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US5156785A Expired / Lapsed US ⏱️ 0.0 years remaining

Extruded tubing and catheters having increased rotational stiffness

Assignee: Cordis Corp
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Filing: 1991-07-10
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Granted: 1992-10-20
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Expires: 2011-07-10
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Abstract

Abstract Extruded catheters and other flexible plastic tubing may be manufactured with improved rotational and/or longitudinal stiffness, compared with catheters made of more conventional plastics. A tubing of liquid crystal polymer plastic-containing material may be extruded through a tube extrusion die while rotating the inner and outer die walls to provide circumferential shear to the extruded tube. Thus the liquid crystal polymer is oriented in a helical manner to provide improved properties, including greater rotational stiffness.

Inventors

  • 👤 Richard J. Zdrahala

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:35
CPC Classifications
A; A61; A61M; A61M25/00; A61M25/0009; B; B29; B29C; B29C48/00; B29C48/001; B29C48/0013; B29C48/0015; B29C48/0016; B29C48/03; B29C48/09; B29C48/10; B29C48/131; B29C48/16; B29C48/18; B29C48/21; B29C48/25; B29C48/30; B29C48/32; B29C48/33; B29C48/34; A61M25/0043; A61M25/005; A61M25/0053; B29C48/335; B29K; B29K2105/00; B29K2105/0079; B29L; B29L2031/00; B29L2031/753; B29L2031/7542

