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US5196126A Expired / Lapsed US ⏱️ 0.0 years remaining

Oscillating chemical reaction

Assignee: Iomech Ltd
•
Filing: 1990-08-06
•
Granted: 1993-03-23
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Expires: 2010-08-06
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Abstract

Abstract A process of producing a disinfecting BZ reaction comprising continuously adding, at a point in a system of continuously flowing water in which a reductant consisting of microbial life forms is present, halogens or halogen containing compounds which hydrolize to create two bistable systems at equilibrium. The first bistable system consists of Cl 2 , HOCL, OCl and chloramines in the water, and the second bistable system consists of IO 3 - , I 2 and HIO in the water. The bistable systems when perturbed by the reductant will initiate an oscillating reaction certain of whose intermediate products are microbicidal.

Inventors

  • 👤 Dennis H. O'Dowd

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:52
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/72; C02F1/76; C02F1/766

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 194 words
A process of producing a disinfecting BZ reaction comprising continuously adding at a point in a system of continuously flowing water in which a reductant consisting of microbial life forms or their metabolic by-products is present, chlorine (Cl 2 ) or a Cl 2 releasing compound and iodine (I 2 ) or a I 2 releasing compound, the amount of I 2 present being in the range of about 0.02-0.15 mg/l of water, the I 2 being added before about 50% of the Cl 2 has been hydrolized, the amount of Cl 2 not exceeding 5.0 mg/l at the I 2 addition point, which hydrolize to create two bistable systems at equilibrium, the first bistable system consisting of Cl 2 HOCl, OCl and chloramines in the water, the total chloramine existing in the water or produced by reaction with microbial life or their metabolic by-products being present to an amount being less than 25% of the total HOCl, the second bistable system consisting of IO 3 , I 2 and HIO in the water, which bistable systems when perturbed by the reductant will initiate an oscillating reaction certain of whose intermediate products are microbicidal.
Claim 2
Dependent Claim 194 words
A process of producing a disinfecting BZ reaction comprising continuously adding at a point in a system of continuously flowing water in which a reductant consisting of microbial life forms or their metabolic by-products is present, chlorine (Cl 2 ) or a Cl 2 releasing compound and iodine (I 2 ) or a I 2 releasing compound, the amount of I 2 present being in the range of about 0.02-0.15 mg/l of water, the I 2 being added before about 50% of the Cl 2 has been hydrolized, the amount of Cl 2 not exceeding 5.0 mg/l at the I 2 addition point, which hydrolize to create two bistable systems at equilibrium, the first bistable system consisting of Cl 2 HOCl, OCl and chloramines in the water, the total chloramine existing in the water or produced by reaction with microbial life or their metabolic by-products being present to an amount being less than 25% of the total HOCl, the second bistable system consisting of IO 3 , I 2 and HIO in the water, which bistable systems when perturbed by the reductant will initiate an oscillating reaction certain of whose intermediate products are microbicidal.
Claim 3
Dependent Claim 26 words
A process as claimed in claim 1 in which the concentration of Cl 2 in the water is in a range whereby the water is potable.
Claim 4
Dependent Claim 49 words
A method as claimed in claim 1 in which the I 2 or I 2 releasing compound and Cl 2 or Cl 2 releasing compound are added to water flowing through a pipe whereby the disinfecting BZ reaction removes bacterial colonization debris from the inner wall of the pipe.
Claim 5
Dependent Claim 24 words
A process as claimed in claim 1 in which the I 2 is introduced in to the continuous flow system in a saturated solution.
Claim 6
Dependent Claim 25 words
A process as claimed in claim 1 in which the I 2 is introduced into the continuous flow system as thermodynamically free I 2 .
Claim 7
Dependent Claim 41 words
A process as claimed in claim 1 in which the amount of chloramines is reduced to the maximum permissible level of 25% of the total HOCl by breakpoint chlorination wherein Cl 2 is added to the system to oxidize the chloramines.
Claim 8
Dependent Claim 37 words
A process as claimed in claim 1 in which the amount of chloramines is reduced to a maximum permissible level of 25% of the total HOCl prior to entry of the I 2 at the addition point.

References Cited (Backward Citations)

US2443429A Cited
US3189518A Cited
US3136716A Cited
US3733266A Cited
US3975271A Cited
US4555347A Cited
US4451376A Cited
SU1488708A1 Cited
GB2210362A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-03-22 1996-09-21 1997-03-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-03-22 2000-09-21 2001-03-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-03-22 2004-09-21 2005-03-23 $7700.00 Window Closed / Lapsed

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