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Method of improving the maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor

Assignee: Osram Sylvania Inc
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Filing: 1992-04-02
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Granted: 1993-02-09
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Expires: 2012-04-02
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Abstract

Abstract The initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor is significantly improved by combining the phosphor with a flux and subjecting the phosphor/flux mixture to a refiring and rewashing process before applying the phosphor to the interior of a fluorescent lamp envelope. Surface concentrations of europium and barium are significantly increased, while surface concentrations of magnesium and silicon are decreased.

Inventors

  • 👤 Anthony F. Kasenga
  • 👤 Tuan A. Dang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:31
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/02; C09K11/025; C09K11/08; C09K11/77; C09K11/7728; C09K11/77342

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 205 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7 :Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) combining said europium-activated barium magnesium silicate phosphor with a flux selected from the group consisting of barium fluoride, barium silicofluoride, magnesium silicofluoride, ammonium silicofluoride, ammonium fluoride, magnesium fluoride, calcium fluoride, and strontium fluoride, said flux being in an amount of between about 0.06% and 0.25% by weight of the phosphor/flux mixture to form a uniform mixture; b) firing said mixture in a reducing atmosphere at a temperature of about 1150° C. to about 1300° C. for about 2 to 6 hours; c) washing said fired mixture in an aqueous solution of potassium hydroxide; d) removing said potassium hydroxide solution from said fired mixture and washing the resulting potassium hydroxide-washed mixture with deionized water; e) filtering, drying and screening the resulting washed mixture to obtain a treated europium-activated barium magnesium silicate phosphor; and f) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 2
Dependent Claim 205 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7 :Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) combining said europium-activated barium magnesium silicate phosphor with a flux selected from the group consisting of barium fluoride, barium silicofluoride, magnesium silicofluoride, ammonium silicofluoride, ammonium fluoride, magnesium fluoride, calcium fluoride, and strontium fluoride, said flux being in an amount of between about 0.06% and 0.25% by weight of the phosphor/flux mixture to form a uniform mixture; b) firing said mixture in a reducing atmosphere at a temperature of about 1150° C. to about 1300° C. for about 2 to 6 hours; c) washing said fired mixture in an aqueous solution of potassium hydroxide; d) removing said potassium hydroxide solution from said fired mixture and washing the resulting potassium hydroxide-washed mixture with deionized water; e) filtering, drying and screening the resulting washed mixture to obtain a treated europium-activated barium magnesium silicate phosphor; and f) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 3
Dependent Claim 11 words
The process of claim 1 wherein said flux is ammonium fluoride.
Claim 4
Dependent Claim 21 words
The process of claim 1 wherein said reducing atmosphere comprises about 33% by volume hydrogen and about 67% by volume nitrogen.
Claim 5
Dependent Claim 21 words
The process of claim 1 wherein said aqueous solution of potassium hydroxide is maintained at a temperature of about 60° C.
Claim 6
Dependent Claim 21 words
The process of claim 1 wherein said phosphor is washed in said aqueous solution of potassium hydroxide for about 2 hours.
Claim 7
Dependent Claim 23 words
The process of claim 1 wherein the weight ratio of said potassium hydroxide to said phosphor is about 0.7:1 to about 1.3: 1.
Claim 8
Dependent Claim 19 words
The process of claim 1 wherein the weight ratio of said potassium hydroxide to said phosphor is about 1:1.
Claim 9
Dependent Claim 24 words
The process of claim 1 wherein said mixture is washed with deionized water until the pH of said mixture is less than about 10.
Claim 10
