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P-type II-VI compound semiconductor doped

Assignee: Toshiba Corp
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Filing: 1990-11-21
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Granted: 1992-09-22
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Expires: 2010-11-21
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Abstract

Abstract An optical semiconductor device is provided with a p-type ZnSe semiconductor layer. Si, Cl and O atoms are added, as dopants, to the ZnSe semiconductor layer. Associations of the Si, Cl and O atoms are formed to define a shallow acceptor level in the semiconductor layer. Each of the associations comprises one Si atom, one Cl atom and one O atom by which the lattice points of Se are displaced between those crystal lattice points in the semiconductor layer which are adjacent to one another.

Inventors

  • 👤 Nawoto Motegi
  • 👤 Tsutomu Uemoto
  • 👤 Atsushi Kamata
  • 👤 Hiroshi Mitsuhashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 13:39
CPC Classifications
H; H10; H10H; H10H20/00; H10H20/80; H10H20/81; H10H20/822; H10H20/823; H10H20/8232; H10D; H10D62/00; H10D62/80; H10D62/86; H10D62/864; H10F; H10F77/00; H10F77/10; H10F77/12; H10F77/123; H10F77/1233; H10H20/01; H10H20/011; H10H20/012; H10H20/0125; H10P; H10P14/00; H10P14/20; H10P14/24; H10P14/29; H10P14/2901; H10P14/2907; H10P14/2911; H10P14/2913; H10P14/2916; H10P14/32; H10P14/3202; H10P14/3224; H10P14/3231; H10P14/34; H10P14/3402; H10P14/3424; H10P14/3428; H10P14/3431; H10P14/3438; H10P14/3441; H10P14/3442; H10P14/3444

