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US5109080A
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High refractive-index ceramic/polymer hybrid material
Assignee: Virginia Tech Intellectual Properties Inc
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Filing: 1989-11-27
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Granted: 1992-04-28
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Expires: 2009-11-27
Abstract
Abstract New hybird materials prepared by incorporating a metal alkoxide sol, which is adapted to yield a high refractive-index metal oxide (e.g., titanium dioxide or zirconium dioxide), with a high refractive-index organic polymeric component (e.g., a triethoxysilane-capped poly(arylene ether) ketone or poly(arylene ether) sulfone) have been developed by the sol-gel method. The final products are transparent and display a high refractive index (n D =1.60-1.76). The refractive index of these hybrid materials has a linear relationship with the metal oxide content.
Inventors
- 👤 Bing Wang
- 👤 Garth L. Wilkes
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 16:34
CPC Classifications
C; C08; C08G; C08G79/00; C04; C04B; C04B28/00; C04B28/003; C08G65/00; C08G65/34; C08G65/48; G; G02; G02B; G02B1/00; G02B1/04
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
33 words
A high refractive-index ceramic/polymer hybrid material, having a refractive index of from 1.60 to 1.76, formed by the sol-gel synthesis of a metal alkoxide and an alkoxysilane-capped poly(arylene ether) polymeric component reactive therewith.
Claim 2
Dependent Claim
33 words
A high refractive-index ceramic/polymer hybrid material, having a refractive index of from 1.60 to 1.76, formed by the sol-gel synthesis of a metal alkoxide and an alkoxysilane-capped poly(arylene ether) polymeric component reactive therewith.
Claim 3
Dependent Claim
25 words
A material as claimed in claim 1 wherein the metal alkoxide is selected from the group consisting of a titanium alkoxide and a zirconium alkoxide.
Claim 4
Dependent Claim
15 words
A material as claimed in claim 1 wherein the metal alkoxide is a titanium alkoxide.
Claim 5
Dependent Claim
17 words
A material as claimed in claim 1 wherein the polymeric component is an alkoxysilane-capped poly(arylene ether) ketone.
Claim 6
Dependent Claim
17 words
A material as claimed in claim 1 wherein the polymeric component is an alkoxysilane-capped (arylene ether) sulfone.
Claim 7
Dependent Claim
15 words
A material as claimed in claim 4 wherein the metal alkoxide is a titanium alkoxide.
Claim 8
Dependent Claim
15 words
A material as claimed in claim 5 wherein the metal alkoxide is a titanium alkoxide.
Claim 9
Dependent Claim
55 words
Material as claimed in claim 1 which comprises from about 10% to about 90%, by weight of a metal oxide component derived from a metal alkoxide selected from the group consisting of a titanium alkoxide and a zirconium alkoxide and from about 90% to about 10%, by weight of a trialkoxysilane-capped poly(arylene ether) polymeric component.
Claim 10
Dependent Claim
16 words
A material as claimed in claim 8 wherein the poly(arylene ether) is a poly(arylene ether) ketone.
Claim 11
Dependent Claim
16 words
A material as claimed in claim 8 wherein the poly(arylene ether) is a poly(arylene ether) sulfone.
References Cited (Backward Citations)
US4715999A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-04-28 | 1995-10-28 | 1996-04-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-04-28 | 1999-10-28 | 2000-04-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-04-28 | 2003-10-28 | 2004-04-28 | $7700.00 | Window Closed / Lapsed |