Stabilized, aqueous hydrazide solutions for photographic elements

Claim 2

A process for the stabilization of an aqueous solution of an aryl hydrazide of the general formula: Ar--NR--NR.sub.1 --G--X.sup.+ A- wherein: Ar is a substituted phenyl group or another substituted or unsubstituted aryl group; G is CO, SO, SO 2 , PO 2 , PO 3 , and C═NR 2 ; X + is a radical containing a cationic group; R, R 1 , R 2 , which can be the same or different, are hydrogen, alkyl of 1-6 carbon atoms, and alkyl sulfinyl of 1-6 carbon atoms; and A - ) is an anion, the improvement comprising adding to said aqueous solution a stabilizing amount of a stabilizer/antioxidant selected from the group consisting of ascorbic acid, an ascorbic acid isomer, tartaric acid, citric acid, glucose, α-cyclodextrin, β-cyclodextrin and gamma-cyclodextrin, and mixtures thereof.

Claim 3

A process according to claim 1 wherein said aryl hydrazide has the following structure: ##STR3## wherein R 1 to R 5 , which can be the same or different, are hydrogen, alkyl, alkoxy, hydroxyalkyl, haloalkyl, alkylamino, aliphatic acylamino or cycloalkyl, each with 1-20 carbon atoms; aryl, aryloxy or aromatic acylamino, each with 6-10 carbon atoms in the alkylene chain; or an aliphatic acylamino radical with 1-4 carbon atoms substituted by a phenoxy radical which may be substituted by one or more alkyl radicals with 1-10 carbon atoms, with the proviso that at least one of R 1 to R 5 is not hydrogen, Q + is a trialkyl ammonium, pyridinium-1-yl, N-alkyl-pyridinium-m-yl where m is a whole number of 2,3 or 4, thiazolinium-3-yl or N-alkylthiazolinium-m-yl where m is 2,4 or 5, in which the heterocyclic rings may be substituted by additional alkyl radicals, and in which all alkyl groups of a radical Q + may be the same or different and/or may be substituted by a hydroxyl or sulfonic acid group, each alkyl group having no more than 12 carbon atoms, but in the case of trialkylammonium, two of them may also form with the quaternary nitrogen, a ring with 3-4 members, B is a bridge when may be composed of 1-3 methylene groups, each of which may be substituted by methyl or ethyl, or if Q + is N-alkylpyridinium-m-yl or N-alkylthiazolinium-m-yl, may also be an oxygen atom or a single bond, and, A - denotes an anion which is not present when Q + contains a sulfo group.

Claim 4

A process according to claim 1 wherein said aryl hydrazide has the following structure: ##STR4##

Claim 5

A process according to claim 3 wherein said stabilizer/antioxidant is present in an amount from 0.01 to 10.0 percent by weight.

Claim 6

A process according to claim 4 wherein said stabilizer/antioxidant is a mixture of L-ascorbic acid and β-cyclodextrin.

Claim 7

A process according to claim 1 wherein an isomer of ascorbic acid is isoascorbic acid or erythorbic acid.

Claim 8

A photographic, silver halide emulsion stabilized with a solution according to claim 5.