Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
180 words
Method of preparing a biologically degradable film composed of non-biologically degradable synthetic polymer and a biologically degradable polymer, which comprises subjecting particles of said biologically degradable polymer (biopolymer) in aqueous suspension to enzymes that split said biologically degradable polymer to small molecules which are released from the surface of the biopolymer particles and continuing the subjecting of said biologically degradable polymer to said enzymes until particles of predetermined small size are obtained, emulsifying the thus formed biopolymer particles of predetermined small size with a vegetable oil to coat the thus formed particles with the vegetable oil, thus isolating the enzyme from the water of the aqueous suspension and interrupting the degradation of the biopolymers by the enzymes, the enzymes remaining on the biopolymer particles, separating the thus vegetable oil-coated particles from the suspension, drying and then pulverizing the same, and mixing the thus obtained pulverized biopolymer particles with said synthetic polymer and forming a film therefrom in a film extruder, wherein the biopolymer degradation continues only after oxidation of the oil film which permits contact of the enzymes with moisture.
Claim 2
Dependent Claim
180 words
Method of preparing a biologically degradable film composed of non-biologically degradable synthetic polymer and a biologically degradable polymer, which comprises subjecting particles of said biologically degradable polymer (biopolymer) in aqueous suspension to enzymes that split said biologically degradable polymer to small molecules which are released from the surface of the biopolymer particles and continuing the subjecting of said biologically degradable polymer to said enzymes until particles of predetermined small size are obtained, emulsifying the thus formed biopolymer particles of predetermined small size with a vegetable oil to coat the thus formed particles with the vegetable oil, thus isolating the enzyme from the water of the aqueous suspension and interrupting the degradation of the biopolymers by the enzymes, the enzymes remaining on the biopolymer particles, separating the thus vegetable oil-coated particles from the suspension, drying and then pulverizing the same, and mixing the thus obtained pulverized biopolymer particles with said synthetic polymer and forming a film therefrom in a film extruder, wherein the biopolymer degradation continues only after oxidation of the oil film which permits contact of the enzymes with moisture.
Claim 3
Dependent Claim
12 words
Method according to claim 1 wherein said synthetic polymer is a polyolefin.
Claim 4
Dependent Claim
18 words
Method according to claim 1 wherein said biologically degradable polymer is starch, cellulose, rye flour or wheat flour.
Claim 5
Dependent Claim
12 words
Method according to claim 3 wherein said synthetic polymer is a polyolefin.
Claim 6
Dependent Claim
27 words
Method according to claim 1 wherein a catalyst which catalyzes oxidation of the oil is added to the biopolymer and synthetic polymer to form the film therefrom.
Claim 7
Dependent Claim
14 words
Method according to claim 5 wherein said catalyst is an oxidant for vegetable oils.
Claim 8
Dependent Claim
29 words
Method according to claim 1 wherein the pulverized biopolymer particles are granulated with a synthetic polymer film forming material and the formed granulate is then extruded into a film.
Claim 9
Dependent Claim
32 words
Method according to claim 7 wherein a catalyst which catalyzes oxidation of the oil is mixed with the synthetic film forming polymer before said film forming polymer is mixed with the biopolymer.
Claim 10
Dependent Claim
15 words
Method according to claim 1 wherein the predetermined particle size is between about 0.5-10 μm.
Claim 11
Dependent Claim
26 words
Method according to claim 7 wherein the amount of the biologically degradable polymer in the mixture thereof with the synthetic polymer is about 60-80% by weight.
Claim 12
Dependent Claim
15 words
Method according to claim 1 wherein the vegetable oil is soya, rape or sunflower oil.
Claim 13
Dependent Claim
50 words
Method according to claim 1 wherein the biopolymer is a starch and the enzyme is α-amylase, and wherein calcium chloride is added to the water and the water is heated to a temperature such that the pH, calcium ion concentration and temperature are suitable for α-amylase degradation of the starch.
Claim 14
Dependent Claim
34 words
Method according to claim 1 wherein the dried particles are pulverized by causing the same to collide with each other at high speed and at a temperature such as to obtain a dry material.
Claim 15
Dependent Claim
26 words
Method according to claim 7 wherein the granulation is effected by means of a screw extruder and the granulated particles are then subjected to air drying.
Claim 16
Dependent Claim
16 words
Method according to claim 1 wherein the melting index of the synthetic polymer is about 4.
Claim 17
Dependent Claim
22 words
Method according to claim 1 wherein the proportion of biopolymer to synthetic polymer is about 10-60% biopolymer and about 40-90% synthetic polymer.
Claim 18
Dependent Claim
17 words
Method according to claim 16 and also including about 0.01-0.1% catalyst which catalyzes oxidation of the oil.
Claim 19
Dependent Claim
41 words
Method according to claim 8 wherein said catalyst is an oxidant for vegetable oils providing Fe 3+ , Se 2+ , Cu 2+ or Zn 2+ and the amount thereof is between 0.05-1% by weight of the catalyst and synthetic polymer.
Claim 20
Dependent Claim
24 words
Method according to claim 1 wherein the biologically degradable polymer is a starch and wherein the enzyme is α-amylase that splits dextrins from starch.
Claim 21
Dependent Claim
24 words
Method according to claim 1 wherein the biologically degradable polymer is a cellulose and wherein the enzyme is endoglucanase that splits cellodextrins from cellulose.
Claim 22
Dependent Claim
24 words
Method according to claim 1 wherein the biologically degradable polymer is a cellulose and wherein the enzyme is cellobiohydrolase that splits cellobiose from cellulose.