US4734240A
Expired / Lapsed
US
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Melt-extrusion of polymer which is capable of forming an anisotropic melt phase to form large shaped articles exhibiting improved polymeric orientation
Assignee: CNA Holdings LLC
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Filing: 1986-01-24
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Granted: 1988-03-29
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Expires: 2006-01-24
Abstract
Abstract An improved technique is provided to melt-extrude a liquid crystalline polymer to form large elongated solid shaped articles which exhibit significantly improved polymeric orientation. The molten polymer which is capable of forming an anisotropic melt phase is extruded through a converging die that is provided with at least one enclosed cooling zone at an interior location within the flowing molten polymer wherein a cooling fluid is circulated. This cools the molten polymer adjacent the cooling zone with the concomitant increase in its melt viscosity. Such increased melt viscosity at the interior of the stream of the molten polymer contributes to the uniformity of the polymeric orientation imparted within the converging die as well as during subsequent drawdown outside the extrusion orifice. Such improved polymeric orientation leads to the formation of an improved product (e.g., a three-dimensional rod) which exhibits an unusually high tensile modulus in the direction of its length. The present invention accordingly overcomes difficulties encountered in the prior art wherein melt-extruded shaped articles significantly larger than fibers heretofore often have exhibited substantial internal heterogeneity and a highly oriented skin and a core of a substantially lesser polymeric orientation.
Inventors
- 👤 Tai-Shung Chung
- 👤 Sunil K. Garg
- 👤 Daniel Palangio
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 21:30
CPC Classifications
B; B29; B29C; B29C48/00; B29C48/25; B29C48/78; B29C48/86; B29C48/87; B29C48/022; B29C48/03; B29C48/05; B29C48/06; B29C48/07; B29C48/08; B29C48/30; B29C48/32; B29C48/34; B29C48/09; B29C48/10; B29C48/12; B29K; B29K2105/00; B29K2105/0079
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
220 words
A process of melt-extrusion for the formation of a solid elongated shaped article having a cross-sectional area of at least 7×10 -4 square inch, a minimum thickness of at least 30 mils, and a polymeric orientation substantially in the direction of its length which exhibits improved polymeric orientation uniformity throughout the interior thereof comprising: (a) providing in a laterally confined zone a moving stream of molten polymer which exhibits an anisotropic melt phase, (b) passing said stream of molten polymer which exhibits an anisotropic melt phase through a converging die to produce an elongated extrudate while providing at the interior of said stream of molten polymer while present in said converging die at least one enclosed cooling zone wherein a cooling fluid is circulated whereby the portion of the molten polymer adjacent to said cooling zone is cooled and the melt viscosity thereof is increased while maintaining said polymer in the molten state, and (c) subjecting the resulting elongated extrudate outside the extrusion die to the cooling of its exterior and to a drawdown of approximately 1.5:1 to 10:1 while forming said solid elongated shaped article, whereby the increased melt viscosity at the interior of said stream of molten polymer created in step (b) contributes to the uniformity of the polymeric orientation which is imparted in steps (b) and (c).
Claim 2
Dependent Claim
220 words
A process of melt-extrusion for the formation of a solid elongated shaped article having a cross-sectional area of at least 7×10 -4 square inch, a minimum thickness of at least 30 mils, and a polymeric orientation substantially in the direction of its length which exhibits improved polymeric orientation uniformity throughout the interior thereof comprising: (a) providing in a laterally confined zone a moving stream of molten polymer which exhibits an anisotropic melt phase, (b) passing said stream of molten polymer which exhibits an anisotropic melt phase through a converging die to produce an elongated extrudate while providing at the interior of said stream of molten polymer while present in said converging die at least one enclosed cooling zone wherein a cooling fluid is circulated whereby the portion of the molten polymer adjacent to said cooling zone is cooled and the melt viscosity thereof is increased while maintaining said polymer in the molten state, and (c) subjecting the resulting elongated extrudate outside the extrusion die to the cooling of its exterior and to a drawdown of approximately 1.5:1 to 10:1 while forming said solid elongated shaped article, whereby the increased melt viscosity at the interior of said stream of molten polymer created in step (b) contributes to the uniformity of the polymeric orientation which is imparted in steps (b) and (c).
