Introducing and removing ion-exchange and other particulates from an assembled electrodeionization stack

Claim 2

Apparatus comprising an electrodeionization stack, which stack comprises first and second sets of parallel chambers, the chambers of said first set alternating with chambers of said second set and separated therefrom by ion exchange membranes, the chambers of each said set comprising at least one flow path defined by an intermembrane spacer, each said at least one flow path in each set of chambers having at least one first channel communicating with a first fluid transfer manifold within said stack, each said at least one flow path in each set of chambers also having at least one second channel communicating with a second fluid transfer manifold within said stack, said flow path having at least one flow path width restrictor between said first and second channel, said first and second manifolds adapted to transfer fluid solely into or out of said at least one flow path solely in one set of chambers, said at least one flow path in said one set of chambers adapted to be substantially filled with particulates comprising ion exchange particles if a suspension of particles is flowed into said at least one flow path, said at least one second channel characterized by retaining at least some of said particulates if fluid is caused to flow from said at least one flow path through said at least one second channel when said flow path is substantially filled with said particulates.

Claim 3

Apparatus according to claim 1 in which said flow path is one set of chambers adapted to be filled with particulates contained in a first portion thereof ion exchange particles differing substantially in at least one characteristic from ion exchange particles in a second portion thereof.

Claim 4

Apparatus according to claim 1 in which said flow path is one set of chambers adapted to be filled with particulates contained in a first portion thereof ion exchange particles differing substantially in at least one characteristic dimension from ion exchange particles in a second portion thereof.

Claim 5

Apparatus according to claim 1 in which said flow path in one set of chambers adapted to be filled with particulates contained at least in part organic scavenging type anion exchange particulates.

Claim 6

Apparatus according to claim 1 in which said flow path in one set of chambers adapted to be filled with particulates contained at least in part a sorbent for at least some organic molecules or colloids.

Claim 7

Apparatus according to claim 1 in which at least some of said ion exchange membranes are bipolar membranes.

Claim 8

Apparatus according to claim 1 which also comprises means for changing the direction of direct current flow through said stack.

Claim 9

Apparatus according to claim 1 which also comprises means for changing the direction of hydraulic flow between at least two of said fluid transfer manifolds.

Claim 10

Apparatus according to claim 1 which also comprises mixing means for forming a suspension of particulates in a fluid and suspension forwarding means for transferring at least part of said suspension into said flow path in one set of chambers adapted to be filled with particulates.

Claim 11

Apparatus according to claim 1 which also comprises mixing means for forming a suspension of particulates in a fluid, suspension forwarding means for transferring at least part of said suspension into said stack and recycle means for transferring a portion of said part of said suspension out of said stack to said mixing means.

Claim 12

A process for substantially demineralizing an aqueous liquid in an electrodeionization stack, said stack comprising a flow path having at least one first channel communicating with a first fluid transfer manifold within said stack and also having at least one second channel communicating with a second transfer manifold within said stack, said flow path substantially filled with particulates comprising ion exchange particles, which process comprises flowing aqueous liquid which is to be substantially demineralized through said first channel and first fluid transfer manifold of said flow path, passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path, subsequently passing fluid into said second fluid transfer manifold through said second channel at a flow rate adapted to carry at least part of said particulates comprising ion exchange particulates out of said flow path into said first fluid transfer manifold, while simultaneously passing fluid into and out of said first fluid transfer manifold at a flow rate adapted to produce a slurry of said at least part of said particulates in said fluid and carry said slurry out of said first fluid transfer manifold, thereafter passing slurry of particulates comprising ion exchange particles into said first transfer manifold, passing a first portion thereof through said at least one first channel into said flow path while passing a second portion thereof out of said first fluid transfer manifold, subsequently flowing aqueous liquid which is to be substantially demineralized through said flow path and said at least one second channel in series and out of said second fluid transfer manifold and simultaneously passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path.