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 97 words
An optical semiconductor device provided with a p-type group II-VI compound semiconductor layer wherein dopants selected from group VII atoms, atoms of groups III and IV, and atoms of groups IV and VII are added and associations are formed so that shallow acceptor level can be defined, each of the associations is selected from the group IV atom and the group III atom, the group IV atom and group VII atom, and the group VII atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 2
Dependent Claim 97 words
An optical semiconductor device provided with a p-type group II-VI compound semiconductor layer wherein dopants selected from group VII atoms, atoms of groups III and IV, and atoms of groups IV and VII are added and associations are formed so that shallow acceptor level can be defined, each of the associations is selected from the group IV atom and the group III atom, the group IV atom and group VII atom, and the group VII atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 3
Dependent Claim 25 words
The optical semiconductor device according to claim 1, wherein the density of each of the doped atoms is larger than 1×10 17 cm -3 .
Claim 4
Dependent Claim 57 words
The optical semiconductor device according to claim 1, wherein the dopants are selected from atoms of the groups III and IV and atoms of the groups IV and VII and the density of the group IV atom in the semiconductor layer is substantially equal to or larger than that of the group III or VII atom therein.
Claim 5
Dependent Claim 21 words
The optical semiconductor device according to claim 1, wherein the semiconductor layer consists of ZnSe or a mixed crystal of ZnSe.
Claim 6
Dependent Claim 58 words
The optical semiconductor device according to claim 4, wherein B and C atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the B atom by which the lattice point of Zn is displaced and the C atom by which the lattice point of Se is displaced.
Claim 7
Dependent Claim 47 words
The optical semiconductor device according to claim 4, wherein Si and Cl atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the Si and Cl atoms by which the lattice points of Se are displaced.
Claim 8
Dependent Claim 49 words
The optical semiconductor device according to claim 4, wherein the Cl atom is added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the Cl atom by which the lattice point of Se is displaced and the vacancy of Zn.
Claim 9
Dependent Claim 131 words
An optical semiconductor device provided with a p-type group II-VI compound semiconductor layer wherein dopants selected from group III and oxygen atoms, group VII and oxygen atoms, atoms of the groups III and IV and oxygen atoms, and atoms of the groups IV and VII and oxygen atom are added and associations are formed so that a shallow acceptor level can be defined, each of the associations is selected from the group IV atom, group III and oxygen atom, the group IV atom, group VII atom and oxygen atom, the group III atom, oxygen atom and a vacancy of a group II atom, and the group VII atom, oxygen atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 10
Dependent Claim 131 words
An optical semiconductor device provided with a p-type group II-VI compound semiconductor layer wherein dopants selected from group III and oxygen atoms, group VII and oxygen atoms, atoms of the groups III and IV and oxygen atoms, and atoms of the groups IV and VII and oxygen atom are added and associations are formed so that a shallow acceptor level can be defined, each of the associations is selected from the group IV atom, group III and oxygen atom, the group IV atom, group VII atom and oxygen atom, the group III atom, oxygen atom and a vacancy of a group II atom, and the group VII atom, oxygen atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 11
Dependent Claim 25 words
The optical semiconductor device according to claim 8, wherein the density of each of the doped atoms is larger than 1×10 17 cm -3 .
Claim 12
Dependent Claim 62 words
The optical semiconductor device according to claim 8, wherein the dopants are selected from atoms of the groups III and IV and oxygen atom and atoms of the groups IV and VII and oxygen atom, and the density of the group IV atom in the semiconductor layer is substantially equal to or larger than that of the group III or VII atom.
Claim 13
Dependent Claim 21 words
The optical semiconductor device according to claim 8, wherein the semiconductor layer consists of ZnSe or a mixed crystal of ZnSe.
Claim 14
Dependent Claim 71 words
The optical semiconductor device according to claim 11, wherein B, C and O atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the B atom by which the lattice point of Zn is displaced, the C atom by which the lattice point of Se is displaced and the O atom by which the lattice point of Se is displaced.
Claim 15
Dependent Claim 49 words
The optical semiconductor device according to claim 11, wherein Si, Cl and O atoms are added to the semiconductor layer and the acceptor level in the semi-conductor layer is defined by the association of the Si, Cl and O atoms by which the lattice points of Se are displaced.
Claim 16
Dependent Claim 62 words
The optical semiconductor device according to claim 11, wherein Ga and O atoms are added to the semi-conductor layer and the acceptor level in the semiconductor layer is defined by the association of the Ga atom by which the lattice point of Zn is displaced, the vacancy of Zn and the O atom by which the lattice point of Se is displaced.
Claim 17
Dependent Claim 62 words
The optical semiconductor device according to claim 11, wherein Cl and O atoms are added to the semi-conductor layer and the acceptor level in the semiconductor layer is defined by the association of the Cl atom by which the lattice point of Se is displaced, the vacancy of Zn and the O atom by which the lattice point of Se is displaced.
Claim 18
Dependent Claim 139 words
An optical semiconductor device provided with a p-type compound semiconductor layer of ZnSe or of a mixed crystal of ZnSe wherein dopants selected from group III and oxygen atoms, group VII and oxygen atoms, atoms of the groups III and IV and oxygen atoms, and atoms of the groups IV and VII and oxygen atom are added and associations are formed so that a shallow acceptor level can be defined, each of the associations is selected from the group IV atom, group III atom and oxygen atom, the group IV atom, group VII atom and oxygen atom, the group III atom, oxygen atom and a vacancy of a group II atom, and the group VII atom, oxygen atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 19
Dependent Claim 139 words
An optical semiconductor device provided with a p-type compound semiconductor layer of ZnSe or of a mixed crystal of ZnSe wherein dopants selected from group III and oxygen atoms, group VII and oxygen atoms, atoms of the groups III and IV and oxygen atoms, and atoms of the groups IV and VII and oxygen atom are added and associations are formed so that a shallow acceptor level can be defined, each of the associations is selected from the group IV atom, group III atom and oxygen atom, the group IV atom, group VII atom and oxygen atom, the group III atom, oxygen atom and a vacancy of a group II atom, and the group VII atom, oxygen atom and a vacancy of a group II atom, and is formed between those lattice points which are adjacent to each other.
Claim 20
Dependent Claim 71 words
The optical semiconductor device according to claim 16, wherein B, C and O atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the B atom by which the lattice point of Zn is displaced, the C atom by which the lattice point of Se is displaced and the O atom by which the lattice point of Se is displaced.
Claim 21
Dependent Claim 49 words
The optical semiconductor device according to claim 16, wherein Si, Cl and O atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the Si, Cl and O atoms by which the lattice points of Se are displaced.
Claim 22
Dependent Claim 62 words
The optical semiconductor device according to claim 16, wherein Ga and O atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the Ga atom by which the lattice point of Zn is displaced, the vacancy of Zn and the O atom by which the lattice point of Se is displaced.
Claim 23
Dependent Claim 62 words
The optical semiconductor device according to claim 16, wherein Cl and O atoms are added to the semiconductor layer and the acceptor level in the semiconductor layer is defined by the association of the Cl atom by which the lattice point of Se is displaced, the vacancy of Zn and the O atom by which the lattice point of Se is displaced.

References Cited (Backward Citations)

US3549434A Cited
US3578507A Cited
US3670220A Cited
US4868615A Cited
US4904618A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-09-22 1996-03-23 1996-09-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-09-22 2000-03-23 2000-09-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-09-22 2004-03-23 2004-09-22 $7700.00 Window Closed / Lapsed

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