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US5139901A
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Lithium secondary battery using hydric boron carbonitride as electrode material
Assignee: Central Glass Co Ltd
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Filing: 1990-11-26
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Granted: 1992-08-18
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Expires: 2010-11-26
Abstract
Abstract The invention provides a lithium secondary battery using hydric boron carbonitride which is a layered compound represented by BC x N y H z , where 0.5≦x≦12, 0.7≦y≦1.5, and 0.01≦z≦3, as the active material of the negative electrode. This compound is obtained by a CVD process. The electrolyte is a solution of a lithium salt in an organic solvent. The material of the positive electrode is an oxide such as MnO 2 or V 2 O 5 , a sulfide such as MoS 2 or TiS 2 or a conductive organic polymer such as polyaniline. In this secondary battery Li is smoothly intercalated in and released from the hydric boron carbonitride of the negative electrode, and the energy density with respect to the active material of the negative electrode is sufficiently high. This battery bears a fairly large number of charge-discharge cycles. Also it is possible to use hydric boron carbonitride as the active material of the positive electrode of a lithium secondary battery in combination with negative electrode of metallic Li or hydric boron carbonitride with intercalation of a larger amount of Li.
Inventors
- 👤 Masayuki Kawaguchi
- 👤 Koji Nozaki
- 👤 Yasushi Kita
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 10:24
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/583; H01M4/587; H01M10/00; H01M10/05; H01M10/052; H01M10/0525; H01M4/581; H01M4/5815; H01M4/13; H01M4/60; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
130 words
A lithium secondary battery comprising: a casing; an electrolyte confined in said casing, the electrolyte being a solution of a lithium salt in an organic polar solvent; a negative electrode which is held in said casing so as to be in contact with said electrolyte and comprises a compound represented by the general formula BC x N y H z , 0.5≦x≦12, 0.7≦y≦1.5, and 0.01≦z≦3, as an active material in which Li is reversibly intercalated; a positive electrode which is held in said casing so as to be in contact with said electrode and made of a material stable to charging and discharging reactions in which lithium ion participates; and an insulating separator which is permeable to said electrolyte and is disposed between said negative electrode and said positive electrode.
Claim 2
Dependent Claim
130 words
A lithium secondary battery comprising: a casing; an electrolyte confined in said casing, the electrolyte being a solution of a lithium salt in an organic polar solvent; a negative electrode which is held in said casing so as to be in contact with said electrolyte and comprises a compound represented by the general formula BC x N y H z , 0.5≦x≦12, 0.7≦y≦1.5, and 0.01≦z≦3, as an active material in which Li is reversibly intercalated; a positive electrode which is held in said casing so as to be in contact with said electrode and made of a material stable to charging and discharging reactions in which lithium ion participates; and an insulating separator which is permeable to said electrolyte and is disposed between said negative electrode and said positive electrode.
Claim 3
Dependent Claim
16 words
A battery according to claim 1, wherein said negative electrode is substantially made of said compound.
Claim 4
Dependent Claim
22 words
A battery according to claim 1, wherein said negative electrode is made of a mixture of said compound and an organic binder.
Claim 5
Dependent Claim
15 words
A battery according to claim 1, wherein said positive electrode is made of an oxide.
Claim 6
Dependent Claim
34 words
A battery according to claim 4, wherein said oxide is selected from the group consisting of MnO 2 , V 2 O 5 and a compound oxide of γ-β-MnO 2 and LiMnO 2 .
Claim 7
Dependent Claim
27 words
A battery according to claim 1, wherein said positive electrode is made of a sulfide selected from the group consisting of MoS 2 and TiS 2 .
Claim 8
Dependent Claim
18 words
A battery according to claim 1, wherein said positive electrode is made of an electrically conductive organic polymer.
Claim 9
Dependent Claim
12 words
A battery according to claim 7, wherein said organic polymer is polyaniline.
Claim 10
Dependent Claim
31 words
A battery according to claim 1, wherein said lithium salt is selected from the group consisting of LiClO 4 , LiPF 6 , LiPF 4 and CF 3 SO 3 Li.
Claim 11
Dependent Claim
14 words
A battery according to claim 1, wherein said separator is impregnated with said electrolyte.
Claim 12
Dependent Claim
17 words
A battery according to claim 10, wherein said separator is a cloth of an organic polymer fiber.
Claim 13
Dependent Claim
121 words
A lithium secondary battery comprising: a casing; an electrolyte confined in said casing, the electrolyte being a solution of a lithium salt in an organic polar solvent; a positive electrode which is held in said casing so as to be in contact with said electrolyte and comprises a compound represented by the general formula BC x N y H z , where 0.5≦x≦12, 0.7≦y≦1.5, and 0.01≦z≦3, as an active material in which Li is reversibly intercalated; a negative electrode which is held in said casing so as to be in contact with said electrode and made of a material comprising Li; an insulating separator which is permeable to said electrolyte and is disposed between said negative electrode and said positive electrode.
Claim 14
Dependent Claim
121 words
A lithium secondary battery comprising: a casing; an electrolyte confined in said casing, the electrolyte being a solution of a lithium salt in an organic polar solvent; a positive electrode which is held in said casing so as to be in contact with said electrolyte and comprises a compound represented by the general formula BC x N y H z , where 0.5≦x≦12, 0.7≦y≦1.5, and 0.01≦z≦3, as an active material in which Li is reversibly intercalated; a negative electrode which is held in said casing so as to be in contact with said electrode and made of a material comprising Li; an insulating separator which is permeable to said electrolyte and is disposed between said negative electrode and said positive electrode.
Claim 15
Dependent Claim
15 words
A battery according to claim 12, wherein said negative electrode is made of metallic lithium.
Claim 16
Dependent Claim
49 words
A battery according to claim 12, wherein said negative electrode comprises a compound represented by said general formula on condition that a larger amount of Li is intercalated in the compound BC x N y H z of said positive electrode than in said compound of said negative electrode.
Claim 17
Independent Claim
81 words
A method of producing an electrode for a lithium secondary battery, the method comprising the steps of: reacting a gas mixture comprising BCl 3 gas and CH 3 CN gas at a temperature not lower than 500° C. thereby depositing a compound represented by the general formula BC x N y H z , where 0.5≦x12, 0.7≦y≦1.5, and 0.01≦z≦3; shaping said compound into at least a portion of an electrode body; and intercalating Li into said compound in said electrode body.
Claim 18
Independent Claim
81 words
A method of producing an electrode for a lithium secondary battery, the method comprising the steps of: reacting a gas mixture comprising BCl 3 gas and CH 3 CN gas at a temperature not lower than 500° C. thereby depositing a compound represented by the general formula BC x N y H z , where 0.5≦x12, 0.7≦y≦1.5, and 0.01≦z≦3; shaping said compound into at least a portion of an electrode body; and intercalating Li into said compound in said electrode body.
References Cited (Backward Citations)
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