Dye-benzyltriaryl borate photoinitiators and photohardenable composition containing these photoinitiators

Claim 2

A photohardenable composition which comprises a free radical polymerizable or crosslinkable compound and a photoinitiator complex comprising a cationic dye moiety and an anionic borate moiety, said complex being represented by the formula (I): ##STR4## where Y 1 and Y 2 are the same or different and represent an oxygen atom, a sulfur atom, a selenium atom, a vinyl group, >C(CH 3 ) 2 , or >N-R 7 where R 7 is a short chain alkyl group; n is 0, 1, 2 or 3; z is 1 to 4; R 5 and R 6 represent alkyl groups; X is a hydrogen atom, an electron withdrawing group or an electron donating group; R 1 is a benzyl or substituted benzyl group; and R 2 , R 3 and R 4 are aryl or substituted aryl groups, wherein said photoinitiator is capable of absorbing actinic radiation and producing free radicals which can initiate free radical polymerization or crosslinking or said polymerizable or crosslinkable compound.

Claim 3

The photohardenable composition of claim 1 wherein the anioinc borate moiety of said photoinitiator complex is benzyltriphenylborate and said cationic dye moiety is selected from the group consisting of cationic cyanine, carbocyanine and hemicyanine dyes.

Claim 4

The photohardenable composition of claim 2 wherein said anionic borate moiety and said cationic dye moiety are present as a complex in an amount up to about 1% by weight based on the weight of the photopolymerizable or crosslinkable species in the photohardenable composition.

Claim 5

The photohardenable composition of claim 3 wherein said anionic borate moiety and said cationic dye moiety are present as a complex in an amount of from about 0.2% to 0.5% by weight based on the weight of the photopolymerizable or crosslinkable species in the photohardenable composition.

Claim 6

The photohardenable composition of claim 2, wherein said photohardenable composition is employed in a negative working system.

Claim 7

The photohardenable composition of claim 1 wherein said photohardenable composition is microencapsulated.

Claim 8

The photohardenable composition of claim 6 wherein said photoinitiator additionally comprises an autooxidizer.

Claim 9

A photosensitive material comprising a support having a layer of photohardenable composition on the surface thereof, said composition comprising a free radical addition polymerizable or crosslinkable compound and a photoinitiator complex comprising a cationic dye moiety and an anionic borate moiety, said complex being ##STR5## where Y 1 and Y 2 are the same or different and represent an oxygen atom, a sulfur atom, a selenium atom, a vinyl group, >C(CH 3 ) 2 , or >N-R 7 wherein R 7 is a short chain alkyl group; n is 0, 1, 2, or 3; z is 1 to 4; R 5 and R 6 represent alkyl groups; and X is a hydrogen atom, an electron withdrawing group or an electron donating group; R 1 is a benzyl or substituted benzyl group; and R 2 , R 3 and R 4 are aryl or substituted aryl groups, wherein said photoinitiator is capable of absorbing actinic radiation and producing free radicals which can initiate free radical polymerization or crosslinking of said polymerizable or crosslinkable compound.

Claim 10

A photosensitive material comprising a support having a layer of photohardenable composition on the surface thereof, said composition comprising a free radical addition polymerizable or crosslinkable compound and a photoinitiator complex comprising a cationic dye moiety and an anionic borate moiety, said complex being ##STR5## where Y 1 and Y 2 are the same or different and represent an oxygen atom, a sulfur atom, a selenium atom, a vinyl group, >C(CH 3 ) 2 , or >N-R 7 wherein R 7 is a short chain alkyl group; n is 0, 1, 2, or 3; z is 1 to 4; R 5 and R 6 represent alkyl groups; and X is a hydrogen atom, an electron withdrawing group or an electron donating group; R 1 is a benzyl or substituted benzyl group; and R 2 , R 3 and R 4 are aryl or substituted aryl groups, wherein said photoinitiator is capable of absorbing actinic radiation and producing free radicals which can initiate free radical polymerization or crosslinking of said polymerizable or crosslinkable compound.

Claim 11

The photosensitive material of claim 8 wherein the anionic borate moiety of said photoinitiator complex is benzyltriphenylborate and said cationic dye moiety is selected from the group consisting of cationic cyanine, carbocyanine and hemicyanine dyes.

Claim 12

The photosensitive material of claim 9, wherein said photosensitive material is employed in a negative working system.