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Magnetic developer, comprising spherical particles magnetic

Assignee: Canon Inc
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Filing: 1990-04-25
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Granted: 1992-08-11
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Expires: 2010-04-25
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Abstract

Abstract A magnetic developer for developing an electrostatic latent image, including hydrophobic silica fine powder and an insulating magnetic toner comprising at least a binder resin and a magnetic material comprising spherical magnetic particles; wherein 0.16 to 1.6 wt. parts of the hydrophobic silica fine powder is mixed with 100 wt. parts of the insulating magnetic toner; the developer contains 17-60% by number of magnetic toner particles having a particles size of 5 microns of smaller, 5-50% by number of magnetic toner particles having a particle size of 6.35-10.08 microns, and 2.0% by volume or less of magnetic toner particles having a particle size of 12.7 microns or larger.

Inventors

  • 👤 Tsuyoshi Takiguchi
  • 👤 Tetsuya Kuribayashi
  • 👤 Koichi Tomiyama
  • 👤 Tsutomu Kukimoto
  • 👤 Hiroshi Yusa
  • 👤 Eiichi Imai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 09:03
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/0821; G03G13/00; G03G13/06; G03G13/08; G03G13/09; G03G9/0819; G03G9/0823; G03G9/083; G03G9/0837; G03G9/0838; G03G9/097; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/104

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 302 words
A magnetic developer for developing electrostatic latent images, comprising hydrophobic silica fine powder and an insulating magnetic toner comprising at least a binder resin and a magnetic material; wherein 0.6 to 1.6 wt. parts of the hydrophobic silica fine powder is mixed with 100 wt. parts of the insulating magnetic toner; said magnetic developer having a BET specific surface area of 1.8 to 3.5 m 2 /g, a triboelectric chargeability of -20 to -35 μC/g, an aerated bulk density of 0.40 to 0.52 g/cm 3 , and a true density of 1.45 to 1.8 g/cm 3 ; said magnetic material having an average particle size of 0.1 to 0.35 micron and comprising at least 50% by number of spherical magnetic particles whose surfaces substantially comprise curved surfaces; said insulating magnetic toner containing 70-120 wt. parts of spherical magnetic particles with respect to 100 wt. parts of the binder resin; said developer containing 17-60% by number of magnetic toner particles having a particle size of no greater than 5 microns, containing 5-50% by number of magnetic toner particles having a particle size of 6.35-10.08 microns, and containing no greater than 2.0% by volume of magnetic toner particles having a particle size of at least 12.7 microns; wherein the magnetic toner has a volume-average particle size of 6-8 microns, and the magnetic toner particles having a particle size of no greater than 5 microns have a particle size distribution satisfying the following formula: N/V=-0.05N+k, wherein N is the percentage by number of magnetic toner particles having a particle size of no greater than 5 micron, V is the percentage by volume of magnetic toner particles having a particle size of no greater than 5 microns, k is a positive number of 4.6 to 6.7, and N is a positive number of 17 to 60.
Claim 2
Dependent Claim 302 words
A magnetic developer for developing electrostatic latent images, comprising hydrophobic silica fine powder and an insulating magnetic toner comprising at least a binder resin and a magnetic material; wherein 0.6 to 1.6 wt. parts of the hydrophobic silica fine powder is mixed with 100 wt. parts of the insulating magnetic toner; said magnetic developer having a BET specific surface area of 1.8 to 3.5 m 2 /g, a triboelectric chargeability of -20 to -35 μC/g, an aerated bulk density of 0.40 to 0.52 g/cm 3 , and a true density of 1.45 to 1.8 g/cm 3 ; said magnetic material having an average particle size of 0.1 to 0.35 micron and comprising at least 50% by number of spherical magnetic particles whose surfaces substantially comprise curved surfaces; said insulating magnetic toner containing 70-120 wt. parts of spherical magnetic particles with respect to 100 wt. parts of the binder resin; said developer containing 17-60% by number of magnetic toner particles having a particle size of no greater than 5 microns, containing 5-50% by number of magnetic toner particles having a particle size of 6.35-10.08 microns, and containing no greater than 2.0% by volume of magnetic toner particles having a particle size of at least 12.7 microns; wherein the magnetic toner has a volume-average particle size of 6-8 microns, and the magnetic toner particles having a particle size of no greater than 5 microns have a particle size distribution satisfying the following formula: N/V=-0.05N+k, wherein N is the percentage by number of magnetic toner particles having a particle size of no greater than 5 micron, V is the percentage by volume of magnetic toner particles having a particle size of no greater than 5 microns, k is a positive number of 4.6 to 6.7, and N is a positive number of 17 to 60.
Claim 3
Dependent Claim 23 words
A developer according to claim 1, wherein the hydrophobic silica fine powder has been treated with a silicone oil or a silicone varnish.
Claim 4
Dependent Claim 20 words
A developer according to claim 1, wherein the hydrophobic silica fine powder has been treated with a silane coupling agent.
Claim 5
Dependent Claim 24 words
A developer according to claim 1, wherein the hydrophobic silica fine powder has been treated with a silane coupling agent and a silicone oil.
Claim 6
Dependent Claim 28 words
A developer according to claim 1, wherein the hydrophobic silica fine powder has been treated with a silicone oil having a viscosity of 50-1000 centistoke at 25° C.
Claim 7
Dependent Claim 45 words
A developer according to claim 1, wherein the insulating magnetic toner has an electric resistance of at least 10 14 ohm cm, a residual magnetization σ r of 1-5 emu/g, a saturation magnetization σ s of 15-50 emu/g, and a coercive force of 20-100 Oe.
Claim 8
Dependent Claim 20 words
A developer according to claim 1, wherein the insulating magnetic toner contains a crosslinked styrene copolymer as a binder resin.
Claim 9
Dependent Claim 19 words
A developer according to claim 1, wherein the insulating magnetic toner contains a crosslinked polyester as a binder resin.
Claim 10
Dependent Claim 32 words
A developer according to claim 1, wherein the hydrophobic silica fine powder is used in an amount of 0.7-1.4 wt. parts with respect to 100 wt. parts of the insulating magnetic toner.
Claim 11
Dependent Claim 43 words
A developer according to claim 1, wherein the hydrophobic silica fine powder has a BET specific surface area of 70-300 m 2 /g, a triboelectric chargeability of -100 to -300 μC/g, and a hydrophobicity of at least 90% with respect to ion-exchanged water.
Claim 12
Dependent Claim 18 words
A developer according to claim 1, which has a BET specific surface area of 1.9-3.0 m 2 /g.
Claim 13
Dependent Claim 31 words
A developer according to claim 1, which has a residual magnetization σ r of 2-4.5 emu/g, a saturation magnetization σ s of 20-40 emu/g, and a coercive force of 40-100 Oe.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-11 1996-02-10 1996-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-11 2000-02-10 2000-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-11 2004-02-10 2004-08-11 $7700.00 Window Closed / Lapsed

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