Vinyl functional reactive tackifiers for pressure-sensitive adhesives

Claim 2

A tackified pressure-sensitive adhesive which comprises: (a) an acrylic based, pressure-sensitive adhesive polymer having a glass transition temperature of less than about 0° C. and comprising at least one polymerized acrylate monomer which when homopolymerized has a glass transition temperature of less than about -25° C., an entanglement molecular weight greater than about 20,000 and comprising from about 50 to about 90% by weight of the total monomers of the acrylic based pressure-sensitive adhesive polymer said acrylic based pressure-sensitive adhesive polymer including at least one other monomer wherein said monomer is selected from the group consisting of alkyl esters of unsaturated carboxylic acids, copolymerizable vinyl unsaturated monomers, styrenic monomers, unsaturated carboxylic acids, diesters of unsaturated dicarboxylic acids in which each alkyl group independently contains from 4 to about 8 carbon atoms, isomeric acrylates, isomeric methacrylates, multifunctional monomers having epoxy and vinyl functionality and mixtures thereof in admixture with and reacted with; (b) a reactive tackifier present in amount up to about 50% by weight of the acrylic based, pressure-sensitive adhesive polymer, said reactive tackifier having the formula: ##STR7## wherein rings 2 and 3 are independently saturated or unsaturated, R 1 and R 2 are independently --H or an alkyl group consisting from 1 to about 4 carbon atoms, R 3 is isopropyl and Y is a pendant vinyl unsaturated organo group which reacts in the presence of said acrylic based, pressure-sensitive adhesive polymer under the action of actinic or electron beam radiation and is of the formula: CH.sub.2 ═C(R.sub.4)--Z, wherein: R 4 ═--H or --CH 3 ; Z═--COO--CH 2 --CH 2 --NH--COO--CH 2 --. PG,21

Claim 3

A tackified pressure-sensitive adhesive as claimed in claim 1 in which the reactive tackifier is present in an amount of from about 10 to about 20% by weight based on the weight of the polymer and tackifier.

Claim 4

A tackified pressure-sensitive adhesive which comprises: (a) an acrylic based, pressure-sensitive adhesive polymer having a glass transition temperature of less than about 0° C. and comprising at least one polymerized acrylate monomer which when homopolymerized has a glass transition temperature of less than about -20° C., an entanglement molecular weight greater than about 20,000 and selected from the group consisting of butyl acrylate, 2-ethyl hexylacrylate, and isooctylacrylate and mixtures thereof, said acrylate monomer comprising from about 50 to about 90% be weight of the total monomers of the acrylic based, pressure-sensitive adhesive polymer, and co-polymerized with at least one other monomer selected from the group consisting of alkyl esters of unsaturated carboxylic acids, alkyl methacrylates copolymerizable vinyl unsaturated monomers, styrenic monomers, unsaturated carboxylic acids, diesters of unsaturated dicarboxylic acids in which each alkyl group independently contains from 4 to about 8 carbon atoms, isomeric acrylates, isomeric methacrylates, multifunctional monomers having epoxy and vinyl functionality and mixtures thereof in admixture with and reacted with; (b) a reactive tackifier present in a tackifying amount of from about 10 to about 50% by weight of the acrylic based, pressure-sensitive adhesive polymer, said reactive tackifier having the formula: ##STR8## and mixtures thereof, which R 1 and R 2 are independently --H or an alkyl group containing from 1 to about 4 carbon atoms, R 3 is isopropyl and Y is a pendant vinyl unsaturated organo group which reacts with said acrylic based, pressure-sensitive adhesive polymer under the action of actinic or electron beam radiation and is of the formula: CH.sub.2 ═C(R.sub.4)--Z, wherein: R 4 ═--H or --CH 3 ; Z═--COO--CH 2 --CH 2 --NH--COO--CH 2 --.

Claim 5

A tackified pressure-sensitive adhesive which comprises: (a) an acrylic based, pressure-sensitive adhesive polymer having a glass transition temperature of less than about 0° C. and comprising at least one polymerized acrylate monomer which when homopolymerized has a glass transition temperature of less than about -20° C., an entanglement molecular weight greater than about 20,000 and selected from the group consisting of butyl acrylate, 2-ethyl hexylacrylate, and isooctylacrylate and mixtures thereof, said acrylate monomer comprising from about 50 to about 90% be weight of the total monomers of the acrylic based, pressure-sensitive adhesive polymer, and co-polymerized with at least one other monomer selected from the group consisting of alkyl esters of unsaturated carboxylic acids, alkyl methacrylates copolymerizable vinyl unsaturated monomers, styrenic monomers, unsaturated carboxylic acids, diesters of unsaturated dicarboxylic acids in which each alkyl group independently contains from 4 to about 8 carbon atoms, isomeric acrylates, isomeric methacrylates, multifunctional monomers having epoxy and vinyl functionality and mixtures thereof in admixture with and reacted with; (b) a reactive tackifier present in a tackifying amount of from about 10 to about 50% by weight of the acrylic based, pressure-sensitive adhesive polymer, said reactive tackifier having the formula: ##STR8## and mixtures thereof, which R 1 and R 2 are independently --H or an alkyl group containing from 1 to about 4 carbon atoms, R 3 is isopropyl and Y is a pendant vinyl unsaturated organo group which reacts with said acrylic based, pressure-sensitive adhesive polymer under the action of actinic or electron beam radiation and is of the formula: CH.sub.2 ═C(R.sub.4)--Z, wherein: R 4 ═--H or --CH 3 ; Z═--COO--CH 2 --CH 2 --NH--COO--CH 2 --.

