Abstract A process for applying an adherent electrically insulative moisture-resistant composite coating to a substrate. A thin, adherent, highly cross-linked, substantially liquid moisture-impervious primer coating is provided on the substrate by glow discharge polymerization of a low molecular weight hydrocarbon monomer in a low pressure chamber containing the substrate, the monomer being selected from among methane, ethane, propane, ethylene, and propylene. A second polymeric coating layer is provided over the primer coating by glow discharge polymerization of a second precursor comprising a hydrocarbon or substituted hydrocarbon. The precurser exhibits a hydrogen yield of not greater than about 0.75 hydrogen atoms per molecule under the glow discharge polymerization conditions under which the second layer is deposited, whereby the second polymeric coating layer is substantially resilient and strongly bonded to the primer coating and the second layer comprises a high concentration of surface and bulk free radicals. An article produced by the process and an apparatus for carrying out the process are also disclosed.
An apparatus for deposition of an electrically insulative composite polymeric coating on the surface of a substrate, said apparatus comprising a polymerization chamber, means within the polymerization chamber for support of a substrate, inlet means for delivery of a glow discharge polymerization monomer gas to said polymerization chamber, means for applying a vacuum to said polymerization chamber, inductance coupling coil outside said polymerization chamber for establishing a glow discharge zone within said chamber, whereby a glow discharge polymer primer coating may be applied to said substrate, means outside said polymerization chamber for vaporizing a precursor for a vapor deposition polymer, a pyrolysis chamber having an inlet in communication with said vaporization means, and an outlet in communication with said polymerization chamber, means for heating said vaporized precursor for pyrolysis thereof within said pyrolysis chamber, and means for controlling the temperature of said substrate at a temperature adapted for condensation of a polymer from said pyrolyzed vapor, the respective orientation of said pyrolysis chamber, said outlet from said pyrolysis chamber into said polymerization chamber, said support means, and said inductance coupling coil being such that precursor vaporized by said vaporization means may be deposited either by glow discharge polymerization or vapor deposition polymerization over the primer coating on said substrate.
Claim 2
Independent Claim
209 words
An apparatus for deposition of an electrically insulative composite polymeric coating on the surface of a substrate, said apparatus comprising a polymerization chamber, means within the polymerization chamber for support of a substrate, inlet means for delivery of a glow discharge polymerization monomer gas to said polymerization chamber, means for applying a vacuum to said polymerization chamber, inductance coupling coil outside said polymerization chamber for establishing a glow discharge zone within said chamber, whereby a glow discharge polymer primer coating may be applied to said substrate, means outside said polymerization chamber for vaporizing a precursor for a vapor deposition polymer, a pyrolysis chamber having an inlet in communication with said vaporization means, and an outlet in communication with said polymerization chamber, means for heating said vaporized precursor for pyrolysis thereof within said pyrolysis chamber, and means for controlling the temperature of said substrate at a temperature adapted for condensation of a polymer from said pyrolyzed vapor, the respective orientation of said pyrolysis chamber, said outlet from said pyrolysis chamber into said polymerization chamber, said support means, and said inductance coupling coil being such that precursor vaporized by said vaporization means may be deposited either by glow discharge polymerization or vapor deposition polymerization over the primer coating on said substrate.