Three-stage sorption type cryogenic refrigeration systems and methods employing heat regeneration

Claim 2

A refrigeration method comprising: heating a first heat exchange fluid having a first boiling point to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state, cooling the first fluid from the high pressure gaseous state to a high pressure liquid state, and then reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; heating a second heat exchange fluid having a second boiling point lower than the first boiling point to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state, cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state, and then reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; heating a third heat exchange fluid having a third boiling point lower than the second boiling point to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state, cooling the third fluid from the high pressure gaseous state to a high pressure liquid state, by heat exchange with the second fluid in its low pressure liquid state, and then reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, and, before said step of cooling the third fluid, pre-cooling the third fluid to a low temperature gaseous state by heat exchange with the first fluid in its low pressure liquid state.

Claim 3

A method as defined in claim 1 wherein said steps of heating the first and second heat exchange fluids are carried out by transferring heat from the third heat exchange fluid while in its high pressure gaseous state.

Claim 4

A refrigeration method comprising: heating a first heat exchange fluid having a first boiling point to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state, cooling the first fluid from the high pressure gaseous state to a high pressure liquid state, and then reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; heating a second heat exchange fluid having a second boiling point lower than the first boiling point to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state, cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state, and then reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and heating a third heat exchange fluid having a third boiling point lower than the second boiling point to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state, cooling the third fluid from the high pressure gaseous state to a high pressure liquid state, by heat exchange with the second fluid in its low pressure liquid state, and then reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said steps of heating the first and second heat exchange fluids are carried out by transferring heat from the third heat exchange fluid while in its high pressure gaseous state.

Claim 5

A refrigeration method comprising: heating a first heat exchange fluid having a first boiling point to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state, cooling the first fluid from the high pressure gaseous state to a high pressure liquid state, and then reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; heating a second heat exchange fluid having a second boiling point lower than the first boiling point to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state, cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state, and then reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and heating a third heat exchange fluid having a third boiling point lower than the second boiling point to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state, cooling the third fluid from the high pressure gaseous state to a high pressure liquid state, by heat exchange with the second fluid in its low pressure liquid state, and then reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said steps of heating the first and second heat exchange fluids are carried out by transferring heat from the third heat exchange fluid while in its high pressure gaseous state.

Claim 6

A method as defined in claim 3 wherein said steps of heating the first, second and third fluids are performed in three respective sorption compressors and the sorption compressors for the first and second fluids surround the sorption compressor for the third fluid.

Claim 7

A method as defined in claim 4 wherein there are two sorption compressors for the third fluid, and said step of heating the third fluid is performed in each of the two sorption compressors in alternation and comprises thermally coupling the two sorption compressors for the third fluid in order to transfer heat to the compressor in which the heating step is being performed to the other compressor.

Claim 8

A refrigeration method comprising: heating a first heat exchange fluid having a first boiling point to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state, cooling the first fluid from the high pressure gaseous state to a high pressure liquid state, and then reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; heating a second heat exchange fluid having a second boiling point lower than the first boiling point to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state, cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state, and then reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and heating a third heat exchange fluid having a third boiling point lower than the second boiling point to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state, cooling the third fluid from the high pressure gaseous state to a high pressure liquid state, by heat exchange with the second fluid in its low pressure liquid state, and then reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said step of heating the third fluid is performed in two sorption compressors and is performed in each of the two sorption compressors in alternation and comprises thermally coupling the two sorption compressors for the third fluid in order to transfer heat to the compressor in which the heating step is being performed to the other compressor.

Claim 9

A refrigeration method comprising: heating a first heat exchange fluid having a first boiling point to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state, cooling the first fluid from the high pressure gaseous state to a high pressure liquid state, and then reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; heating a second heat exchange fluid having a second boiling point lower than the first boiling point to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state, cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state, and then reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and heating a third heat exchange fluid having a third boiling point lower than the second boiling point to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state, cooling the third fluid from the high pressure gaseous state to a high pressure liquid state, by heat exchange with the second fluid in its low pressure liquid state, and then reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said step of heating the third fluid is performed in two sorption compressors and is performed in each of the two sorption compressors in alternation and comprises thermally coupling the two sorption compressors for the third fluid in order to transfer heat to the compressor in which the heating step is being performed to the other compressor.

Claim 10

A method as defined in claim 1 wherein the third fluid is oxygen.

