Electroluminescent element

Claim 2

An electroluminescent element comprising a cathode, a fluorescent substance layer of organic compound, a hole transport layer of organic compound and an anode which are laminated in sequence, wherein the fluorescent substance layer predominantly comprises a coumarinic derivative that emits light efficiently at a high luminance upon application of a low voltage.

Claim 3

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A 1) below, ##STR40## wherein R 1 is selected from the group consisting of a hydrogen atom, a cyano group, a substituted or unsubstituted aryl group, an alkyl group, a carboxyl group, an acyloxy group, an aralkyl group and a heterocyclic group including one, two or three hetero atoms independently selected from oxygen atoms, sulfur atoms and nitrogen atoms, R 2 is selected from the group consisting of a hydrogen atom, an alkyl group, an acyloxy group, a haloalkyl group, a carboxyl group, a cyano group and an acyl group, R 3 is a hydrogen atom, a hydroxyl group or an allyl group, R 4 is a hydrogen atom, an alkyl group, an alkoxyl group, a hydroxyl group, an allyl group, an acyl group or a glycosido group, R 5 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxyl group, an acyloxy group, an amino group, an alkylamino group, a dialkylamino group, an alkoxycarbonyl group, an alkylamino group substituted by a sulfonium group or a hydroxyl group, and an aromatic heterocyclic or five-membered ring group including two or three nitrogen atoms, and R 6 is a hydrogen atom or an alkyl group.

Claim 4

An electroluminescent element as claimed in claim 2, in which said coumarinic derivative is represented by the structural formula (A1a-55) below, ##STR41##

Claim 5

An electroluminescent element as claimed in claim 2, in which said coumarinic derivative is represented by the structural formula (A1-ex2) below, ##STR42##

Claim 6

An electroluminescent element as claimed in claim 2, in which said coumarinic derivative is represented by the structural formula (A1-ex3) below, ##STR43##

Claim 7

An electroluminescent element as claimed in claim 3, in which said organic hole transport layer is made of a triphenylamine derivative represented by the formula (I) below, ##STR44##

Claim 8

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, ##STR45## wherein R 1 is selected from the group consisting of a hydrogen atom, a cyano group, a substituted or unsubstituted aryl group, an alkyl group, a carboxyl group, an acyloxy group and a heterocyclic group including one, two or three hetero atoms independently selected from oxygen atoms, sulfur atoms and nitrogen atoms, R 2 is selected from the group consisting of a hydrogen atom, an alkyl group, an acyloxy groups, a haloalkyl group, a carboxyl group, a cyano group and an acyl group, R 3 is a hydrogen atom, a hydroxyl group or an allyl group, R 4 and R 5 form a condensed ring together when R 5 is an amino group, and R 6 is a hydrogen atom or an alkyl group.

Claim 9

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, wherein R 1 is selected from the group consisting of a hydrogen atom, a cyano group, a substituted or unsubstituted aryl group, an alkyl group, a carboxyl group, an acyloxy group and a heterocyclic group including one, two or three hetero atoms independently selected from oxygen atoms, sulfur atoms and nitrogen atoms, R 2 is selected from the group consisting of a hydrogen atom, an alkyl group, an acyloxy group, a haloalkyl group, a carboxyl group, a cyano group and an acyl group, R 3 is a hydrogen atom, a hydroxyl group or an allyl group, R 4 is a hydrogen atom, an alkyl group, an alkoxyl group, a hydroxyl group, an allyl group or an acyl group, and R 5 and R 6 form a condensed ring together when R 5 is an amino group.

Claim 10

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, ##STR46## wherein R 1 is selected from the group consisting of a hydrogen atom, a cyano group, a substituted or unsubstituted aryl group, an alkyl group, a carboxyl group, an acyloxy group, an allyloxycarbonyl group, an acyl group and a heterocyclic group including one, two or three hetero atoms independently selected from oxygen atoms, sulfur atoms and nitrogen atoms, R 2 is selected from the group consisting of a hydrogen atom, an alkyl group, an acyloxy group, a haloalkyl group, a carboxyl group, a cyano group and an acyl group, R 3 is a hydrogen atom, hydroxyl group or allyl group, and R 4 , R 5 and R 6 form a condensed ring together when R 5 is an amino group.

Claim 11

An electroluminescent element as claimed in claim 9, in which said coumarinic derivative is represented by the structural formula (A1d-ex5) below, ##STR47##

Claim 12

An electroluminescent element as claimed in claim 10, in which said organic hole transport layer is made of a triphenylamine derivative represented by the formula (I) below, ##STR48##

Claim 13

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, ##STR49## wherein R 1 and R 2 form a condensed ring together R 3 is a hydrogen atom, a hydroxyl group or an allyl group, R 4 is a hydrogen atom, an alkyl group, an alkoxyl group, a hydroxyl group, an allyl group or an acyl group, R 5 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxyl group, an acyloxy group, an amino group, an alkylamino group, a dialkylamino group, an alkyl group unsubstituted or substituted by a sulfonium group, and an aromatic heterocyclic or five-membered ring group including two or three nitrogen atoms, and R 6 is a hydrogen atom or an alkyl group.

