US4183796A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Radiation curable oligomers based on tris(2-hydroxyethyl) isocyanurate
Assignee: Covestro Resins BV
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Filing: 1978-02-09
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Granted: 1980-01-15
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Expires: 1998-02-09
Abstract
Abstract A radiation curable oligomer which cures to provide a combination of improved elongation and tensile strength is constituted by a selected hydroxy functional polyester having its active hydrogen atoms end-capped by reaction with ethylenically unsaturated monoisocyanate. This polyester is the reaction product of one mole of tris (2-hydroxyethyl) isocyanurate with three moles of saturated dicarboxylic acid and three moles of diol, these proportions being variable within the limits of ±20%, the polyester reaction product having an acid value of less than 20, preferably less than 5, and providing hydroxyl-terminated branches having an average length corresponding to a calculated molecular weight of 100-1500.
Inventors
- 👤 Robert E. Ansel
- 👤 John C. Graham
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 18:22
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/46; C08G18/4615; C08G18/4638; C08G18/4661; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31935
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
82 words
A radiation curable oligomer constituted by an hydroxy functional polyester having its active hydrogen atoms end-capped by reaction with ethylenically unsaturated monoisocyanate, said polyester being the reaction product of one mole of tris(2-hydroxyethyl)isocyanurate with three moles of saturated dicarboxylic acid and three moles of diol, these proportions being variable within the limits of ±20%, said polyester reaction product having an acid value of less than 20 and providing hydroxyl-terminated branches having an average length corresponding to a calculated molecular weight of 100-1500.
Claim 2
Dependent Claim
82 words
A radiation curable oligomer constituted by an hydroxy functional polyester having its active hydrogen atoms end-capped by reaction with ethylenically unsaturated monoisocyanate, said polyester being the reaction product of one mole of tris(2-hydroxyethyl)isocyanurate with three moles of saturated dicarboxylic acid and three moles of diol, these proportions being variable within the limits of ±20%, said polyester reaction product having an acid value of less than 20 and providing hydroxyl-terminated branches having an average length corresponding to a calculated molecular weight of 100-1500.
Claim 3
Dependent Claim
23 words
A radiation curable oligomer as recited in claim 1 in which the hydroxyl value of said polyester is in the range of 40-200.
Claim 4
Dependent Claim
28 words
A radiation curable oligomer as recited in claim 2 in which said ethylenically unsaturated monoisocyanate is formed by reacting 2-hydroxy alkyl acrylate or methacrylate with an organic diisocyanate.
Claim 5
Dependent Claim
27 words
A radiation curable oligomer as recited in claim 2 in which said saturated dicarboxylic acid is a straight chain aliphatic dicarboxylic acid having from 4-10 carbon atoms.
Claim 6
Dependent Claim
36 words
A radiation curable oligomer as recited in claim 4 in which said saturated dicarboxylic acid is selected from adipic acid and azelaic acid and the hydroxyl value of said polyester is in the range of 150-180.
Claim 7
Dependent Claim
16 words
A radiation curable oligomer as recited in claim 2 in which said diol is 1,6-hexane diol.
Claim 8
Dependent Claim
16 words
A radiation curable oligomer as recited in claim 3 in which said diisocyanate is 2,4-toluene diisocyanate.
Claim 9
Dependent Claim
19 words
A radiation curable oligomer as recited in claim 7 in which said toluene diisocyanate is reacted with 2-hydroxyethyl acrylate.
Claim 10
Dependent Claim
14 words
A radiation curable oligomer as recited in claim 1 which is a waxy semi-solid.
Claim 11
Dependent Claim
31 words
A radiation curable oligomer as recited in claim 1 in admixture with an ethylenically unsaturated liquid diluent, said diluent constituting from 10% to 60% of the total weight of polymerizable material.
Claim 12
Dependent Claim
29 words
A radiation curable mixture as recited in claim 10 in which the proportion of diluent is in the range of from 20%-40% of the total weight of polymerizable material.
Claim 13
Dependent Claim
18 words
A radiation curable oligomer as recited in claim 1 in admixture with a ketonic photosensitizer for ultraviolet light.
Claim 14
Dependent Claim
16 words
A radiation curable oligomer as recited in claim 3 in which said diisocyanate is isophorone diisocyanate.
Claim 15
Dependent Claim
52 words
A radiation curable oligomer as recited in claim 1 in which said polyester is formed by reacting one mole of tris(2-hydroxyethyl)isocyanurate with about three moles of saturated dicarboxylic acid and about three moles of diol, said reaction being continued to substantial completion as evidenced by an acid value of less than 20.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-01-14 | 1983-07-16 | 1984-01-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-01-14 | 1987-07-16 | 1988-01-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-01-14 | 1991-07-16 | 1992-01-15 | $7700.00 | Window Closed / Lapsed |