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 231 words
In the method of manufacturing tubing by extrusion of a plastic material through a tube extrusion die having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die with longitudinal stretching while rotating the outer and inner walls relative to each other whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation, in which said liquid crystal polymer plastic-containing material comprises a blended mixture of from 1 to 40 weight percent of a liquid crystal polymer and 60 to 99 weight percent of a different, structural plastic matrix, said liquid crystal polymer defining a separate phase from said structural plastic matrix, said separate phase forming generally helically extending fibrils within said extruded tube, said fibrils being dispersed in said structural plastic, whereby an increased amount of rotational stiffness is provided to at least a section of said tubing, and further in which the relative rotation rate of said outer and inner wall is varied as said tube is extruded, whereby various sections of the extruded tubing exhibit helically extending fibrils of differing angles to the longitudinal axis of said extruded tubing, and the various sections of the extruded tubing exhibit differing, predetermined rotational stiffness.
Claim 2
Dependent Claim 231 words
In the method of manufacturing tubing by extrusion of a plastic material through a tube extrusion die having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die with longitudinal stretching while rotating the outer and inner walls relative to each other whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation, in which said liquid crystal polymer plastic-containing material comprises a blended mixture of from 1 to 40 weight percent of a liquid crystal polymer and 60 to 99 weight percent of a different, structural plastic matrix, said liquid crystal polymer defining a separate phase from said structural plastic matrix, said separate phase forming generally helically extending fibrils within said extruded tube, said fibrils being dispersed in said structural plastic, whereby an increased amount of rotational stiffness is provided to at least a section of said tubing, and further in which the relative rotation rate of said outer and inner wall is varied as said tube is extruded, whereby various sections of the extruded tubing exhibit helically extending fibrils of differing angles to the longitudinal axis of said extruded tubing, and the various sections of the extruded tubing exhibit differing, predetermined rotational stiffness.
Claim 3
Dependent Claim 18 words
The method of claim 1 in which said fibrils generally exhibit a aspect ratio of 10 to 300.
Claim 4
Dependent Claim 136 words
In the method of manufacturing an intravascular catheter by extrusion of a plastic material through a tube extrusion die having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die while rotating the outer and inner walls relative to each other, whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation to provide a increased amount of rotational stiffness to at least a section of said tubing, and further in which the rotation rate of said outer and inner wall is varied as said tube is extruded, whereby various sections of the extruded tubing exhibit differing, predetermined rotational stiffness.
Claim 5
Dependent Claim 136 words
In the method of manufacturing an intravascular catheter by extrusion of a plastic material through a tube extrusion die having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die while rotating the outer and inner walls relative to each other, whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation to provide a increased amount of rotational stiffness to at least a section of said tubing, and further in which the rotation rate of said outer and inner wall is varied as said tube is extruded, whereby various sections of the extruded tubing exhibit differing, predetermined rotational stiffness.
Claim 6
Dependent Claim 25 words
The method of claim 3 in which said liquid crystal polymer plastic-containing material comprises from 5 to 35 weight percent of said liquid crystal polymer.
Claim 7
Dependent Claim 22 words
The method of claim 3 in which said liquid crystal polymer is the terpolymer of hydroxybenzoic acid, ethylene glycol, and terephthalic acid.
Claim 8
Dependent Claim 19 words
The method of claim 3 in which said catheter is manufactured to be free of any metal support means.
Claim 9
Dependent Claim 34 words
The method of claim 6 in which a coating of antithrombogenic material is coextruded on the outer surface of said tube during the step of extruding said tube of liquid crystal polymer plastic-containing material.
Claim 10
Dependent Claim 155 words
In the method of manufacturing tubing by extrusion of a plastic material through a tube extrusion die, having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die while rotating the outer and inner walls relative to each other, whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation said liquid crystal polymer plastic-containing material comprising a blend mixture of from 1 to 40 weight percent of a liquid crystal polymer and 60 to 99 weight percent of a different, structural plastic matrix, said liquid crystal polymer defining a separate phase from said structural plastic matrix, said separate phase defining, after extrusion, generally helically extending fibrils within said extruded tube, said fibrils being dispersed in said structural plastic.
Claim 11
Dependent Claim 155 words
In the method of manufacturing tubing by extrusion of a plastic material through a tube extrusion die, having an outer wall to define the extruded tube outer diameter and an inner wall to define the extruded tube inner diameter, the improvement comprising, in combination: extruding a tube of liquid crystal polymer plastic-containing material through said tube extrusion die while rotating the outer and inner walls relative to each other, whereby said tube of liquid crystal polymer plastic-containing material exhibits at least a degree of circumferential orientation said liquid crystal polymer plastic-containing material comprising a blend mixture of from 1 to 40 weight percent of a liquid crystal polymer and 60 to 99 weight percent of a different, structural plastic matrix, said liquid crystal polymer defining a separate phase from said structural plastic matrix, said separate phase defining, after extrusion, generally helically extending fibrils within said extruded tube, said fibrils being dispersed in said structural plastic.
Claim 12
Dependent Claim 18 words
The method of claim 8 in which said fibrils generally exhibit an aspect ratio of 10 to 300.
Claim 13
Dependent Claim 25 words
The method of claim 8 in which said liquid crystal polymer plastic-containing material comprises from 5 to 35 weight percent of said liquid crystal polymer.
Claim 14
Dependent Claim 28 words
The method of claim 8 in which said liquid crystal polymer exhibits a greater propensity than poly(ethylene terephthalate) to orient during melt flow and to retain such orientation.
Claim 15
Dependent Claim 61 words
The method of claim 8 in which the inner and outer die walls are rotated at a varying rate as said tube is extruded, whereby various sections of the extruded tubing exhibit generally helically extending fibrils within said extruded tube which are of differing angles to the tube axis, whereby various sections off the extruded tubing exhibit differing, predetermined rotational stiffness.
Claim 16
Dependent Claim 13 words
The method of manufacturing a catheter, comprising the steps defined in claim 8.
Claim 17
Dependent Claim 19 words
The method of claim 13 in which said catheter is manufactured to be free of any metal support means.
Claim 18
Dependent Claim 30 words
The method of claim 8 in which a coating of antithrombogenic material is coextruded on said tube during the step of extruding said tube of liquid crystal polymer plastic-containing material.
Claim 19
Dependent Claim 19 words
The method of claim 3 in which said different structural plastic matrix is softer than said liquid crystal polymer.
Claim 20
Dependent Claim 18 words
The method of claim 1 in which said fibrils generally exhibit an aspect ratio of 10 to 300.
Claim 21
Dependent Claim 19 words
The method of claim 1 in which said different structural plastic matrix is softer than said liquid crystal polymer.
Claim 22
Dependent Claim 19 words
The method of claim 8 in which said different structural plastic matrix is softer than said liquid crystal polymer.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-20 1996-04-20 1996-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-20 2000-04-20 2000-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-20 2004-04-20 2004-10-20 $7700.00 Window Closed / Lapsed

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