US5164330A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Etchback process for tungsten utilizing a NF3/AR chemistry
Assignee: Intel Corp
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Filing: 1991-04-17
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Granted: 1992-11-17
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Expires: 2011-04-17
Abstract
Abstract A process for etching a tungsten layer formed on a semiconductor substrate is described. The etch is carried out in a parallel plate plasma reactor. The etchant gases include nitrogen trifluoride (NF3) and argon (Ar). The use of NF3 in a tungsten etching process reduces the build-up of polymers or sulfur residues on the electrode as occurs with processes utilizing sulfur or carbon fluorides as etchant gases. The process has a sufficiently high etch rate for volume production. The NF3-Ar etch process can be used to etchback a blanket layer of deposited tungsten to form tungsten via plugs in contact areas of the device. In the via plug process, reduced micro-loading effect, that is, the tendency of some plugs to be etched away before the complete etching of the blanket layer, has been achieved. The etching of tunsten with NF3-Ar process can be preformed in one or more steps in process utilizing several etching steps. Additionally, a tungsten etch incorporating one or more NF3-Ar steps and one or more steps utilizing etchants such as SF6, Cl2, O2, CF4, CBrF3, CF3Cl, CF2Cl2 or similar etchants can be used to optimize etch rate and uniformity while obtaining the benefit of reduced residue build-up.
Inventors
- 👤 Rickie L. Davis
- 👤 Sohail U. Ahmed
- 👤 Sridhar Balakrishnan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 10:08
CPC Classifications
H; H10; H10P; H10P95/00; H10P95/04; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056
Claims Analysis
Total Claims: 47
Claim 1
Independent Claim
130 words
A process for etching a refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer; and exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas, wherein said flow of said NF 3 in said first mixture is in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said flow of said first inert gas in said first mixture is in the range of approximately 300-500 SCCM, said first plasma is formed at a power in the range of approximately 325-425 Watts and at a pressure in the range of approximately 350-600 mTorr.
Claim 2
Dependent Claim
130 words
A process for etching a refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer; and exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas, wherein said flow of said NF 3 in said first mixture is in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said flow of said first inert gas in said first mixture is in the range of approximately 300-500 SCCM, said first plasma is formed at a power in the range of approximately 325-425 Watts and at a pressure in the range of approximately 350-600 mTorr.
Claim 3
Dependent Claim
14 words
The process as described in claim 1 wherein said first inert gas is argon.
Claim 4
Dependent Claim
19 words
The process as described in claim 1 wherein said exposure to said first plasma proceeds for a predetermined time.
Claim 5
Dependent Claim
16 words
The process as described in claim 1 wherein said refractory metal layer comprises a tungsten layer.
Claim 6
Dependent Claim
14 words
The process as described in claim 4 wherein said first inert gas is argon.
Claim 7
Dependent Claim
19 words
The process as described in claim 4 wherein said exposure to said first plasma proceeds for a predetermined time.
Claim 8
Dependent Claim
19 words
The process as described in claim 5 wherein said exposure to said first plasma proceeds for a predetermined time.
Claim 9
Dependent Claim
128 words
A process for etching a refractory metal layer and an adhesion metal layer disposed beneath said refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer and said adhesion underlayer; exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising NF 3 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising NF 3 , Cl 2 and a third inert gas.
Claim 10
Dependent Claim
128 words
A process for etching a refractory metal layer and an adhesion metal layer disposed beneath said refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer and said adhesion underlayer; exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising NF 3 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising NF 3 , Cl 2 and a third inert gas.
Claim 11
Dependent Claim
78 words
The process as described in claim 8 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer has been removed.
Claim 12
Dependent Claim
161 words
The process as described in claim 8 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said NF 3 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 200-300 SCCM, said NF 3 in said third mixture has a flow rate in the range of approximately 20-30 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 70-85 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 150-200 SCCM.
Claim 13
Dependent Claim
84 words
The process as described in claim 10 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 450-600 mTorr, and said third plasma is formed at a power in the range of approximately 175-200 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 14
Dependent Claim
31 words
The process as described in claim 8 wherein said refractory metal layer comprises tungsten and said adhesion layer is selected from the group consisting of titanium, titanium nitride and titanium tungsten.
Claim 15
Dependent Claim
78 words
The process as described in claim 12 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer has been removed.
Claim 16
Dependent Claim
161 words
The process as described in claim 12 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said NF 3 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 200-300 SCCM, said NF 3 in said third mixture has a flow rate in the range of approximately 20-30 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 70-85 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 150-200 SCCM.
Claim 17
Dependent Claim
78 words
The process as described in claim 14 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer has been removed.