Claim 3
Dependent Claim
53 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is selected from the group consisting of wholly aromatic polyesters, aromatic-aliphatic polyesters, wholly aromatic poly(ester-amides), aromatic-aliphatic poly(ester-amides), aromatic polyazomethines, aromatic polyester carbonates, and mixtures of the foregoing.
Claim 4
Dependent Claim
41 words
A process of melt-extrusion for the formation of solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is wholly aromatic in the sense that each moiety present contributes a least one aromatic ring.
Claim 5
Dependent Claim
31 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a wholly aromatic polyester.
Claim 6
Dependent Claim
31 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a wholly aromatic poly(ester-amide).
Claim 7
Dependent Claim
46 words
A process a melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase, is a polymer which includes not less than about 10 mole percent of recurring units which include a naphthalene moiety.
Claim 8
Dependent Claim
55 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase includes not less than about 10 mole percent of recurring units which include a naphthalene moiety selected from the group consisting of 6-oxy2-naphthoyl moiety, 2,6-dioxynaphthalene moiety, and 2,6-dicarboxynaphthalene moiety.
Claim 9
Dependent Claim
120 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a wholly aromatic polyester and consists essentially of moieties I and II which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR6## with said optional substitution if present being selected from the group consisting of an alkyl group to 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein said wholly aromatic polyester comprises approximately 10 to 90 mole percent of moiety I and approximately 10 to 90 mole percent of moiety II.
Claim 10
Dependent Claim
52 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a wholly aromatic polyester which consists essentially of approximately 27 mole percent of recurring 6-oxy-2-naphthoyl moieties and approximately 73 mole percent of recurring 4-oxybenzoyl moieties.
Claim 11
Dependent Claim
199 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a poly(ester-amide) and consists essentially of moieties I, II, III, and optionally IV, wherein: ##STR7## where A is a divalent radical comprising at least one aromatic ring or a divalent trans-1,4-cyclohexylene radical; III is--Y--Ar--Z--where Ar is a divalent radical comprising at least one aromatic ring, Y is 0, NH or NR, and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms; and IV is--O--Ar'--O--where Ar' is a divalent radical comprising at least one aromatic ring; wherein at least some of the hydrogen atoms present upon the rings optionally may be replaced by substitution selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, phenyl, and mixtures thereof, and wherein said poly(ester-amide) comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, approximately 5 to 45 mole percent of moiety III, and approximately 0 to 40 mole percent of moiety IV.
Claim 12
Dependent Claim
59 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said polymer which exhibits an anisotropic melt phase is a poly- (ester-amide) which consists essentially of approximately 60 mole percent of recurring 6-oxy-2-naphthoyl moieties, approximately 20 mole percent of recurring terephthaloyl moieties, and approximately 20 mole percent of recurring 4-oxyaminophenylene moieties.
Claim 13
Dependent Claim
34 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said converging die utilized in step (b) has a convergence ratio of approximately 2:1 to 20:1.
Claim 14
Dependent Claim
25 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 12 wherein said converging die is conical in configuration.
Claim 15
Dependent Claim
33 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said extrudate in step (c) is subjected to a drawdown of approximately 3:1 to 5:1.
Claim 16
Dependent Claim
32 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said solid elongated extrudate has a circular cross-section of approximately 30 to 120 mils.
Claim 17
Dependent Claim
32 words
A process of melt-extrusion for the formation of a solid elongated shaped article according to claim 1 wherein said solid elongated extrudate has a circular cross-section of approximately 70 to 75 mils.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-29 | 1991-09-28 | 1992-03-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-29 | 1995-09-28 | 1996-03-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-29 | 1999-09-28 | 2000-03-29 | $7700.00 | Window Closed / Lapsed |