Abstract This invention relates to radiopaque polyurethane compositions which are reaction products of (a) cycloaliphatic diisocyanates; (b) at least one polyether diol having a molecular weight of from about 500 to about 6000; and (c) an isocyanate-reactive bromine-containing compound selected from the group consisting of (i) tetrabromodipentaerythritol and (ii) a mixture of tetrabromodipentaerythritol and dibromoneopentyl glycol; and (d) optionally, a catalyst; wherein the amount of component (c) is such that bromine constitutes at least 15% by weight of the polyurethane composition, wherein the weight ratio of component (b) to component (c) is from about 2:98 to about 55:45, and wherein the components are reacted at an isocyanate index of from about 95 to about 120.
A radiopaque polyurethane composition comprising a reaction product of (a) a cycloaliphatic diisocyanate; (b) at least one polyether diol having a molecular weight of from 500 to 6000; (c) isocyanate-reactive bromine-containing compound selected from the group consisting of (i) tetrabromodipentaerythritol and (ii) a mixture of tetrabromodipentaerythritol and dibromoneopentyl glycol; and (d) optionally, a catalyst; wherein the amount of component (c) is such that the amount of bromine in the polyurethane composition is at least 15% by weight, wherein the weight ratio of component (b) to component (c) is from 2:98 to 55:45, and wherein the components are reacted at an isocyanate index of from 0.95 to 1.2.
Claim 2
Dependent Claim
107 words
A radiopaque polyurethane composition comprising a reaction product of (a) a cycloaliphatic diisocyanate; (b) at least one polyether diol having a molecular weight of from 500 to 6000; (c) isocyanate-reactive bromine-containing compound selected from the group consisting of (i) tetrabromodipentaerythritol and (ii) a mixture of tetrabromodipentaerythritol and dibromoneopentyl glycol; and (d) optionally, a catalyst; wherein the amount of component (c) is such that the amount of bromine in the polyurethane composition is at least 15% by weight, wherein the weight ratio of component (b) to component (c) is from 2:98 to 55:45, and wherein the components are reacted at an isocyanate index of from 0.95 to 1.2.
Claim 3
Dependent Claim
14 words
A radiopaque polyurethane composition according to claim 1 wherein the cycloaliphatic diisocyanate is dicyclohexylmethane-4,4'-diisocyanate.
Claim 4
Dependent Claim
23 words
A radiopaque polyurethane composition according to claim 1 wherein the amount of bromine in the polyurethane composition is 20 to 30% by weight.
Claim 5
Dependent Claim
23 words
A radiopaque polyurethane composition according to claim 1 wherein the weight ratio of component (b) to component (c) is from 10:90 to 40:60.
Claim 6
Dependent Claim
12 words
A radiopaque polyurethane composition according to claim 1 which is optically transparent.