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Method for forming color image

Assignee: Fujifilm Holdings Corp
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Filing: 1990-02-14
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Granted: 1992-11-10
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Expires: 2010-02-14
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Abstract

Abstract A method for processing a silver halide color photosensitive material is disclosed: (i) subjecting a full-color photographic material to scanning exposure to three lights each having different wavelength; (ii) processing said exposed full-color photographic material with a color developer containing at least one aromatic primary amine color developing agent and containing chloride ion in amount of from 3.5×10 -2 to 1.5×10 -1 mole/liter and bromide ion in an amount from 3.5×10 -2 to 1.5×10 -1 mole/liter. The full-color photographic material contains at least three silver halide light-sensitive layers each containing yellow-coloring, magenta-coloring or cyan coloring-couplers; at least two of the layers are so color-sensitized that may have a maximum value of the color sensitivity at a different wavelength of 670 nm or more; at least one of the layers contains high silver chloride emulsions having silver chloride content 90 mole % or more; and at least one dye of formula (A): ##STR1## where R 1 to R 6 , Z 1 , Z 2 , L, X and n are defined as disclosed in the specification.

Inventors

  • 👤 Yoshio Inagaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:31
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/407; G03C7/413; Y; Y10; Y10S; Y10S430/00; Y10S430/145

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 283 words
A method for forming a color image wherein a full-color photographic material which has at least three silver halide light-sensitive layers each containing yellow-coloring, magenta-coloring or cyan-coloring couplers, at least two of the layers being color-sensitized so that they have a maximum value of color sensitivity at a different wavelength of 670 nm or more and at least one of the layers being made of a high silver chloride emulsion having a layer average silver chloride content of 90 mol% or more, and which has a hydrophilic colloid layer containing at least one dye of the following formula (A), is subjected to scanning exposure by three lights each having a different wavelength and then processed with a color developer containing at least one aromatic primary amine color developing agent and containing chloride ion in an amount of from 3.5×10 -2 to 1.5×10 -1 mol/liter and bromide ion in an amount of from 3.0×10 -5 to 1.0×10 -3 mol/liter, ##STR121## where R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may be same or different and each represents a substituted or unsubstituted alkyl group; Z 1 and Z 2 each represent a non-metallic atomic group necessary for forming a substituted or unsubstituted benzo-condensed or naphtho-condensed ring; provided that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , Z 1 and Z 2 are such that the dye molecule has at least three acid groups; L represents a substituted or unsubstituted methine group; X represents an anion; n represents 1 or 2; provided that when the dye is in the form of an internal salt, n is 1.
Claim 2
Independent Claim 283 words
A method for forming a color image wherein a full-color photographic material which has at least three silver halide light-sensitive layers each containing yellow-coloring, magenta-coloring or cyan-coloring couplers, at least two of the layers being color-sensitized so that they have a maximum value of color sensitivity at a different wavelength of 670 nm or more and at least one of the layers being made of a high silver chloride emulsion having a layer average silver chloride content of 90 mol% or more, and which has a hydrophilic colloid layer containing at least one dye of the following formula (A), is subjected to scanning exposure by three lights each having a different wavelength and then processed with a color developer containing at least one aromatic primary amine color developing agent and containing chloride ion in an amount of from 3.5×10 -2 to 1.5×10 -1 mol/liter and bromide ion in an amount of from 3.0×10 -5 to 1.0×10 -3 mol/liter, ##STR121## where R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may be same or different and each represents a substituted or unsubstituted alkyl group; Z 1 and Z 2 each represent a non-metallic atomic group necessary for forming a substituted or unsubstituted benzo-condensed or naphtho-condensed ring; provided that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , Z 1 and Z 2 are such that the dye molecule has at least three acid groups; L represents a substituted or unsubstituted methine group; X represents an anion; n represents 1 or 2; provided that when the dye is in the form of an internal salt, n is 1.
Claim 3
Dependent Claim 395 words
The method for forming a color image as in claim 1, in which the photographic material contains a super-color sensitizing agent of one of the following formulae (IV), (V), (VI), (VII), (VIIIa), (VIIIb) and (VIIIc): ##STR122## where A 41 represents a divalent aromatic residue; R 41 , R 42 , R 43 and R 44 each represent a hydrogen atom, a hydroxyl group, an alkyl group, an alkoxy group, an aryloxy group, a halogen atom, a heterocyclic group, a heterocyclic-thio group, an arylthio group, an amino group, an alkylamino group, an arylamino group, an aralkylamino group, an aryl group or a mercapto group, which may optionally be substituted; provided that at least one of A 41 , R 41 , R 42 , R 43 and R 44 has a sulfo group; X 41 and Y 41 each represents --CH═ or --N═; and at least one of X 41 and Y 41 represents --N═; ##STR123## where Z 51 represents a non-metallic atomic group necessary for completing a 5-membered or 6-membered nitrogen-containing hetero-ring, which may be condensed with a benzene ring or a naphthalene ring; R 51 represents a hydrogen atom, an alkyl group or an alkenyl group; R 52 represents a hydrogen atom or a lower alkyl group; and X 51 represents an acid anion; ##STR124## where R 61 represents an alkyl group, an alkenyl group or an aryl group; and X 61 represents a hydrogen atom, an alkali metal atom, an ammonium group or a percursor thereof; ##STR125## where Y 71 represents an oxygen atom, a sulfur atom, ═NH or ═N--(L 71 )n 72 --R 72 ; L 71 represents a divalent linking group; R 71 and R 72 each represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group; n 72 represents 0 or 1; X 71 has the same meaning as X 61 ; and n 71 represents 0 or 1; ##STR126## where R 81 and R 82 each represent OH, OM 81 , OR 84 , NH 2 , NHR 84 , --N(R 84 ) 2 , --NHNH 2 or --NHNHR 84 ; R 84 represents an alkyl group, an aryl group or an aralkyl group; M 81 represents an alkali metal or an alkaline earth metal; R 83 represents OH or a halogen atom; and n 81 and n 82 each represent 1, 2 or 3.
Claim 4
Dependent Claim 33 words
The method for forming a color image as in claim 1, in which the content of the dye of the formula (A) is from 10 -3 g/m 2 to 1 g/m 2 .
Claim 5
Dependent Claim 54 words
The method for forming a color image as in claim 1, which L groups in formula (A) may combine to form a group according to formula (B): ##STR127## wherein Z 3 represents a non-metal atomic group necessary for forming 5 or 6 membered ring and Y represents a hydrogen atom or a monovalent group.
Claim 6
Dependent Claim 29 words
The method for forming a color image as in claim 1, the maximum absorption wavelength range of said dyes represented by formula (A) is from 730 to 850 nm.
Claim 7
Dependent Claim 29 words
The method for forming a color image as in claim 1, the maximum absorption wavelength range of said dyes represented by formula (A) is from 770 to 850 nm.

References Cited (Backward Citations)

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US4536473A Cited
US4619892A Cited
US4839265A Cited
EP0256858A2 Cited
US4874684A Cited
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EP0288076A2 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-11-10 1996-05-11 1996-11-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-11-10 2000-05-11 2000-11-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-11-10 2004-05-11 2004-11-10 $7700.00 Window Closed / Lapsed

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