Patent US3529049A successfully refreshed from Google Patents.
Patent US5180705A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5180705A Expired / Lapsed US ⏱️ 0.0 years remaining

Transfer imaging using metal-azo and metal-azomethine dyes

Assignee: Eastman Kodak Co
•
Filing: 1991-03-11
•
Granted: 1993-01-19
•
Expires: 2011-03-11
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Dye donor sheets comprising a substrate having a coating comprising a binder and at least one neutral 1:1 metal-azo or neutral 1:1 metal-azomethine dye having the general structure: ##STR1## wherein Z 1 and Z 2 each independently represent an arene nucleus, having from 5 to 14 ring atoms; G 1 and G 2 each independently represent a metal ligating group, and further wherein G 1 and G 2 may be contained within or pendant from at least one of Z 1 and Z 2 ; R represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, an alkoxy group, a sulfonamido group, an aryl group, a thiol group, an alkylthio group, an arylthio group, an alkylamino group, an arylamino group, an amino group, an alkoxycarbonyl group, an acyloxy group, a nitro group, a cyano group, a sulfonyl group, a sulfoxyl group, an aryloxy group, a hydroxy group, a thioamido group, a carbamoyl group, a sulfamoyl group, a carboxyl group, a sulfo group, a formyl group, an acyl group, a ureido group, or aryloxycarbonyl group, a silyl group, a carbonato group, or a sulfoalkoxy group; L is any combination of monodentate, bidentate, or tridentate ligands which satisfy the coordination requirements of the metal; X represents nitrogen or a methine (CH) group; M is a divalent or polyvalent transition metal where the coordination number is at least four; and k, m, and n are whole numbers less than or equal to 3. Use of the above constructions in thermal dye transfer imaging is also disclosed.

Inventors

  • 👤 Terrance P. Smith
  • 👤 David W. Macomber
  • 👤 Jeffrey C. Chang
  • 👤 Linda K. Williams

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:13
CPC Classifications
B; B41; B41M; B41M3/00; B41M3/06; B41M5/00; B41M5/26; B41M5/382; B41M5/385; B41M5/3856; B41M5/3854; B41M5/39; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 238 words
A thermal transfer dye donor sheet comprising a substrate having a coating consisting essentially of at least one neutral 1:1 metalazo or neutral 1:1 metal-azomethine dye having the general structure: ##STR38## wherein Z 1 and Z 2 each independently represent an arene nucleus, having from 5 to 14 ring atoms; G 1 and G 2 each independently represent a metal ligating group, and further wherein G 1 and G 2 may be contained within or pendant from at least one of Z 1 and Z 2 ; R represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, an alkoxy group, a sulfonamido group, an aryl group, a thiol group, an alkylthio group, an arylthio group, an alkylamino group, an arylamino group, an amino group, an alkoxycarbonyl group, an acyloxy group, a nitro group, a cyano group, a sulfonyl group, a sulfoxyl group, an aryloxy group, a hydroxy group, a thioamido group, a carbamoyl group, a sulfamoyl group, a formyl group, an acyl group, a ureido group, or aryloxycarbonyl group, a silyl group, a carbonato group, or a sulfoalkoxy group; L is any combination of monodentate, bidentate, or tridentate ligands which satisfy the coordination requirements of the metal; X represents nitrogen or a methine group; M is a divalent or polyvalent transition metal where the coordination number is at least four; and k, m, and n are whole numbers less than or equal to 3.
Claim 2
Dependent Claim 238 words
A thermal transfer dye donor sheet comprising a substrate having a coating consisting essentially of at least one neutral 1:1 metalazo or neutral 1:1 metal-azomethine dye having the general structure: ##STR38## wherein Z 1 and Z 2 each independently represent an arene nucleus, having from 5 to 14 ring atoms; G 1 and G 2 each independently represent a metal ligating group, and further wherein G 1 and G 2 may be contained within or pendant from at least one of Z 1 and Z 2 ; R represents a hydrogen atom, a halogen atom, an alkyl group, an acylamino group, an alkoxy group, a sulfonamido group, an aryl group, a thiol group, an alkylthio group, an arylthio group, an alkylamino group, an arylamino group, an amino group, an alkoxycarbonyl group, an acyloxy group, a nitro group, a cyano group, a sulfonyl group, a sulfoxyl group, an aryloxy group, a hydroxy group, a thioamido group, a carbamoyl group, a sulfamoyl group, a formyl group, an acyl group, a ureido group, or aryloxycarbonyl group, a silyl group, a carbonato group, or a sulfoalkoxy group; L is any combination of monodentate, bidentate, or tridentate ligands which satisfy the coordination requirements of the metal; X represents nitrogen or a methine group; M is a divalent or polyvalent transition metal where the coordination number is at least four; and k, m, and n are whole numbers less than or equal to 3.
Claim 3
Dependent Claim 11 words
A dye-donor sheet according to claim 1 further comprising a binder.
Claim 4
Dependent Claim 12 words
A dye-donor sheet according to claim 2 wherein said binder is nontransferrable.
Claim 5
Dependent Claim 29 words
A dye-donor sheet according to claim 1 wherein G, and G 2 independently represent hydroxy, carboxy, or a nitrogen atom which is part of Z, and Z 2 .
Claim 6
Dependent Claim 16 words
A dye-donor sheet according to claim 1 wherein L is a nitrogen-containing heterocycle or tertiary phosphine.
Claim 7
Dependent Claim 23 words
A dye-donor sheet according to claim 1 wherein L is selected from the group consisting of pyridine, substituted pyridines, imidazole, and substituted imidazoles.
Claim 8
Dependent Claim 21 words
A dye-donor sheet according to claim 1 wherein L is selected from the group consisting of 4-vinyl pyridine or 1-vinyl imidazole.
Claim 9
Dependent Claim 21 words
A dye-donor sheet according to claim 1 wherein M is selected from the group consisting of chromium(III), nickel(II), palladium(II), and platinum(II).
Claim 10
Dependent Claim 11 words
A dye-donor sheet according to claim 8 wherein M is chromium(III).
Claim 11
Dependent Claim 50 words
A thermal dye transfer process which comprises the steps of: (a) contacting the thermal transfer dye-donor sheet of claim 1 with a suitable receptor sheet; and (b) thereafter, applying heat in an imagewise fashion to said thermal transfer dye-donor sheet whereby the dye is thermally transferred to the receptor sheet.
Claim 12
Dependent Claim 41 words
A thermal dye transfer process according to claim 10 wherein said dye-donor sheet is heated to a temperature from about 100° C. to 400° C. for a period of about 1 to 10 milliseconds while in contact with the receptor sheet.
Claim 13
Dependent Claim 19 words
A thermal dye transfer process according to claim 10 wherein the receptor sheet is paper or transparent polyester film.

References Cited (Backward Citations)

US3765814A Cited
US4218367A Cited
US4605607A Cited
US5084435A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-01-19 1996-07-20 1997-01-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-01-19 2000-07-20 2001-01-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-01-19 2004-07-20 2005-01-19 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag