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US4379319A Expired / Lapsed US ⏱️ 0.0 years remaining

Monolithic ceramic capacitors and improved ternary ceramic compositions for producing same

Assignee: Vibrantz Corp
•
Filing: 1982-02-18
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Granted: 1983-04-05
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Expires: 2002-02-18
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Abstract

Abstract A multi-layer ceramic capacitor is prepared from a novel ceramic composition produced from the oxides of lead (PbO), iron (Fe 2 O 3 ), niobium (Nb 2 O 5 ), nickel (NiO), and tungsten (WO 3 ), or the synthesized compounds Pb(Fe 1/2 Nb 1/2 )O 3 , Pb(Fe 2/3 W 1/3 )O 3 and Pb(Ni 1/3 Nb 2/3 )O 3 , together with a small quantity of a Mn(NO 3 ) 2 solution to improve certain electric properties of the capacitor. When used in the correct proportions the oxides disclosed herein are capable of producing monolithic ceramic capacitors having Z5U ratings. In particular, the lead, nickel, niobate compound tends to flatten and to lower the curie peak for the ceramic composition.

Inventors

  • 👤 James M. Wilson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:45
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/495; C04B35/497; H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; H01G4/1209; H01G4/1254

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 94 words
A ceramic composition capable of producing capacitors having a temperature coefficient range of +22% to -56% at an operating temperature range of +10° C. to +85° C., and an insulation resistance of 7.5×10 9 Ω or higher, and consisting essentially of [Pb(Fe 1/2 Nb 1/2 )O 3 ]X, [Pb(Fe 2/3 W 1/3 )O 3 ]Y and [Pb(Ni 1/3 Nb 2/3 )O 3 ]Z, and from 0.1 to 0.75 wt.% Mn(NO 3 ) 2 , where X+Y+Z=1.0, and the proportions of X, Y, and Z fall within the ranges of about: 0.55≦X≦0.70, 0.15≦Y≦0.36, and, 0.07≦Z≦0.32.
Claim 2
Dependent Claim 94 words
A ceramic composition capable of producing capacitors having a temperature coefficient range of +22% to -56% at an operating temperature range of +10° C. to +85° C., and an insulation resistance of 7.5×10 9 Ω or higher, and consisting essentially of [Pb(Fe 1/2 Nb 1/2 )O 3 ]X, [Pb(Fe 2/3 W 1/3 )O 3 ]Y and [Pb(Ni 1/3 Nb 2/3 )O 3 ]Z, and from 0.1 to 0.75 wt.% Mn(NO 3 ) 2 , where X+Y+Z=1.0, and the proportions of X, Y, and Z fall within the ranges of about: 0.55≦X≦0.70, 0.15≦Y≦0.36, and, 0.07≦Z≦0.32.
Claim 3
Dependent Claim 51 words
A ceramic composition as claimed in claim 1, wherein the proportions of X, Y and Z fall within the generally trapezoidal region denoted by the letters A, B, C and D on the ternary phase diagram shown in FIG. 1 of the accompanying drawings, and wherein Y is ≧0.15 mole percent.
Claim 4
Dependent Claim 16 words
A multilayer ceramic capacitor made from a ceramic composition of the type claimed in claim 1.

References Cited (Backward Citations)

US4078938A Cited
JPS54146812A Cited
JPS54159697A Cited
US4236928A Cited
US4308571A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-04-04 1986-10-04 1987-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-04-04 1990-10-04 1991-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-04-04 1994-10-04 1995-04-05 $7700.00 Window Closed / Lapsed

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