Claim 13

A process for substantially demineralizing an aqueous liquid in an electrodeionization stack, said stack comprising a flow path having at least one first channel communicating with a first fluid transfer manifold within said stack and also having at least one second channel communicating with a second transfer manifold within said stack, said flow path substantially filled with particulates comprising ion exchange particles, which process comprises flowing aqueous liquid which is to be substantially demineralized through said first channel and first fluid transfer manifold of said flow path, passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path, subsequently passing fluid into said second fluid transfer manifold through said second channel at a flow rate adapted to carry at least part of said particulates comprising ion exchange particulates out of said flow path into said first fluid transfer manifold, while simultaneously passing fluid into and out of said first fluid transfer manifold at a flow rate adapted to produce a slurry of said at least part of said particulates in said fluid and carry said slurry out of said first fluid transfer manifold, thereafter passing slurry of particulates comprising ion exchange particles into said first transfer manifold, passing a first portion thereof through said at least one first channel into said flow path while passing a second portion thereof out of said first fluid transfer manifold, subsequently flowing aqueous liquid which is to be substantially demineralized through said flow path and said at least one second channel in series and out of said second fluid transfer manifold and simultaneously passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path.

Claim 14

A process for substantially demineralizing an aqueous liquid in an electrodeionization stack, said stack comprising a flow path having at least one first channel communicating with a first fluid transfer manifold within said stack and also having at least one second channel communicating with a second transfer manifold within said stack, said flow path substantially filled with particulates comprising ion exchange particles, which process comprises the following steps: (a) flowing aqueous liquid which is to be substantially demineralized through said flow path and said at least one second channel in series and out of said second fluid transfer manifold while simultaneously passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path, (b) passing a substantially direct electric current through said flow path in a direction adapted to cause ions to enter said flow path, (c) repeating steps (a) and (b), (d) passing fluid into said second fluid transfer manifold through said second channel, said flow path and said first channel in series into said first transfer manifold at a flow rate adapted to carry at least part of said particulates comprising ion exchange particles out of said flow path into said first fluid transfer manifold while simultaneously passing fluid into and out of said first fluid transfer manifold at a flow rate adapted to produce a slurry of said at least part of said particulates in said last mentioned fluid and to carry said slurry out of said first fluid transfer manifold, (e) passing slurry of particulates comprising ion exchange particles into said first transfer manifold, passing a first portion thereof through said at least one first channel into said flow path while passing a second portion thereof out of said first liquid transfer manifold, (f) repeating steps (a) and (b).

Claim 15

A process for substantially demineralizing an aqueous liquid in an electrodeionization stack, said stack comprising a flow path having at least one first channel communicating with a first fluid transfer manifold within said stack and also having at least one second channel communicating with a second transfer manifold within said stack, said flow path substantially filled with particulates comprising ion exchange particles, which process comprises the following steps: (a) flowing aqueous liquid which is to be substantially demineralized through said flow path and said at least one second channel in series and out of said second fluid transfer manifold while simultaneously passing a substantially direct electric current through said flow path in a direction adapted to cause ions to leave said flow path, (b) passing a substantially direct electric current through said flow path in a direction adapted to cause ions to enter said flow path, (c) repeating steps (a) and (b), (d) passing fluid into said second fluid transfer manifold through said second channel, said flow path and said first channel in series into said first transfer manifold at a flow rate adapted to carry at least part of said particulates comprising ion exchange particles out of said flow path into said first fluid transfer manifold while simultaneously passing fluid into and out of said first fluid transfer manifold at a flow rate adapted to produce a slurry of said at least part of said particulates in said last mentioned fluid and to carry said slurry out of said first fluid transfer manifold, (e) passing slurry of particulates comprising ion exchange particles into said first transfer manifold, passing a first portion thereof through said at least one first channel into said flow path while passing a second portion thereof out of said first liquid transfer manifold, (f) repeating steps (a) and (b).

Claim 16

A process according to claims 11 or 12 comprising forming a slurry of particulates comprising ion exchange particles which particulates are characterized by having a range of true densities in a fluid having a density within the range of such true densities, passing at least part of said slurry into said first fluid transfer manifold, passing a first portion of said part through said at least one first channel into said flow path, passing a second portion of said part out of said first transfer manifold.