Claim 18
Dependent Claim
84 words
The process as described in claim 14 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 450-600 mTorr, and said third plasma is formed at a power in the range of approximately 175-200 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 19
Dependent Claim
78 words
The process as described in claim 16 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer has been removed.
Claim 20
Dependent Claim
33 words
The process as described in claim 8, 12, 10, 14, 11 or 16 wherein said first inert gas is argon, said second inert gas is argon and said third inert gas is argon.
Claim 21
Dependent Claim
180 words
A process for filling openings in a dielectric layer formed on a substrate, said openings exposing a plurality of underlying regions on said substrate, said process comprising the steps of: providing said substrate with said dielectric layer formed thereon; depositing a refractory metal layer on said dielectric layer and said underlying regions to substantially cover said dielectric layer and said underlying regions and to substantially fill said openings; etching said refractory metal layer overlying said dielectric layer in a parallel plate reactor by a method comprising the step of: exposing said substrate to a plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas, wherein said flow of said NF 3 in said first mixture is in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said flow of said first inert gas in said first mixture is in the range of approximately 300-500 SCCM, said first plasma is formed at a power in the range of approximately 325-425 Watts and at a pressure in the range of approximately 350-600 mTorr.
Claim 22
Dependent Claim
180 words
A process for filling openings in a dielectric layer formed on a substrate, said openings exposing a plurality of underlying regions on said substrate, said process comprising the steps of: providing said substrate with said dielectric layer formed thereon; depositing a refractory metal layer on said dielectric layer and said underlying regions to substantially cover said dielectric layer and said underlying regions and to substantially fill said openings; etching said refractory metal layer overlying said dielectric layer in a parallel plate reactor by a method comprising the step of: exposing said substrate to a plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas, wherein said flow of said NF 3 in said first mixture is in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said flow of said first inert gas in said first mixture is in the range of approximately 300-500 SCCM, said first plasma is formed at a power in the range of approximately 325-425 Watts and at a pressure in the range of approximately 350-600 mTorr.
Claim 23
Dependent Claim
19 words
The process as described in claim 19 wherein said exposure to said first plasma proceeds for a predetermined time.
Claim 24
Dependent Claim
16 words
The process as described in claim 19 wherein said refractory metal layer comprises a tungsten layer.
Claim 25
Dependent Claim
19 words
The process as described in claim 21 wherein said exposure to said first plasma proceeds for a predetermined time.
Claim 26
Dependent Claim
16 words
The process as described in claim 19 or 21 wherein said first inert gas is argon.
Claim 27
Dependent Claim
181 words
A process for filling openings in a dielectric layer formed on a substrate, said openings exposing a plurality of underlying regions on said substrate, said process comprising the steps of: providing said substrate having said dielectric layer; depositing an adhesion layer on said dielectric layer and said underlying regions to substantially cover said dielectric layer and said underlying regions; depositing a refractory metal layer on said adhesion layer to substantially cover said adhesion layer and to substantially fill said openings; etching said refractory metal layer and said adhesion layer overlying said dielectric layer in a parallel plate reactor by a method comprising the steps of; exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising NF 3 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising NF 3 , Cl 2 and a third inert gas.
Claim 28
Dependent Claim
181 words
A process for filling openings in a dielectric layer formed on a substrate, said openings exposing a plurality of underlying regions on said substrate, said process comprising the steps of: providing said substrate having said dielectric layer; depositing an adhesion layer on said dielectric layer and said underlying regions to substantially cover said dielectric layer and said underlying regions; depositing a refractory metal layer on said adhesion layer to substantially cover said adhesion layer and to substantially fill said openings; etching said refractory metal layer and said adhesion layer overlying said dielectric layer in a parallel plate reactor by a method comprising the steps of; exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising NF 3 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising NF 3 , Cl 2 and a third inert gas.
Claim 29
Dependent Claim
86 words
The process as described in claim 24 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer overlying said dielectric layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer overlying said dielectric layer has been removed.
Claim 30
Dependent Claim
161 words
The process as described in claim 24 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said NF 3 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 200-300 SCCM, said NF 3 in said third mixture has a flow rate in the range of approximately 20-30 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 70-85 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 150-200 SCCM.
Claim 31
Dependent Claim
84 words
The process as described in claim 26 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 450-600 mTorr, and said third plasma is formed at a power in the range of approximately 175-200 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 32
Dependent Claim
31 words
The process as described in claim 24 wherein said refractory metal layer comprises tungsten and said adhesion layer is selected from the group consisting of titanium, titanium nitride and titanium tungsten.
Claim 33
Dependent Claim
86 words
The process as described in claim 28 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer overlying said dielectric layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer overlying said dielectric layer has been removed.
