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US5128289A Expired / Lapsed US ⏱️ 0.0 years remaining

X7R dielectric ceramic composition and capacitor made therefrom

Assignee: Vibrantz Corp
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Filing: 1990-12-07
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Granted: 1992-07-07
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Expires: 2010-12-07
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Abstract

Abstract A barium titanate based dielectric ceramic composition having a temperature coefficient range of about +/-15% form its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, is prepared from a ternary system comprising barium titanate, nickel niobate and manganese niobate in the molar ratios of approximately 97.23 mole % of BaTiO 3 , 2.35 mole % of NiO.sub.(1-x).NbO 2 .5(x), and 0.42 mole % of MnO 1-y ).NbO 2 .5(y), where x may equal approximately 0.73 and y approximately 0.53. Tantalum is also used in place of the niobium.

Inventors

  • 👤 James M. Wilson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:33
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/02; H01B3/12; C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/468; C04B35/4682; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1218; H01G4/1227

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 153 words
A ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, and consisting essentially of the ternary system of BaTiO and the non-stoichiometric niobates of NiO.sub.(1-x), NbO 2 ,5(x) and MnO.sub.(1-y), NbO 2 .5(y), said BaTiO 3 being a prereacted powder in crystallite form, the niobium particle sizes ranging anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and manganese oxide particle sizes ranging anywhere from approximately 0.1 to 1.0 microns, the constituents of said composition being present in the molar ratios of about 97.23 mole % of BaTiO 3 , 2.35 mole % of NiO.sub.(1-x), NbO 2 .5(x), and 0.42 mole % of MnO.sub.(1-y), NbO 2 .5(y), and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 2
Dependent Claim 153 words
A ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, and consisting essentially of the ternary system of BaTiO and the non-stoichiometric niobates of NiO.sub.(1-x), NbO 2 ,5(x) and MnO.sub.(1-y), NbO 2 .5(y), said BaTiO 3 being a prereacted powder in crystallite form, the niobium particle sizes ranging anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and manganese oxide particle sizes ranging anywhere from approximately 0.1 to 1.0 microns, the constituents of said composition being present in the molar ratios of about 97.23 mole % of BaTiO 3 , 2.35 mole % of NiO.sub.(1-x), NbO 2 .5(x), and 0.42 mole % of MnO.sub.(1-y), NbO 2 .5(y), and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 3
Dependent Claim 29 words
A dielectric composition as defined in claim 1, wherein said prereacted powder has a particle size in the range of anywhere from approximately 0.2 microns to approximately 0.5 microns.
Claim 4
Dependent Claim 154 words
A ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, and consisting essentially of the ternary system of BaTiO 3 and the non-stoichiometric tantalates of NiO.sub.(1-x), TaO 2 .5(x) and MnO.sub.(1-y), TaO 2 .5(y), said BaTiO 3 being a prereacted powder in crystallite form, the tantalate particle sizes ranging anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and maganese oxide particle sizes ranging anywhere from approximately 0.1 to 1.0 microns, the constituents of said composition being present in the molar ratios of about 97.23 mole % of BaTiO 3 , 2.35 mole % of NiO.sub.(1-x), TaO 2 .5(x) and 0.42 mole % of MnO.sub.(1-y), TaO 2 .5(y) and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 5
Dependent Claim 154 words
A ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, and consisting essentially of the ternary system of BaTiO 3 and the non-stoichiometric tantalates of NiO.sub.(1-x), TaO 2 .5(x) and MnO.sub.(1-y), TaO 2 .5(y), said BaTiO 3 being a prereacted powder in crystallite form, the tantalate particle sizes ranging anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and maganese oxide particle sizes ranging anywhere from approximately 0.1 to 1.0 microns, the constituents of said composition being present in the molar ratios of about 97.23 mole % of BaTiO 3 , 2.35 mole % of NiO.sub.(1-x), TaO 2 .5(x) and 0.42 mole % of MnO.sub.(1-y), TaO 2 .5(y) and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 6
Dependent Claim 11 words
A multi-layer capacitor made from the composition defined in claim 1.
Claim 7
Dependent Claim 11 words
A multi-layer capacitor made from the composition defined in claim 3.
Claim 8
Dependent Claim 30 words
A ceramic dielectric composition as defined in claim 3, wherein said prereacted powder has a particle size in the range of anywhere from approximately 0.2 microns to approximately 0.5 microns.
Claim 9
Dependent Claim 100 words
A barium titanate based ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, including non-stoichiometric niobates of NiO.sub.(1-x), NbO 2 .5(x) and MnO.sub.(1-y), NbO 2 .5(y) wherein the niobium particle sizes range anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and manganese oxide particle sizes range anywhere from approximately 0.1 to 1.0 microns, and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 10
Dependent Claim 100 words
A barium titanate based ceramic dielectric composition in powder form capable of producing capacitors having a temperature coefficient range of about ±15% from its value at 25° C. over a temperature range of -55° C. to 125° C., and a dielectric constant in excess of 5000, including non-stoichiometric niobates of NiO.sub.(1-x), NbO 2 .5(x) and MnO.sub.(1-y), NbO 2 .5(y) wherein the niobium particle sizes range anywhere from approximately 0.2 to 1.2 microns, and the nickel oxide and manganese oxide particle sizes range anywhere from approximately 0.1 to 1.0 microns, and wherein x is approximately 0.73 and y is approximately 0.53.
Claim 11
Dependent Claim 37 words
The ceramic dielectric composition as defined in claim 7, wherein said niobates are present in the molar ratios of about 2.35 mole % of NiO.sub.(1-x) ·NbO 2 .5(x), and 0.42 mole % of MnO.sub.(1-y) ·NbO 2 .5(y).

References Cited (Backward Citations)

US4379319A Cited
US4882305A Cited
US4863883A Cited
US4670243A Cited
US4939108A Cited
US4816430A Cited
US5084424A Cited
US4988650A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-07-07 1996-01-06 1996-07-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-07-07 2000-01-06 2000-07-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-07-07 2004-01-06 2004-07-07 $7700.00 Window Closed / Lapsed

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