentially free from lead and cadmium and which consists essentially of the following components: ______________________________________ SiO.sub.2 35 to 60% Bi.sub.2 O.sub.3 5 to 45% Al.sub.2 O.sub.3 7 to 45% B.sub.2 O.sub.3 4 to 10% at least one of CaO, MgO, SrO or BaO 2 to 20% at least one of Li.sub.2 O, Na.sub.2 O, K.sub.2 O 1 to 10% TiO.sub.2 0 to 10% ZrO.sub.2 0 to about 2.5% SnO 0 to 10% Nb.sub.2 O.sub.5 0 to 5% Ta.sub.2 O.sub.5 0 to 5% Sb.sub.2 O.sub.3 0 to 5% a rare earth oxide 0 to 10% ZnO 0 to 10% P.sub.2 O.sub.5 0 to 10% MoO.sub.3 and/or WO.sub.3 0 to 5% fluoride ions 0 to 5% ______________________________________ all percentages being percentages by weight based on the total weight of the composition, with the proviso that BaO is not contained in an amount of more than 2% by weight, the glaze composition having a firing temperature of 1100° C.±40° C., and having a coefficient of thermal expansion of 50 to 90×10 -7 ° C. -1 .
Claim 3
Dependent Claim 20 words
Glaze composition according to claim 1 which comprises from 10 to 25% by weight of Bi 2 O 3 .
Claim 4
Dependent Claim 19 words
Glaze composition according to claim 1 wherein the amount of SiO 2 is from 45 to 60% by weight.
Claim 5
Dependent Claim 28 words
Glaze composition according to claim 1 which fires at a temperature range of from 1060° to 1140° C. and which has a refractive index of at least 1.45.
Claim 6
Dependent Claim 11 words
Glaze composition according to claim 1 which additionally contains a pigment.

References Cited (Backward Citations)

US3428466A Cited
US4282035A Cited
US4554258A Cited
US4961999A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-04-05 1996-10-05 1997-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-04-05 2000-10-05 2001-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-04-05 2004-10-05 2005-04-06 $7700.00 Window Closed / Lapsed

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