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US5186985A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal displays of high tilt bias angles

Assignee: Kent State University
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Filing: 1991-04-04
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Granted: 1993-02-16
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Expires: 2011-04-04
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Abstract

Abstract Liquid Crystal Display Devices having alignment layers of polyimides which are characterized by pendant perfluorinated chains, preferably linear, and having more than 6 perfluorinated carbon atoms. These alignment layers are capable to provide the Liquid Crystal Display Devices with stable tilt angles of 5 or more degrees.

Inventors

  • 👤 William E. Estes
  • 👤 David P. Higley
  • 👤 Brian C. Auman
  • 👤 Andrew E. Feiring

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:01
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1039; G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1337; G02F1/133711; G02F1/133723; C09; C09K; C09K2323/00; C09K2323/02; C09K2323/027; C09K2323/0271

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 92 words
In an improved liquid crystal display device of the type having a common liquid crystal layer with opposite sides, a set of electrodes on either side of the liquid crystal layer, and an alignment polyimide layer between each set of electrodes and the common liquid crystal layer, wherein the improvement comprises the polyimide layer contains pendant perfluorinated hydrocarbon chains of more than 6 perfluorinated carbon atoms, wherein the polyimide layer comprises a reaction product of an acid dianhydride and a diamine, and wherein the pendant perfluorinated chains are part of the diamine.
Claim 2
Dependent Claim 92 words
In an improved liquid crystal display device of the type having a common liquid crystal layer with opposite sides, a set of electrodes on either side of the liquid crystal layer, and an alignment polyimide layer between each set of electrodes and the common liquid crystal layer, wherein the improvement comprises the polyimide layer contains pendant perfluorinated hydrocarbon chains of more than 6 perfluorinated carbon atoms, wherein the polyimide layer comprises a reaction product of an acid dianhydride and a diamine, and wherein the pendant perfluorinated chains are part of the diamine.
Claim 3
Dependent Claim 33 words
The liquid crystal display device as defined in claim 1, wherein the alignment polyimide layer is adaptable to provide the liquid crystal layer with a constant tilt angle of 5 degrees or more.
Claim 4
Dependent Claim 40 words
The liquid crystal display device as defined in claim 1, wherein the pendant perfluorinated chains are contained in the polyimide in an effective amount to provide the liquid crystal layer with a constant tilt angle of 5 degrees or more.
Claim 5
Dependent Claim 17 words
The liquid crystal display device as defined in claim 1, wherein the dianhydride is 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride.
Claim 6
Dependent Claim 17 words
The liquid crystal display device as defined in claim 1, wherein the pendant perfluorinated chain is linear.
Claim 7
Dependent Claim 22 words
The liquid crystal display device as defined in claim 5, wherein the pendant perfluorinated chain comprises 8 or more perfluorinated carbon atoms.
Claim 8
Dependent Claim 15 words
The liquid crystal display device as defined in claim 6, wherein the diamine is 3,5-diamino-1-perfluorooctylbenzene.
Claim 9
Dependent Claim 17 words
The liquid crystal display device as defined in claim 7, wherein the dianhydride is 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride.
Claim 10
Dependent Claim 15 words
The liquid crystal display device as defined in claim 6, wherein the diamine is 2-perfluorooctyl-4,6-diaminomesitylene.
Claim 11
Dependent Claim 17 words
The liquid crystal display device as defined in claim 9, wherein the dianhydride is 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride.
Claim 12
Dependent Claim 15 words
The liquid crystal display device as defined in claim 6, wherein the diamine is 4-(1,1,11-trihydroperfluorounecyloxy)-1,3-phenylenediamine.
Claim 13
Dependent Claim 17 words
The liquid crystal display device as defined in claim 11, wherein the dianhydride is 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-02-16 1996-08-17 1997-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-02-16 2000-08-17 2001-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-02-16 2004-08-17 2005-02-16 $7700.00 Window Closed / Lapsed

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