Patent US4139262A successfully refreshed from Google Patents.
Patent US5154760A successfully refreshed from Google Patents.
US5154760A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyamide resin compositions for use as laminating ink resin binders
Assignee: Wilmington Trust FSB
•
Filing: 1990-11-27
•
Granted: 1992-10-13
•
Expires: 2010-11-27
Abstract
Abstract A polyamide resin composition for use as laminating ink resin binder is provided by the condensation reaction product of dimerized fatty acids having 36 carbon atoms, at least one dibasic acid, at least one C 1 -C 4 alkyl diamine and at least one piperazine-like diamine. The equivalents of amine groups in the composition are substantially equal to the equivalents of carboxyl groups, where 30 to 50 equivalent perecent of the carboxyl groups are contributed by the dibasic acid component and 73 to 93 equivalent percent of the amine groups are contributed by the piperazine-like diamine component. Printing inks with the polyamide resin composition of this invention are also provided.
Inventors
- 👤 George E. Miller, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:13
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/102; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/34
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
118 words
A polyamide resin composition for use as laminating ink resin binder which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 35 to 45 equivalent percent of the carboxyl groups are contributed by the dibasic acid component, 55 to 65 equivalent percent of the carboxyl groups are contributed by the dimerized fatty acid component and 78 to 88 equivalent percent of the amine groups are contributed by the piperazine-like diamine component.
Claim 2
Dependent Claim
118 words
A polyamide resin composition for use as laminating ink resin binder which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 35 to 45 equivalent percent of the carboxyl groups are contributed by the dibasic acid component, 55 to 65 equivalent percent of the carboxyl groups are contributed by the dimerized fatty acid component and 78 to 88 equivalent percent of the amine groups are contributed by the piperazine-like diamine component.
Claim 3
Dependent Claim
14 words
The polyamide resin composition according to claim 1 the dibasic acid is azelaic acid.
Claim 4
Dependent Claim
14 words
The polyamide resin composition according to claim 1 wherein the piperazine-like diamine is piperazine.
Claim 5
Dependent Claim
19 words
The polyamide resin composition according to claim 1 wherein the C 1 to C 4 alkyl diamine is ethylenediamine.
Claim 6
Dependent Claim
63 words
A polyamide resin composition for use as laminating ink resin binder which comprises the condensation reaction product of: (a) about 60 equivalent percent of a C 36 dimerized fatty acid; (b) about 40 equivalent percent azelaic acid; (c) ethylenediamine in an amount sufficient to provide about 2 to about 6 equivalent percent excess of amine groups; and (d) about 83 equivalent percent piperazine.
Claim 7
Dependent Claim
63 words
A polyamide resin composition for use as laminating ink resin binder which comprises the condensation reaction product of: (a) about 60 equivalent percent of a C 36 dimerized fatty acid; (b) about 40 equivalent percent azelaic acid; (c) ethylenediamine in an amount sufficient to provide about 2 to about 6 equivalent percent excess of amine groups; and (d) about 83 equivalent percent piperazine.
Claim 8
Dependent Claim
131 words
A printing ink comprising: (a) a C 2 -C 4 aliphatic alcohol solvent, (b) a polyamide resin composition which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 30 to 50 equivalent percent of the carboxyl groups are contributed by the dibasic acid component and 73 to 93 equivalent percent of the amine groups are contributed by the piperazine-like diamine component, and (c) a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
Claim 9
Dependent Claim
131 words
A printing ink comprising: (a) a C 2 -C 4 aliphatic alcohol solvent, (b) a polyamide resin composition which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 30 to 50 equivalent percent of the carboxyl groups are contributed by the dibasic acid component and 73 to 93 equivalent percent of the amine groups are contributed by the piperazine-like diamine component, and (c) a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
Claim 10
Dependent Claim
14 words
The printing ink according to claim 6 wherein the dibasic acid is azelaic acid.
Claim 11
Dependent Claim
13 words
The printing ink according to claim 6 wherein the piperazine-like diamine is piperazine.
Claim 12
Dependent Claim
18 words
The printing ink according to claim 6 wherein the C 1 to C 4 alkyl diamine is ethylenediamine.
Claim 13
Dependent Claim
140 words
A printing ink comprising: an alcohol solvent, a polyamide resin composition which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 35 to 45 equivalent percent of the carboxyl groups are contributed by the dibasic acid component, 55 to 65 equivalent percent of the carboxyl groups are contributed by the dimerized fatty acid component and 78 to 88 equivalent percent of the amine groups are contributed by the piperazine-like diamine component, and a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
Claim 14
Dependent Claim
140 words
A printing ink comprising: an alcohol solvent, a polyamide resin composition which comprises the condensation reaction product of: (a) a C 36 dimerized fatty acid; (b) at least one C 6 to C 10 dibasic acid; (c) at least one C 1 -C 4 alkyl diamine; and (d) at least one piperazine-like diamine; the equivalents of amine groups being substantially equal to the equivalents of carboxyl groups, where 35 to 45 equivalent percent of the carboxyl groups are contributed by the dibasic acid component, 55 to 65 equivalent percent of the carboxyl groups are contributed by the dimerized fatty acid component and 78 to 88 equivalent percent of the amine groups are contributed by the piperazine-like diamine component, and a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
Claim 15
Dependent Claim
14 words
The printing ink according to claim 10 wherein the dibasic acid is azelaic acid.
Claim 16
Dependent Claim
13 words
The printing ink according to claim 10 wherein the piperazine-like diamine is piperazine.
Claim 17
Dependent Claim
18 words
The printing ink according to claim 10 wherein the C 1 to C 4 alkyl diamine is ethylenediamine.
Claim 18
Dependent Claim
22 words
The printing ink according to claim 10 wherein the alcohol solvent is comprised primarily of a C 2 -C 4 aliphatic alcohol;
Claim 19
Dependent Claim
90 words
A printing ink comprising: a C 2 -C 4 aliphatic alcohol solvent, a polyamide resin composition which comprises the condensation reaction product of: (a) about 60 equivalent percent of a C 36 dimerized fatty acid; (b) about 40 equivalent percent azelaic acid; (c) ethylenediamine in an amount sufficient to provide about 2 to about 6 equivalent percent excess of amine groups; and (d) about 83 equivalent percent piperazine, and a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
Claim 20
Dependent Claim
90 words
A printing ink comprising: a C 2 -C 4 aliphatic alcohol solvent, a polyamide resin composition which comprises the condensation reaction product of: (a) about 60 equivalent percent of a C 36 dimerized fatty acid; (b) about 40 equivalent percent azelaic acid; (c) ethylenediamine in an amount sufficient to provide about 2 to about 6 equivalent percent excess of amine groups; and (d) about 83 equivalent percent piperazine, and a colorant distributed through the printing ink in an effective amount sufficient to impart a color to the resulting printing ink.
References Cited (Backward Citations)
US2149286A
Cited
US4066585A
Cited
US4243702A
Cited
US4514540A
Cited
EP0171850A1
Cited
US5026755A
Cited
US4921932A
Cited
US5025043A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-10-13 | 1996-04-13 | 1996-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-10-13 | 2000-04-13 | 2000-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-10-13 | 2004-04-13 | 2004-10-13 | $7700.00 | Window Closed / Lapsed |