Claim 11

A method as defined in claim 7 wherein the first and second fluids are, respectively, xenon and krypton.

Claim 12

A method as defined in claim 7 wherein said step of heating the third fluid is carried out to heat the third fluid to a peak temperature of the order of 500° C.

Claim 13

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said means for heating in each said heat exchange circuit is a sorption compressor.

Claim 14

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said means for heating in each said heat exchange circuit is a sorption compressor.

Claim 15

A refrigeration system as defined in claim 10 wherein said sorption compressors of said first and second circuits comprise annular fluid storage chambers surrounding said sorption compressor of said third circuit, and said means for heating one of said first and second fluids comprises heat exchange means for transferring heat from the third fluid in the high pressure gaseous state to one of the first and second fluids.

Claim 16

A refrigeration system as defined in claim 11 wherein said means for heating said first and second fluids each comprises a respective one of said heat exchange means.

Claim 17

A refrigeration system as defined in claim 11 wherein said third circuit further comprises means for pre-cooling the third fluid from the means for heating the third fluid to a low temperature gaseous state by heat exchange with the first fluid in its low pressure liquid state.

Claim 18

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said third circuit further comprises means for pre-cooling the third fluid from the means for heating the third fluid to a low temperature gaseous state by heat exchange with the first fluid in its low pressure liquid state.

Claim 19

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said third circuit further comprises means for pre-cooling the third fluid from the means for heating the third fluid to a low temperature gaseous state by heat exchange with the first fluid in its low pressure liquid state.

Claim 20

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said means for heating in said third heat exchange circuit comprises two sorption compressors and heat exchange means coupled between said compressors for transferring heat from fluid in one compressor to fluid in the other compressor.

Claim 21

A refrigeration system comprising: a first heat exchange circuit comprising: a mass of a first heat exchange fluid having a first boiling point; means for heating the first heat exchange fluid to a selected temperature above the first boiling point in order to place the first fluid in a high pressure gaseous state; means for cooling the first fluid from the high pressure gaseous state to a high pressure liquid state; and means for reducing the pressure of the first fluid to convert the first fluid from the high pressure liquid state to a low pressure liquid state; a second heat exchange circuit comprising: a mass of a second heat exchange fluid having a second boiling point lower than the first boiling point; means for heating the second fluid to a selected temperature above the second boiling point in order to place the second fluid in a high pressure gaseous state; means for cooling the second fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the first fluid in its low pressure liquid state; and means for reducing the pressure of the second fluid to convert the second fluid from the high pressure liquid state to a low pressure liquid state; and a third heat exchange circuit comprising: a mass of a third heat exchange fluid having a third boiling point lower than the second boiling point; means for heating the third heat exchange fluid to a selected temperature above the third boiling point in order to place the third fluid in a high pressure gaseous state; means for cooling the third fluid from the high pressure gaseous state to a high pressure liquid state by heat exchange with the second fluid in its low pressure liquid state; and means for reducing the pressure of the third fluid to convert the third fluid from the high pressure liquid state to a low pressure liquid state, wherein said means for heating in said third heat exchange circuit comprises two sorption compressors and heat exchange means coupled between said compressors for transferring heat from fluid in one compressor to fluid in the other compressor.

Claim 22

A refrigeration system as defined in claim 15 wherein said heat exchange means comprise a solid thermally conductive member and controllable heat transfer members for transferring heat between said thermally conductive member and fluid in each said compressor.

Claim 23

A refrigeration system as defined in claim 15 wherein said means for heating in each of said first and second circuits comprise two sorption chambers each having an annular form and surrounding a respective compressor of said third circuit heat exchange means.

Claim 24

A method as defined in claim 3 wherein the third fluid is oxygen.

Claim 25

A method as defined in claim 18 wherein the first and second fluids are, respectively, xenon and krypton.

Claim 26

A method as defined in claim 16 wherein said step of heating the third fluid is carried out to heat the third fluid to a peak temperature of the order of 500° C.

Claim 27

A method as defined in claim 6 wherein the third fluid is oxygen.

Claim 28

A method as defined in claim 21 wherein the first and second fluids are, respectively, xenon and krypton.

Claim 29

A method as defined in claim 21 wherein said step of heating the third fluid is carried out to heat the third fluid to a peak temperature of the order of 500° C.