Claim 6

A tackified pressure-sensitive adhesive as claimed in claim 3 in which the reactive tackifier is present in an amount of from about 10 to about 20% by weight based on the weight of the polymer and tackifier.

Claim 7

A tackified pressure-sensitive adhesive claimed in claim 1 in which the tackifier is the reaction product of a group providing a vinyl group with a hydroxyl group of a compound of the formula: ##STR9## whereby a tackifier with a pendant vinyl unsaturated organo group of the formula --COO--CH 2 --CH 2 --NH--COO--CH 2 -- is obtained.

Claim 8

A tackified pressure-sensitive adhesive as claimed in claim 5 in which the reactive tackier is present in an amount of from about 10 to about 20% by weight based on the weight of the polymer and tackifier.

Claim 9

A tackified pressure-sensitive adhesive as claimed in claim 1 in which the tackifier is abietyl ethyl methacryl carbamate.

Claim 10

A tackified pressure-sensitive adhesive as claimed in claim 2 in which the tackifier is abietyl ethyl methacryl carbamate.

Claim 11

A tackified pressure-sensitive adhesive which comprises an acrylic based, pressure-sensitive adhesive polymer having a glass transition temperature of less than about 0° C. and comprising at least one polymerized acrylate monomer which when homopolymerized has a glass transition temperature of less than about -25° C., an entanglement molecular weight greater than about 20,000 and comprising from about 50 to about 90% by weight of the total monomers, co-polymerized with at least one unsaturated carboxylic acid present in an amount of up to about 10 per cent by weight of the polymer, said acrylic based, pressure-sensitive adhesive polymer further containing an interpolymerized amount of a reactive tackifier present in a tackifying amount of up to about 50% by weight of the adhesive polymer, said reactive tackifier having the formula: ##STR10## wherein rings 2 and 3 are independently saturated or unsaturated, R 1 and R 2 are independently --H or an alkyl group containing from 1 to about 4 carbon atoms, R 3 is isopropyl and Y is a reactive pendant vinyl unsaturated organo group of the formula: CH.sub.2 ═C(R.sub.4)--Z, wherein: R 4 ═--H or --CH 3 ; Z═--COO--CH 2 --CH 2 --NH--COO--CH 2 --.

Claim 12

A tackified pressure-sensitive adhesive which comprises an acrylic based, pressure-sensitive adhesive polymer having a glass transition temperature of less than about 0° C. and comprising at least one polymerized acrylate monomer which when homopolymerized has a glass transition temperature of less than about -25° C., an entanglement molecular weight greater than about 20,000 and comprising from about 50 to about 90% by weight of the total monomers, co-polymerized with at least one unsaturated carboxylic acid present in an amount of up to about 10 per cent by weight of the polymer, said acrylic based, pressure-sensitive adhesive polymer further containing an interpolymerized amount of a reactive tackifier present in a tackifying amount of up to about 50% by weight of the adhesive polymer, said reactive tackifier having the formula: ##STR10## wherein rings 2 and 3 are independently saturated or unsaturated, R 1 and R 2 are independently --H or an alkyl group containing from 1 to about 4 carbon atoms, R 3 is isopropyl and Y is a reactive pendant vinyl unsaturated organo group of the formula: CH.sub.2 ═C(R.sub.4)--Z, wherein: R 4 ═--H or --CH 3 ; Z═--COO--CH 2 --CH 2 --NH--COO--CH 2 --.

Claim 13

A tackified pressure-sensitive adhesive as claimed in claim 9 in which the reactive tackifier is present in an amount of from about 10 to about 20% by weight based on the weight of the polymer and interpolymerized tackifier.

Claim 14

A tackified pressure-sensitive adhesive as claimed in claim 9 in which the tackifier is abityl ethyl methacryl carbamate.

Claim 15

A tackified pressure-sensitive adhesive which comprises the reaction product of an acrylic based, pressure-sensitive adhesive polymer containing on a parts by weight basis about 56 parts 2-ethyl hexyl acrylate, about parts 36 butyl acrylate, about 10 parts acrylic acid, and about 0.1 part glycidyl methacrylate reacted with up to 50% by weight of the polymer of a reactive tackifier which is abietyl ethyl methacryl carbamate.

Claim 16

A tackified pressure-sensitive adhesive which comprises the reaction product of an acrylic based, pressure-sensitive adhesive polymer containing on a parts by weight basis about 56 parts 2-ethyl hexyl acrylate, about parts 36 butyl acrylate, about 10 parts acrylic acid, and about 0.1 part glycidyl methacrylate reacted with up to 50% by weight of the polymer of a reactive tackifier which is abietyl ethyl methacryl carbamate.