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US5173357A Expired / Lapsed US ⏱️ 0.0 years remaining

Tear-resistant polyester film and laminated sheets comprised of the same

Assignee: Polyplastics Co Ltd
•
Filing: 1991-05-29
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Granted: 1992-12-22
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Expires: 2011-05-29
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Abstract

Abstract Polyester film has a thickness of between 10 to 500 μm and exhibits excellent tear strength retention against thermal history conditions. The film is prepared from a resin composition which includes 100 parts by weight of a polyester consisting essentially of alkylene terephthalate groups as the main recurring units in the polymer chain and between 0.1 to 5 parts by weight of a bisoxazoline compound incorporated thereinto. The film is usefully employed as a sterilizing bag or as a food-packaging material and can be laminated to anther sheet of film or to paper.

Inventors

  • 👤 Toshio Nakane
  • 👤 Yukihiko Kageyama
  • 👤 Kenji Hijikata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 01:08
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/10; B32B27/36; B32B7/00; B32B7/04; B32B7/12; C; C08; C08J; C08J5/00; C08J5/18; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35; C08L; C08L67/00; C08L67/02; B32B2307/00; B32B2307/50; B32B2307/582; B32B2307/5825; B32B2317/00; B32B2317/12; B32B2367/00; B32B2439/00; B32B2439/70; C08J2367/00; C08J2367/02; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/268; Y10T428/269; Y10T428/31504; Y10T428/31786; Y10T428/3179

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 112 words
A polybutylene terephthalate film having a thickness of between 10 to 500 μm and exhibiting excellent tear-strength retention after being subjected to thermal history conditions, said film being formed of a resin composition which consists essentially of a blend of 100 parts by weight of a polybutylene terephthalate base resin and between 0.1 to 5 parts by weight of a bisoxazoline compound, and wherein said film has an initial tear strength value determined according to JIS P 8116 of at least 15 grams-force per 10 μm thickness of said film and a tear strength retention of at least 70% after being subjected to thermal history conditions of 120° C. for 3 minutes.
Claim 2
Dependent Claim 112 words
A polybutylene terephthalate film having a thickness of between 10 to 500 μm and exhibiting excellent tear-strength retention after being subjected to thermal history conditions, said film being formed of a resin composition which consists essentially of a blend of 100 parts by weight of a polybutylene terephthalate base resin and between 0.1 to 5 parts by weight of a bisoxazoline compound, and wherein said film has an initial tear strength value determined according to JIS P 8116 of at least 15 grams-force per 10 μm thickness of said film and a tear strength retention of at least 70% after being subjected to thermal history conditions of 120° C. for 3 minutes.
Claim 3
Dependent Claim 19 words
A polybutylene terephthalate film according to claim 1, wherein said polybutylene terephthalate base resin predominately includes 1,4-butylene terephthalate groups.
Claim 4
Dependent Claim 16 words
A polybutylene terephthalate film according to claim 1 or 2 wherein the bisoxazoline compound is phenylenebisoxazoline.
Claim 5
Dependent Claim 38 words
A polybutylene terephthalate film according to claim 3, wherein said resin composition further consists essentially of between 1 to 20 parts by weight of another thermoplastic resin per 100 parts by weight of the polybutylene terephthalate base resin.
Claim 6
Dependent Claim 127 words
A laminated paper composite sheet comprised of a paper sheet laminated to a polybutylene terephthalate film, wherein said film has a thickness of between 10 to 500 μm and exhibits excellent tear-strength retention after being subjected to thermal history conditions, said film being formed of a resin composition which consists essentially of a blend of 100 parts by weight of a polybutylene terephthalate base resin, and between 0.1 to 5 parts by weight of a bisoxazoline compound, and wherein said film has an initial tear strength value determined according to JIS P 8116 of at least 15 grams-force per 10 μm thickness of said film and a tear strength retention of at least 70% after being subjected to thermal history conditions of 120° C. for 3 minutes.
Claim 7
Dependent Claim 127 words
A laminated paper composite sheet comprised of a paper sheet laminated to a polybutylene terephthalate film, wherein said film has a thickness of between 10 to 500 μm and exhibits excellent tear-strength retention after being subjected to thermal history conditions, said film being formed of a resin composition which consists essentially of a blend of 100 parts by weight of a polybutylene terephthalate base resin, and between 0.1 to 5 parts by weight of a bisoxazoline compound, and wherein said film has an initial tear strength value determined according to JIS P 8116 of at least 15 grams-force per 10 μm thickness of said film and a tear strength retention of at least 70% after being subjected to thermal history conditions of 120° C. for 3 minutes.
Claim 8
Dependent Claim 23 words
A composite sheet as in claim 5, wherein said polybutylene terephthalate base resin of said polybutylene terephthalate film predominately includes 1,4-butylene terephthalate groups.
Claim 9
Dependent Claim 15 words
A composite sheet as in claim 5 or 6, wherein the bisoxazoline compound is phenylenebisoxazoline.
Claim 10
Dependent Claim 36 words
A composite sheet according to claim 7, wherein resin composition further consists essentially of between 1 to 20 parts by weight of another thermoplastic resin per 100 parts by weight of the polybutylene terephthalate base resin.

References Cited (Backward Citations)

US4499219A Cited
US4595612A Cited
US4946372A Cited
US4957578A Cited
US5049603A Cited
EP0400936A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-12-22 1996-06-22 1996-12-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-12-22 2000-06-22 2000-12-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-12-22 2004-06-22 2004-12-22 $7700.00 Window Closed / Lapsed

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