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Chromium-nitrogen alloy surface coating composition

Assignee: Centre Stephanois de Recherches Mecaniques Hydromecanique et Frottement SA
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Filing: 1990-10-16
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Granted: 1992-11-03
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Expires: 2010-10-16
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Abstract

Abstract Coating for conferring good friction properties upon a substrate and comprising a non-equilibrium alloy of chromium and nitrogen. The alloy comprises, per one hundred atoms, from 87 to 68 atoms of chromium and from 13 to 32 atoms of nitrogen and two phases, a cubic microcrystalline chromium phase containing included nitrogen and a quadratic chromium nitride phase with a stoichiometric deficient nitrogen content relative to the Cr2N nitride. The ratio of the quadratic nitride lattice parameters is between 1.02 and 1.5. This quadratic nitride was previously unknown and probably can exist only in association with chromium. It resists wear up to five times better than known single-phase chromium-nitrogen alloys and is free of the inherent fragility of two-phase alloys containing hexagonal Cr2N nitride. The coatings are obtained by magnetron cathode sputtering of chromium with a nitrogen partial presure in a rare gas atmosphere between a maximum and a minimum determined experimentally.

Inventors

  • 👤 Jean-Paul Terrat
  • 👤 Pascal Fort

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:09
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/06; C23C14/14; C23C14/0688

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 78 words
Coating for conferring upon a substrate good friction properties, said coating comprising a metastable alloy of chromium and nitrogen, wherein said alloy comprises, per one hundred atoms, from 87 to 68 atoms of chromium and from 13 to 32 atoms of nitrogen in two phases, consisting essentially of a cubic microcrystalline chromium phase containing including nitrogen and a quadratic chromium nitride phase with a stoichiometric deficient nitrogen content relative to the thermodynamic equilibrium hexagonal Cr 2 N nitride.
Claim 2
Dependent Claim 78 words
Coating for conferring upon a substrate good friction properties, said coating comprising a metastable alloy of chromium and nitrogen, wherein said alloy comprises, per one hundred atoms, from 87 to 68 atoms of chromium and from 13 to 32 atoms of nitrogen in two phases, consisting essentially of a cubic microcrystalline chromium phase containing including nitrogen and a quadratic chromium nitride phase with a stoichiometric deficient nitrogen content relative to the thermodynamic equilibrium hexagonal Cr 2 N nitride.
Claim 3
Dependent Claim 19 words
Coating according to claim 1 wherein the ratio of the quadratic nitride lattice parameters is between 1.02 and 1.5.
Claim 4
Dependent Claim 14 words
Coating according to claim 1 wherein its thickness is between 0.1 and 50 μm.
Claim 5
Dependent Claim 14 words
Coating according to claim 3 wherein its thickness is between 5 and 20 μm.
Claim 6
Dependent Claim 65 words
A chromium and nitrogen alloy having good friction properties, said alloy being metastable and comprising, per one hundred atoms, from 87 to 68 atoms of chromium and from 13 to 32 atoms of nitrogen in two phases, consisting essentially of a microcrystalline chromium phase and a quadratic chromium nitride phase with a stoichiometric deficient nitrogen content to the thermodynamic equilibrium hexagonal Cr 2 N nitride.
Claim 7
Dependent Claim 65 words
A chromium and nitrogen alloy having good friction properties, said alloy being metastable and comprising, per one hundred atoms, from 87 to 68 atoms of chromium and from 13 to 32 atoms of nitrogen in two phases, consisting essentially of a microcrystalline chromium phase and a quadratic chromium nitride phase with a stoichiometric deficient nitrogen content to the thermodynamic equilibrium hexagonal Cr 2 N nitride.

References Cited (Backward Citations)

FR2512070A1 Cited
EP0074322A2 Cited
US4486285A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-11-03 1996-05-04 1996-11-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-11-03 2000-05-04 2000-11-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-11-03 2004-05-04 2004-11-03 $7700.00 Window Closed / Lapsed

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