Dependent Claim 157 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7 :Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) firing said europium-activated barium magnesium silicate phosphor in a reducing atmosphere at a temperature of about 1150° C. to about 1300° C. for about 2 to 6 hours to produce a fired phosphor; b) washing said fired phosphor in an aqueous solution of potassium hydroxide; c) removing said potassium hydroxide solution from said fired phosphor and washing the resulting potassium hydroxide-washed phosphor with deionized water; d) filtering, drying and screening the resulting washed phosphor to obtain a treated europium-activated barium magnesium silicate phosphor; and e) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 11
Dependent Claim 157 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7 :Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) firing said europium-activated barium magnesium silicate phosphor in a reducing atmosphere at a temperature of about 1150° C. to about 1300° C. for about 2 to 6 hours to produce a fired phosphor; b) washing said fired phosphor in an aqueous solution of potassium hydroxide; c) removing said potassium hydroxide solution from said fired phosphor and washing the resulting potassium hydroxide-washed phosphor with deionized water; d) filtering, drying and screening the resulting washed phosphor to obtain a treated europium-activated barium magnesium silicate phosphor; and e) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 12
Dependent Claim 21 words
The process of claim 9 wherein said reducing atmosphere comprises about 33% by volume hydrogen and about 67% by volume nitrogen.
Claim 13
Dependent Claim 21 words
The process of claim 9 wherein said aqueous solution of potassium hydroxide is maintained at a temperature of about 60° C.
Claim 14
Dependent Claim 21 words
The process of claim 9 wherein said phosphor is washed in said aqueous solution of potassium hydroxide for about 2 hours.
Claim 15
Dependent Claim 22 words
The process of claim 9 wherein the weight ratio of said potassium hydroxide to said phosphor is about 0.7:1 to about 1.3:1.
Claim 16
Dependent Claim 19 words
The process of claim 9 wherein the weight ratio of said potassium hydroxide to said phosphor is about 1:1.
Claim 17
Dependent Claim 24 words
The process of claim 9 wherein said phosphor is washed with deionized water until the pH of said phosphor is less than about 10.
Claim 18
Dependent Claim 122 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7: Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) washing said europium-activated barium magnesium silicate phosphor in an aqueous solution of potassium hydroxide; b) removing said potassium hydroxide solution from said phosphor and washing said phosphor with deionized water; c) filtering, drying and screening the resulting washed phosphor to obtain a treated europium-activated barium magnesium silicate phosphor; and d) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 19
Dependent Claim 122 words
A process for improving the initial power output and maintenance of a fluorescent lamp containing europium-activated barium magnesium silicate phosphor having the general formulation BaMg 2 Si 2 O 7: Eu and an atomic concentration of component elements at its particle surfaces of 2.3% barium, 1.4% europium, 25% magnesium, 15% silicon and the balance oxygen, comprising the steps of: a) washing said europium-activated barium magnesium silicate phosphor in an aqueous solution of potassium hydroxide; b) removing said potassium hydroxide solution from said phosphor and washing said phosphor with deionized water; c) filtering, drying and screening the resulting washed phosphor to obtain a treated europium-activated barium magnesium silicate phosphor; and d) coating the interior of a fluorescent lamp envelope with said treated phosphor.
Claim 20
Dependent Claim 21 words
The process of claim 16 wherein said aqueous solution of potassium hydroxide is maintained at a temperature of about 60° C.
Claim 21
Dependent Claim 21 words
The process of claim 16 wherein said phosphor is washed in said aqueous solution of potassium hydroxide for about 2 hours.
Claim 22
Dependent Claim 22 words
The process of claim 16 wherein the weight ratio of said potassium hydroxide to said phosphor is about 0.7:1 to about 1.3:1.
Claim 23
Dependent Claim 19 words
The process of claim 16 wherein the weight ratio of said potassium hydroxide to said phosphor is about 1:1.
Claim 24
Dependent Claim 24 words
The process of claim 16 wherein said phosphor is washed with deionized water until the pH of said phosphor is less than about 10.

References Cited (Backward Citations)

US3157602A Cited
US3651363A Cited
US3676361A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-02-09 1996-08-10 1997-02-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-02-09 2000-08-10 2001-02-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-02-09 2004-08-10 2005-02-09 $7700.00 Window Closed / Lapsed

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