Claim 34
Dependent Claim
161 words
The process as described in claim 28 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said NF 3 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 40-80 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 200-300 SCCM, said NF 3 in said third mixture has a flow rate in the range of approximately 20-30 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 70-85 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 150-200 SCCM.
Claim 35
Dependent Claim
84 words
The process as described in claim 30 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 450-600 mTorr, and said third plasma is formed at a power in the range of approximately 175-200 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 36
Dependent Claim
86 words
The process as described in claim 31 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer overlying said dielectric layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer overlying said dielectric layer has been removed.
Claim 37
Dependent Claim
86 words
The process as described in claim 30 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer overlying said dielectric layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer overlying said dielectric layer has been removed.
Claim 38
Dependent Claim
33 words
The process as described in claim 24, 28, 26, 30, 27 or 31 wherein said first inert gas is argon, said second inert gas is argon and said third inert gas is argon.
Claim 39
Dependent Claim
86 words
The process as described in claim 34 wherein said exposure to said first plasma proceeds for a predetermined time, said exposure to said second plasma proceeds until a first endpoint is reached, said first endpoint being triggered when substantially all of said refractory metal layer overlying said dielectric layer has been removed, and said exposure to said third plasma proceeds until a second endpoint is reached, said second endpoint being triggered when substantially all of said adhesion metal layer overlying said dielectric layer has been removed.
Claim 40
Dependent Claim
153 words
A process for etching a refractory metal layer and an adhesion metal layer disposed beneath said refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer and said adhesion underlayer, etching said refractory metal layer and said adhesion layer overlying said dielectric layer in a parallel plate reactor by a method comprising the steps of: exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising SF 6 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising SF 6 , Cl 2 and a third inert gas.
Claim 41
Dependent Claim
153 words
A process for etching a refractory metal layer and an adhesion metal layer disposed beneath said refractory metal layer in a parallel plate reactor during the fabrication of a device on a semiconductor substrate, said process comprising the steps of: providing said substrate having said refractory metal layer and said adhesion underlayer, etching said refractory metal layer and said adhesion layer overlying said dielectric layer in a parallel plate reactor by a method comprising the steps of: exposing said substrate to a first plasma formed in a flow of a first mixture comprising NF 3 and a first inert gas; exposing said substrate to a second plasma formed in a flow of a second mixture comprising SF 6 , Cl 2 and a second inert gas; and exposing said substrate to a third plasma formed in a flow of a third mixture comprising SF 6 , Cl 2 and a third inert gas.
Claim 42
Dependent Claim
31 words
The process as described in claim 36 wherein said refractory metal layer comprises tungsten and said adhesion layer is selected from the group consisting of titanium, titanium nitride and titanium tungsten.
Claim 43
Dependent Claim
161 words
The process as described in claim 37 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said SF 6 in said second mixture has a flow rate in the range of approximately 50-100 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 35-60 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 100-200 SCCM, said SF 6 in said third mixture has a flow rate in the range of approximately 15-25 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 35-45 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 75-150 SCCM.
Claim 44
Dependent Claim
84 words
The process as described in claim 38 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 350-550 mTorr, and said third plasma is formed at a power in the range of approximately 150-175 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 45
Dependent Claim
161 words
The process as described in claim 36 wherein said NF 3 in said first mixture has a flow rate in the range of approximately 50-150 Standard Cubic Centimeters per Minute (SCCM), said first inert gas in said first mixture has a flow rate in the range of approximately 300-500 SCCM, said SF 6 in said second mixture has a flow rate in the range of approximately 50-100 SCCM, said Cl 2 in said second mixture has a flow rate in the range of approximately 35-60 SCCM, said second inert gas in said second mixture has a flow rate in the range of approximately 100-200 SCCM, said SF 6 in said third mixture has a flow rate in the range of approximately 15-25 SCCM, said Cl 2 in said third mixture has a flow rate in the range of approximately 35-45 SCCM, and said third inert gas in said third mixture has a flow rate in the range of approximately 75-150 SCCM.
Claim 46
Dependent Claim
84 words
The process as described in claim 40 wherein said first plasma is formed at a power in the range of approximately 325-425 Watts and a pressure in the range of approximately 350-600 mTorr, said second plasma is formed at a power in the range of approximately 250-400 Watts and a pressure in the range of approximately 350-550 mTorr, and said third plasma is formed at a power in the range of approximately 150-175 Watts and a pressure in the range of approximately 350-550 mTorr.
Claim 47
Dependent Claim
33 words
The process as described in claim 36, 37, 40, 38, 41 or 39 wherein said first inert gas is argon, said second inert gas is helium and said third inert gas is helium.
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