Claim 14

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, ##STR50## wherein R 1 and R 2 form a condensed ring together, R 3 is a hydrogen atom, a hydroxyl group or an allyl R 4 , R 5 and R 6 form a condensed ring together when R 5 is an amino group.

Claim 15

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is represented by the structural formula (A1) below, ##STR51## wherein R 1 is selected from the group consisting of a hydrogen atom, a cyano group, a substituted or unsubstituted aryl group, an alkyl group, a carboxyl group, an acyloxy group and a heterocyclic group including one, two or three hetero atoms independently selected from oxygen atoms, sulfur atoms and nitrogen atoms, R 2 is selected from the group consisting of a hydrogen atom, an alkyl group, an acyloxy group, a haloalkyl group, a carboxyl group, a cyano group and an acyl group, R 3 and R 4 form a condensed ring together, R 5 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxyl group, an hydrogen atom, a hydroxyl group, an alkoxyl group, an acyloxy group, an amino group, an alkylamino group, a dialkylamino group, an alkyl group unsubstituted or substituted by a sulfonium group, and an aromatic heterocyclic or five-membered ring group including two or three nitrogen atoms, and R 6 is a hydrogen atom or an alkyl group.

Claim 16

An electroluminescent element as claimed in claim 14, in which said coumarinic derivative is represented by the structural formula (A1f-ex4) below, ##STR52##

Claim 17

An electroluminescent element as claimed in claim 15, in which said organic hole transport layer is made of a triphenylamine derivative represented by the formula (I) below, ##STR53##

Claim 18

An electroluminescent element as claimed in claim 1, in which said coumarinic derivative is ##STR54## wherein R 9 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxyl group, an alkoxycarbonyl group, an amino group, an alkylamino group, a dialkylamino group and an alkyl group unsubstituted or substituted by a sulfonium group, and R 10 is a hydrogen atom or a cyano group.

Claim 19

An electroluminescent element as claimed in claim 17, in which said coumarinic derivative is represented by the structural formula (A4-ex1) below, ##STR55##

Claim 20

An electroluminescent element as claimed in claim 18, in which said organic hole transport layer is made of a triphenylamine derivative represented by the formula (I) below, ##STR56##

Claim 21

An electroluminescent element as claimed in claim 1, which further comprises an organic electron transport layer interposed between said cathode and said fluorescent substance layer.

Claim 22

An electroluminescent element as claimed in claim 1, wherein the fluorescent substance consists essentially of the coumarinic derivative.

Claim 23

An electroluminescent element as claimed in claim 1, wherein the fluorescent substance consists of the coumarinic derivative.

Claim 24

An electroluminescent element comprising a cathode, a fluorescent substance layer of organic compound, a hole transport layer of organic compound and an anode which are laminated in sequence, wherein the fluorescent substance layer predominantly comprises a azocoumarinic derivative that emits light efficiently at a high luminance upon application of a low voltage.

Claim 25

An electroluminescent element comprising a cathode, a fluorescent substance layer of organic compound, a hole transport layer of organic compound and an anode which are laminated in sequence, wherein the fluorescent substance layer predominantly comprises a azocoumarinic derivative that emits light efficiently at a high luminance upon application of a low voltage.

Claim 26

An electroluminescent element as claimed in claim 23, in which said azacoumarinic derivative is represented by the structural formula (A2) below, ##STR57## wherein X is a hydrogen atom or an alkyl group.

Claim 27

An electroluminescent element as claimed in claim 23, in which said azacoumarinic derivative is represented by the structural formula (A3) below, ##STR58## wherein R 7 is a hydrogen atom, an alkyl group or a cyano group, R 8 is an alkyl group or a cyano group, and X is selected from the group consisting of a hydroxyl group, an amino group, an alkylamino group, a dialkylamino group, and an aromatic heterocyclic or six-membered ring group including one oxygen atom and one nitrogen atom.

Claim 28

An electroluminescent element as claimed in claim 23, which further comprises an organic electron transport layer interposed between said cathode and said fluorescent substance layer.

Claim 29

An electroluminescent element as claimed in claim 23, wherein the fluorescent substance consists essentially of the coumarinic derivative.

Claim 30

An electroluminescent element as claimed in claim 23, wherein the fluorescent substance consists of the coumarinic derivative.