Soluble magnesium hydrides, method of preparing them, and use thereof
Abstract
Abstract Organic-solvent soluble magnesium hydrides of the formulas (MgH.sub.2).sub.n. MgQ.sub.2 (II) (MgH.sub.2).sub.n. RMgX (III) ##STR1## are prepared by catalytically hydrogenating finely powdered magnesium, optionally in the presence of a magnesium halide, in an organic solvent in the presence of their MgH 2 -free counterparts in which Q is an alkyl, alkenyl, alkoxy, dialkylamino, aralkyl, aryl or diarylamino group, each with up to 18 carbon atoms, R is an alkenyl, aralkyl or aryl group, each with up to 18 carbon atoms, X is chlorine, bromine, or iodine, --E D→ is a chelating ligand, E is --CH 2 , --N(R)-- or --O--, is an alkylene radical of the formula --(CH 2 ) p , D is a dialkylamino, diarylamino or alkoxy group, each with up to 19 carbon atoms, M is aluminum or boron, m is 1, 2, or 3, and 1<n≦50.
Inventors
- 👤 Borislav Bogdanovic
- 👤 Manfred Schwickardi
Bibliographic Details
Claims Analysis
Total Claims: 4References Cited (Backward Citations)
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