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US5122428A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making opaque grid lines for thermally-transferred color filter array element

Assignee: Eastman Kodak Co
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Filing: 1990-05-04
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Granted: 1992-06-16
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Expires: 2010-05-04
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Abstract

Abstract A process of making opaque grid lines for a color filter array element comprising a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer; a water-soluble dichromate salt; and up to 1 g/m 2 of a black pigment, black dye or dyes providing an opaque color, or a precursor thereof; b) washing the element with a solvent to remove the unexposed areas of the element, leaving a grid line pattern of hardened polymeric substance on the element; and c) drying the element to produce open cells on the support divided by opaque lines of the hardened polymeric substance greater than 0.3 μm in height above the support. In another embodiment of the invention, the above dichromate salt coating does not contain any black pigment or dye, and the grid pattern is dyed black before the drying step. Thus, a process of making opaque grid lines for a color filter array element according to another embodiment of the invention comprises a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer and a water-soluble dichromate salt; b) washing the element with a solvent to remove the unexposed areas of the element, leaving a grid line pattern of hardened polymeric substance on the element; c) soaking the element in a solution of black dye or dyes providing a black, opaque color of sufficient concentration to provide a laydown of up to 1.0 g/m 2 , and d) drying the element to produce open cells on the support divided by opaque lines of the hardened polymeric substance greater than 0.3 μm in height above the support. In another preferred embodiment, the above processes include the further steps of: e) coating the cellular element with a polymeric dye-receiving layer; and f) thermally transferring individual dyes to form a color filter array element comprising a repeating mosaic pattern of colorants in a polymeric binder, the pattern being made up of color patches bounded by the opaque lines in a grid pattern.

Inventors

  • 👤 Michael J. Simons

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:05
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1335; G02F1/133509; G02F1/133512; G03; G03F; G03F7/00; G03F7/0005; G03F7/0007

