Photographic silver halide elements containing aryl hydrazides

Claim 2

A photographic silver halide element containing an aryl hydrazide for the production of images with ultrahigh contrast comprising a support having thereon at least one silver halide emulsion layer, the emulsion layer or at least one other auxiliary layer in contact with a silver halide emulsion layer on said support contains aryl hydrazide of the general formula: Ar-NR-NR.sup.1 -G-X.sup.+ A.sup.- (I) wherein Ar is a substituted phenyl group or another substituted or unsubstituted aryl group, G is CO, SO, SO 2 , PO 2 , PO 3 and C═NR 2 X+ is a radical containing a cationic group, R, R 1 , R 2 , which can be the same or different, are hydrogen, alkyl of 1 to 6 carbon atoms and alkyl sulfinyl of 1 to 6 carbon atoms, and A - is an anion.

Claim 3

A photographic silver halide element according to claim 1 wherein the aryl hydrazide is of the formula: Ph-NR-NR.sup.1 -G-X.sup.+ A.sup.- (Ia) where Ph is a substituted phenyl group, G is CO, SO, SO 2 , PO 2 , PO 3 , or C═NR 2 , X + is a radical containing a cationic group, R, R 1 , R 2 , which can be the same or different, are hydrogen, alkyl, or alkylsulfinyl with 1 to 6 carbon atoms, and A - is an anion.

Claim 4

A photographic silver halide element according to claim 1 wherein the aryl hydrazide is of the formula: Ph-NR-NR.sup.1 -CO-X.sup.+ A.sup.- (Ib) where Ph is a substituted phenyl group, X + is a radical containing a cationic group, R, R 1 , which can be the same or different, are hydrogen, alkyl or alkylsulfinyl with 1 to 6 carbon atoms, and A - is an anion.

Claim 5

A photographic silver halide element according to claim 1 wherein the aryl hydrazide is of formula: Ph-NR-NR.sup.1 -G-Y.sup.+ A.sup.- (Ic) where Ph is a substituted phenyl group, G is CO, SO, SO 2 , PO 2 , PO 3 , or C═NR 2 , Y + is a radical containing a cationic group with at least one quarternated nitrogen atom, R, R 1 , R 2 which can be the same or different, are hydrogen, alkyl or alkylfulfinyl with 1 to 6 carbon atoms, and A - is an anion.

Claim 6

A photographic silver halide element according to claim 1 wherein the aryl hydrazide is present in the element in an amount of 10 -5 mole/mole of silver to 5×10 -2 mole/mole of silver.

Claim 7

A photographic silver halide element according to claim 1 wherein the aryl hydrazide is of the formula: ##STR5## wherein R 1 to R 5 , which can be the same or different, are hydrogen halogen alkyl, alkoxy, hydroxyalkyl, haloalkyl, alkylamino, aliphatic acylamino or cycloalkyl each with 1 to 20 carbon atoms, aryl, aryloxy or aromatic acylamino, each with 6 to 10 carbon atoms, aralkyl, or aralkoxy with 1 to 3 carbon atoms in the alkylene chain or an aliphatic acylamino radical with 1 to 4 carbon atoms substituted by a phenoxy radical which may be substituted by one or more alkyl radicals with 1 to 10 carbon atoms with the proviso that at least one of R 1 to R 5 is not hydrogen, Q + is trialkylammonium, pyridinium-1-yl, N-alkylpyridinium-m-yl where m is a whole number of 2, 3 or 4, thiazolinium-3-yl, or N-alkylthiazolinium-m-yl where m is 2, 4 or 5, in which the heterocyclic rings may be substituted by additional alkyl radicals, and in which all alkyl groups of a radical Q + may be the same or different and/or may be substituted by hydroxyl or sulfonic acid groups, each alkyl group having no more than 12 carbon atoms, but in the case of trialkylammonium, two of them may also form with the quaternary nitrogen a ring with 3 to 12 members, B is a bridge which may be composed of 1 to 3 methylene groups, each of which may be substituted by methyl or ethyl, or if Q + is N-alkylpyridinium-m-yl or N-alkylthiazolinium-m-yl, may also be an oxygen atom or a single bond, and A - denotes an anion which is not present when Q + contains a sulfo group.

Claim 8

A photographic silver halide element according to claim 6 wherein the aryl hydrazide is present in the element in an amount of 10 -5 mole/mole of silver to 5×10 31 2 mole/mole of silver.