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Synthetic dental compositions formed from cyclopolymerizable bis-acrylate and multi-functional oligomer and bonding method
Assignee: United States, COMMERCE THE, Secretary of
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Filing: 1989-10-03
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Granted: 1992-09-08
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Expires: 2009-10-03
Abstract
Abstract Synthetic dental compositions comprise an inorganic filler and a resin formed by polymerization of at least one bis-acrylate of the formula <IMAGE> (I) wherein R is selected from the group consisting of alkyl groups having 1 to 6 carbon atoms and aryl substituted alkyl groups in which the alkyl portion has 1 to 6 carbon atoms, or by polymerization of at least one multifunctional oligomer of the formula <IMAGE> (II) wherein X is the group <IMAGE> with R1 being H or CH2OH, and Y is a hydrocarbon group having about four to about twenty carbon atoms. Diacids or diacid salts of the hydrolyzed bis-acrylates are also useful in methods for bonding a variety of substrates to teeth.
Inventors
- 👤 Jeffrey W. Stansbury
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 19:57
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/30
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
59 words
A synthetic dental composition, comprising (a) a resin formed by polymerization of at least one bis-acrylate monomer of the formula ##STR15## wherein R is selected from the group consisting of alkyl groups having 1 to 6 carbon atoms and aryl substituted alkyl groups in which the alkyl portion has 1 to 6 carbon atoms; and (b) an inorganic filler.
Claim 2
Dependent Claim
59 words
A synthetic dental composition, comprising (a) a resin formed by polymerization of at least one bis-acrylate monomer of the formula ##STR15## wherein R is selected from the group consisting of alkyl groups having 1 to 6 carbon atoms and aryl substituted alkyl groups in which the alkyl portion has 1 to 6 carbon atoms; and (b) an inorganic filler.
Claim 3
Dependent Claim
39 words
A synthetic dental composition as defined by claim 1, wherein the resin is formed by polymerization of at least one bis-acrylate monomer of formula I wherein R is selected from the group consisting of methyl, ethyl, isobutyl and phenethyl.
Claim 4
Dependent Claim
29 words
A synthetic dental composition as defined by claim 1, wherein the resin is formed by polymerization of said at least one bis-acrylate monomer and at least one additional monomer.
Claim 5
Dependent Claim
26 words
A synthetic dental composition as defined by claim 3, wherein said at least one additional monomer is selected from the group consisting of acrylates and methacrylates.
Claim 6
Dependent Claim
31 words
A synthetic dental composition as defined by claim 4, wherein said at least one additional monomer is selected from the group consisting of 2,2-bis[4-(2-hydroxy-3-methacroyloxy propoxy) phenyl] propane and triethylene glycol dimethacrylate.
Claim 7
Dependent Claim
18 words
A synthetic dental composition as defined by claim 1, wherein the resin is formed by bulk polymerization techniques.
Claim 8
Dependent Claim
33 words
A synthetic dental composition as defined by claim 1, comprising from about 10 to about 90 weight percent of the resin and from about 90 to about 10 weight percent of the filler.
Claim 9
Dependent Claim
60 words
A synthetic dental composition, comprising (a) a resin formed by polymerization of at least one multifunctional oligomer of the formula ##STR16## wherein X is the group ##STR17## with being selected from the group consisting of H and CH 2 OH, and Y is a hydrocarbon group having from about four to about twenty carbon atoms; and (b) an inorganic filler.
Claim 10
Dependent Claim
60 words
A synthetic dental composition, comprising (a) a resin formed by polymerization of at least one multifunctional oligomer of the formula ##STR16## wherein X is the group ##STR17## with being selected from the group consisting of H and CH 2 OH, and Y is a hydrocarbon group having from about four to about twenty carbon atoms; and (b) an inorganic filler.
Claim 11
Dependent Claim
31 words
A synthetic dental composition as defined by claim 8, wherein Y is a group selected from alkylene groups of from about 4 to about 10 carbon atoms and the group ##STR18##
Claim 12
Dependent Claim
29 words
A synthetic dental composition as defined by claim 8, wherein the resin is formed by polymerization of said at least one multifunctional oligomer and at least one additional monomer.
Claim 13
Dependent Claim
26 words
A synthetic dental composition as defined by claim 9, wherein said at least one additional monomer is selected from the group consisting of acrylates and methacrylates.
Claim 14
Dependent Claim
20 words
A synthetic dental composition as defined by claim 11, wherein said at least one additional monomer is triethylene glycol dimethacrylate.
Claim 15
Dependent Claim
33 words
A synthetic dental composition as defined by claim 8, comprising from about 10 to about 90 weight percent of the resin and from about 90 to about 10 weight percent of the filler.
Claim 16
Independent Claim
53 words
A method for adhesively bonding a substrate to a tooth, comprising applying an adhesive composition between the substrate and the tooth, said adhesive composition being formed by the hydrolysis of a bis-acrylate monomer yielding a dicarboxylic acid or a dicarboxylate salt of the formula ##STR19## wherein R is H or a metal cation.
Claim 17
Independent Claim
53 words
A method for adhesively bonding a substrate to a tooth, comprising applying an adhesive composition between the substrate and the tooth, said adhesive composition being formed by the hydrolysis of a bis-acrylate monomer yielding a dicarboxylic acid or a dicarboxylate salt of the formula ##STR19## wherein R is H or a metal cation.
Claim 18
Dependent Claim
20 words
A method as defined by claim 14, wherein said adhesive composition further is formed from at least one additional monomer.
Claim 19
Dependent Claim
26 words
A synthetic dental composition as defined by claim 15, wherein said at least one additional monomer is selected from the group consisting of acrylates and methacrylates.
Claim 20
Dependent Claim
31 words
A synthetic dental composition as defined by claim 16, wherein said at least one additional monomer is selected from the group consisting of 2,2-bis[4-(2-hydroxy-3-methacroyloxy propoxy) phenyl] propane and triethylene glycol dimethacrylate.
Claim 21
Dependent Claim
16 words
A method as defined by claim 14, wherein said adhesive composition further comprises an inorganic filler.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1995-09-08 | 1996-03-09 | 1996-09-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-09-08 | 2000-03-09 | 2000-09-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-09-08 | 2004-03-09 | 2004-09-08 | $7700.00 | Window Closed / Lapsed |