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 166 words
A process of making a color filter array element comprising a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer; a water-soluble dichromate salt; and up to 1 g/m 2 of a black pigment, black dye or dyes providing an opaque color, or a precursor thereof; b) washing said element with a solvent to remove the unexposed areas of said element, leaving a grid line pattern of hardened polymeric substance on said element; c) drying said element to produce open cells on said support divided by opaque lines of said hardened polymeric substance greater than 0.3 μm in height above said support; d) coating said cellular element with a polymeric dye-receiving layer; and e) thermally transferring individual dyes to form a color filter array element comprising a repeating mosaic pattern of colorants in a polymeric binder, said pattern being made up of color patches bounded by said opaque lines in a grid pattern.
Claim 2
Dependent Claim 166 words
A process of making a color filter array element comprising a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer; a water-soluble dichromate salt; and up to 1 g/m 2 of a black pigment, black dye or dyes providing an opaque color, or a precursor thereof; b) washing said element with a solvent to remove the unexposed areas of said element, leaving a grid line pattern of hardened polymeric substance on said element; c) drying said element to produce open cells on said support divided by opaque lines of said hardened polymeric substance greater than 0.3 μm in height above said support; d) coating said cellular element with a polymeric dye-receiving layer; and e) thermally transferring individual dyes to form a color filter array element comprising a repeating mosaic pattern of colorants in a polymeric binder, said pattern being made up of color patches bounded by said opaque lines in a grid pattern.
Claim 3
Dependent Claim 176 words
A process of making a color filter array element comprising a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer and a water-soluble dichromate salt; b) washing said element with a solvent to remove the unexposed areas of said element, leaving a grid line pattern of hardened polymeric substance on said element; c) soaking said element in a solution of black dye or dyes providing a black, opaque color of sufficient concentration to provide a laydown of up to 1.0 g/m 2 , d) drying said element to produce open cells on said support divided by opaque lines of said hardened polymeric substance greater than 0.3 μm in height above said support; e) coating said cellular element with a polymeric dye-receiving layer; and f) thermally transferring individual dyes to form a color filter array element comprising a repeating mosaic pattern of colorants in a polymeric binder, said pattern being made up of color patches bounded by said opaque lines in a grid pattern.
Claim 4
Dependent Claim 176 words
A process of making a color filter array element comprising a) exposing to light through a negative grid pattern a photo-hardenable element comprising a support having thereon a coating comprising a water-soluble polymer and a water-soluble dichromate salt; b) washing said element with a solvent to remove the unexposed areas of said element, leaving a grid line pattern of hardened polymeric substance on said element; c) soaking said element in a solution of black dye or dyes providing a black, opaque color of sufficient concentration to provide a laydown of up to 1.0 g/m 2 , d) drying said element to produce open cells on said support divided by opaque lines of said hardened polymeric substance greater than 0.3 μm in height above said support; e) coating said cellular element with a polymeric dye-receiving layer; and f) thermally transferring individual dyes to form a color filter array element comprising a repeating mosaic pattern of colorants in a polymeric binder, said pattern being made up of color patches bounded by said opaque lines in a grid pattern.
Claim 5
Dependent Claim 30 words
The process of claim 1 wherein said opaque lines are about 10 μm to 60 μm in width and are separated from each other by 100 μm to 600 μm.
Claim 6
Dependent Claim 30 words
The process of claim 2 wherein said opaque lines are about 10 μm to 60 μm in width and are separated from each other by 100 μm to 600 μm.
Claim 7
Dependent Claim 10 words
The process of claim 1 wherein said support is glass.
Claim 8
Dependent Claim 10 words
The process of claim 2 wherein said support is glass.
Claim 9
Dependent Claim 11 words
The process of claim 1 wherein said water-soluble polymer is gelatin.
Claim 10
Dependent Claim 11 words
The process of claim 2 wherein said water-soluble polymer is gelatin.
Claim 11
Dependent Claim 13 words
The process of claim 1 wherein said water-soluble dichromate salt is potassium dichromate.
Claim 12
Dependent Claim 13 words
The process of claim 2 wherein said water-soluble dichromate salt is potassium dichromate.
Claim 13
Dependent Claim 34 words
The process of claim 1 wherein said water-soluble polymer is present at a concentration of 1-5 g/m 2 and said dichromate salt is present at a concentration of 10-50 weight percent of said polymer.
Claim 14
Dependent Claim 34 words
The process of claim 2 wherein said water-soluble polymer is present at a concentration of 1-5 g/m 2 and said dichromate salt is present at a concentration of 10-50 weight percent of said polymer.
Claim 15
Dependent Claim 44 words
The process of claim 1 wherein said black pigment or dye employed is such that the average optical density between the wavelengths of 400-700 nm of the material is at least twice the average optical density between the wavelengths between 330 and 400 nm.
Claim 16
Dependent Claim 13 words
The process of claim 1 wherein said coating also contains a dye mordant.
Claim 17
Dependent Claim 13 words
The process of claim 2 wherein said coating also contains a dye mordant.
Claim 18
Dependent Claim 19 words
The process of claim 1 wherein said polymeric binder is cross-linked after transfer of said color filter array image.
Claim 19
Dependent Claim 19 words
The process of claim 2 wherein said polymeric binder is cross-linked after transfer of said color filter array image.
Claim 20
Dependent Claim 19 words
The process of claim 1 wherein said pattern consists of a set of red, green and blue additive primaries.
Claim 21
Dependent Claim 19 words
The process of claim 2 wherein said pattern consists of a set of red, green and blue additive primaries.
Claim 22
Dependent Claim 13 words
The process of claim 1 wherein said binder also contains a cross-linking agent.
Claim 23
Dependent Claim 13 words
The process of claim 2 wherein said binder also contains a cross-linking agent.

References Cited (Backward Citations)

US4081277A Cited
US4311773A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-06-16 1995-12-16 1996-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-06-16 1999-12-16 2000-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-06-16 2003-12-16 2004-06-16 $7700.00 Window Closed / Lapsed

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