US4745138A
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Radiation curable partial esters of anhydride-containing copolymers
Assignee: Sartomer Co Inc
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Filing: 1985-08-05
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Granted: 1988-05-17
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Expires: 2005-08-05
Abstract
Abstract Radiation-curable low molecular weight partial ester copolymer compositions comprising products of a terminally ethylenically unsaturated compound and a maleic anhydride characterized by having free-anhydride functionality are provided. The partial esters are produced by esterification of certain copolymers with a hydroxyalkyl acrylyl compound, or an admixture thereof with a monohydric alcohol. The compositions of the invention are useful as radiation cross-linkable diluents for radiation-hardenable compositions, particularly in improving adhesion promotion and/or dispersive capabilities of binder resins.
Inventors
- 👤 Chandrakant B. Thanawalla
- 👤 Gary W. Ceska
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 20:01
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/14; C08F2810/00; C08F2810/20; C08F2810/30
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
280 words
A radiation-curable partial ester of a free anhydride-containing copolymer corresponding to the structural formula: ##STR6## wherein: R 1 and R 2 are each independently selected from the group consisting of hydrogen, alkyl containing of from 1 to 20 carbon atoms, aryl containing of from 6 to 10 carbon atoms, alkaryl containing of from 7 to 14 carbon atoms, cycloalkyl containing of from 4 to 12 carbon atoms, and a halo radical; R 3 , R 4 and R 5 are each independently selected from the group consisting of hydrogen, and an alkyl radical containing of from 1 to 5 carbon atoms; the radical R 6 is a member selected from the group consisting of an alkyl, arylalkyl, alkyl-substituted arylalkyl and oxyalkylated derivatives of each of such radicals containing of from 2 to 4 carbon atoms in each oxyalkylene group, which group may be of 1 to 20 repeating units; the radical A is a linear or branched divalent alkylene of from 1 to 20 carbon atoms, or an oxyalkylated derivative thereof containing of from 2 to 4 carbon atoms in each oxyalkylene group, which group may be of 1 to 20 repeating units, and subscripts x, y, z, m and p are each whole numbers such that the sum of x, y, z, m and p may range from 4 to about 20, with x, p, m and y each being equal to or greater than 1, and z may be 0, said partial ester being characterized a exhibiting a number average molecular weight of between about 1,000 and 20,000, an acid number of at least about 40, and an acrylate equivalent per gram value of at least about 0.1.
Claim 2
Dependent Claim
280 words
A radiation-curable partial ester of a free anhydride-containing copolymer corresponding to the structural formula: ##STR6## wherein: R 1 and R 2 are each independently selected from the group consisting of hydrogen, alkyl containing of from 1 to 20 carbon atoms, aryl containing of from 6 to 10 carbon atoms, alkaryl containing of from 7 to 14 carbon atoms, cycloalkyl containing of from 4 to 12 carbon atoms, and a halo radical; R 3 , R 4 and R 5 are each independently selected from the group consisting of hydrogen, and an alkyl radical containing of from 1 to 5 carbon atoms; the radical R 6 is a member selected from the group consisting of an alkyl, arylalkyl, alkyl-substituted arylalkyl and oxyalkylated derivatives of each of such radicals containing of from 2 to 4 carbon atoms in each oxyalkylene group, which group may be of 1 to 20 repeating units; the radical A is a linear or branched divalent alkylene of from 1 to 20 carbon atoms, or an oxyalkylated derivative thereof containing of from 2 to 4 carbon atoms in each oxyalkylene group, which group may be of 1 to 20 repeating units, and subscripts x, y, z, m and p are each whole numbers such that the sum of x, y, z, m and p may range from 4 to about 20, with x, p, m and y each being equal to or greater than 1, and z may be 0, said partial ester being characterized a exhibiting a number average molecular weight of between about 1,000 and 20,000, an acid number of at least about 40, and an acrylate equivalent per gram value of at least about 0.1.
Claim 3
Dependent Claim
78 words
The partial ester of claim 1 wherein, in said formula, R 1 and R 2 are each independently selected from the group consisting of hydrogen, methyl, phenyl, and benzyl, and R 3 , R 4 and R 5 are each independently selected from the group consisting of hydrogen and methyl; R 6 is an alkyl radical containing of from 1 to 6 carbon atoms; A is an alkylene hydrocarbon chain containing of from 2 to 4 carbon atoms.
Claim 4
Dependent Claim
15 words
The partial ester of claim 2 wherein, in said formula, the subscript z is 0.
Claim 5
Dependent Claim
39 words
The partial ester of claim 3 wherein, in said formula, R 1 is hydrogen; R 2 is phenyl; R 3 , R 4 and R 5 are hydrogen; and A is an alkylene hydrocarbon chain containing 2 carbon atoms.
Claim 6
Dependent Claim
43 words
The partial ester of claim 1 wherein, in said formula, R 1 is hydrogen; R 2 is phenyl; R 3 , R 4 and R 5 are each hydrogen; R 6 is methyl; A is an alkylene hydrocarbon chain containing 2 carbon atoms.
Claim 7
Dependent Claim
39 words
The partial ester of claim 1 wherein, in said formula, R 1 is hydrogen; R 2 is phenyl; R 3 , R 4 and R 5 are each hydrogen; R 6 is the residue of ethylene glycol butyl ether.
Claim 8
Dependent Claim
72 words
A radiation curable composition comprising an admixture of: (i) a radiation curable partial ester of a free-anhydride-containing copolymer corresponding to the structural formula set forth in claim 1, present in an amount of between about 5% and 80% by weight; (ii) about 20% to 95% by weight, of a free radical polymerizable reactive diluent; and (iii) and from about 0 to about 10% by weight, of a radiation responsive free radical initiator.
Claim 9
Dependent Claim
18 words
The composition of claim 7 wherein said copolymer corresponds to the structural formula set forth in claim 2.
Claim 10
Dependent Claim
18 words
The composition of claim 7 wherein said copolymer corresponds to the structural formula set forth in claim 3.
Claim 11
Dependent Claim
14 words
A polymerization process comprising subjecting the composition admixture of claim 7 to actinic radiation.
Claim 12
Dependent Claim
14 words
A polymerization process comprising subjecting the composition admixture of claim 8 to actinic radiation.
Claim 13
Dependent Claim
14 words
A polymerization process comprising subjecting the composition admixture of claim 9 to actinic radiation.
Claim 14
Dependent Claim
10 words
The polymeric product prepared by the process of claim 10.
Claim 15
Dependent Claim
10 words
The polymeric product prepared by the process of claim 11.
Claim 16
Dependent Claim
10 words
The polymeric product prepared by the process of claim 12.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-05-17 | 1991-11-16 | 1992-05-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-05-17 | 1995-11-16 | 1996-05-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-05-17 | 1999-11-16 | 2000-05-17 | $7700.00 | Window Closed / Lapsed |