Photopolymerizable liquid photoimageable solder mask

Claim 2

A photopolymerizable composition which comprises: (a) a reaction product obtained by reacting an epoxy resin A containing at least two terminated epoxy groups with 0.8 to 1.2 mol, for each epoxy equivalent of epoxy resin A of an α,β-unsaturated carboxylic acid to form an esterified substance and then reacting the esterified substance with 0.2 to 1.0 mol, for each epoxy equivalent of epoxy resin A, of polybasic acid anhydride, (b) diluent, (c) sensitizer, (d) epoxy resin B consisting of tris (2,3-epoxypropyl) isocyanurate having a melting point in the range of 90°-130° C., and (e) an epoxy resin curing agent represented by the general formula (I): ##STR9## wherein R is --, H, halogen --NH 2 , --SH, an aromatic hydrocarbon, a C 1 -C 4 alkyl or NHR' wherein R' is a C 1 -C 4 alkyl, --CN or NH 2 C═NH.

Claim 3

The composition of claim 1 comprising 40-60 wt. % of said (a) component, 10-50 wt. % of said (b) component, 3-10 wt. % of said (c) component, 10-20 wt. % of said (d) component, and 0.5-3 wt. % of said (e) component.

Claim 4

The composition of claim 1 or 2 wherein said epoxy resin A of said (a) component is a novolak-type epoxy resin whose melting point is 65°-90° C. and is represented by the general formula (II): ##STR10## wherein R is hydrogen or methyl.

Claim 5

The composition of claim 1 or 2 wherein said epoxy resin A of said (a) component is a mixture of novolak-type epoxy resin whose melting point is 65°-90° C. and is represented by the general formula: ##STR11## wherein R is hydrogen or methyl and, a bisphenol type epoxy resin whose melting point is 65°-130° C. and is represented by formula: ##STR12##

Claim 6

The composition of claim 4 wherein a weight ratio range of the novolak-type epoxy resin and the bisphenol type epoxy resin is 95:5 to 50:50.

Claim 7

The composition of claim 1 capable of being developed by a dilute alkali aqueous solution.

Claim 8

The composition of claim 1 wherein the α,β unsaturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid and cinnamic acid.

Claim 9

The composition of claim 1 wherein the α,β-unsaturated carboxylic acid is acrylic acid.

Claim 10

The composition of claim 1 wherein the polybasic acid anhydride is selected from the group consisting of hexahydrophthalic acid anhydride, 3-methyl hexahydrophthalic acid anhydride, 4-methyl hexahydrophthalic acid anhydride, 3-ethyl hexahydrophthalic acid anhydride, 4-ethyl hexahydrophthalic acid anhydride, tetrahydrophthalic acid anhydride, 3-methyl tetrahydrophthalic acid anhydride, 4-methyl tetrahydrophthalic acid anhydride, 3-ethyl tetrahydrophthalic acid anhydride and 4-ethyl tetrahydrophthalic acid anhydride.

Claim 11

The composition of claim 1 wherein the diluent is unsaturated compound or an organic solvent.

Claim 12

The composition of claim 1 wherein the diluent comprises 1-5% unsaturated compounds.

Claim 13

The composition of claim 1 wherein the sensitizer comprises the combination of 2-methyl-{4-(methylthio) phenyl}-2-morpholino-1-propanone with one or two of the compounds selected from the group consisting of p-phenylbenzophenone, benzyl dimethyl ketal, 2,4-dimethyl thioxanthone, 2-isopropyl thioxanthone-benzoin ethylether, benzoin isopropylether, benzoin isobutylether, 4,4'-diethylamino benzophenone and p-dimethylamino benzoic acid ethylester.

Claim 14

The composition of claim 1 wherein the curing agent is selected from the group consisting of melamine, guanamine, acetoguanamine, benzoguanamine, ethyldiamino-S-triazine, 2,4-diamino-S-triazine, 2,4-diamino-6-Xylyl-5-triazine and 2,4-diamino-6tolyl-S-triazine.

Claim 15

The composition of claim 1 wherein the diluent is selected from the group consisting of ethyleneglycol dimethacrylate, diethyleneglycol dimethacrylate, glycreine trimethacrylate, 1,3-propylene dimethacrylate, 1,2,4-butanetriol trimethacrylate, 1,4-benzenediol dimethacrylate, bismethacrylate of polyethyleneglycol of 200-500 molecular weight, trimethylolpropane trimethacrylate, pentaerythritol tetramethacrylate, dipentaerythritol hexamethacrylate, methylenebismethacrylamide, diethylenetriamine trimetharylamide-bis(methacryl amidopropoxy) ethane, bismethacrylamide ethylmethacrylate, N-[(β-hydroxyethyloxy) ethyl ] acrylamide, divinyl phthalate, divinyl telephthalate, divinyl benzene-1,3-disulfonate, divinylbutane-1,4-disulfonate, triallyl isocyanurate, trimethacryl isocyanurate, xylylene bis (diallyl isocyanurate), tris (2,3-dibromopropyl) isocyanurate, tris (3-mercaptopropyl isocyanurate, ethyleneglycol monoalkylethers, diethyleneglycol monoalkylether, ethyleneglycol dialkylethers, diethyleneglycol dialkylethers, ethyleneglycol monoalkylether acetates, diethyleneglycol monoalkylether acetates, cyclohexanone, tetrahydronaphthalene, and petroleum naphtha.