Patent US5100746A successfully refreshed from Google Patents.
US5100746A
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US
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Process for production of a multi-layer assembly for an electrochemical generator
Assignee: Hydro-Québec
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Filing: 1988-06-16
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Granted: 1992-03-31
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Expires: 2008-06-16
Abstract
Abstract Electrochemical cells containing lithium and a solid polymer electrolyte in the form of thin films are produced by making multilayer assemblies from double-layer solid polymer electrolyte/composite positive electrode sub-assemblies which are subsequently associated with the other constituent layers of the cell so that the multilayer assembly so obtained comprises a layer of a metal of low ductility. Cells may be made from multilayer assemblies by stacking, rolling or bending techniques.
Inventors
- 👤 Daniel Muller
- 👤 Michel Gauthier
- 👤 Bruno Kapfer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 11:15
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/04; H01M10/0436; H01M10/0431; H01M6/00; H01M6/14; H01M6/18; H01M6/181; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02P; Y02P70/00; Y02P70/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/49112; Y10T29/49115
Claims Analysis
Total Claims: 62
Claim 1
Independent Claim
121 words
A multi-layer assembly for carrying out assembly, by coiling, stacking or folding, of thin-film electrochemical generators with solid polymer electrolyte, includes a layer of metal with low ductility and another five layers, said five layers comprising two composite positive electrode layers, two solid polymer electrolyte layers and one layer of lithium or ductile lithium-base alloy, the five layers being arranged in such a manner in the multi-layer assembly that at least one of the two solid polymer electrolyte layers is separated from the layer of metal with low ductility by a composite positive electrode layer, and that the layer of lithium or ductile lithium-base alloy is separated from at least one composite positive electrode layer by a solid polymer electrolyte layer.
Claim 2
Dependent Claim
121 words
A multi-layer assembly for carrying out assembly, by coiling, stacking or folding, of thin-film electrochemical generators with solid polymer electrolyte, includes a layer of metal with low ductility and another five layers, said five layers comprising two composite positive electrode layers, two solid polymer electrolyte layers and one layer of lithium or ductile lithium-base alloy, the five layers being arranged in such a manner in the multi-layer assembly that at least one of the two solid polymer electrolyte layers is separated from the layer of metal with low ductility by a composite positive electrode layer, and that the layer of lithium or ductile lithium-base alloy is separated from at least one composite positive electrode layer by a solid polymer electrolyte layer.
Claim 3
Dependent Claim
43 words
A multi-layer assembly according to claim 1, wherein the two composite positive electrode layers, the two solid polymer electrolyte layers and the layer of lithium or ductile lithium-base alloy are located on the same side of the layer of metal with low ductility.
Claim 4
Dependent Claim
67 words
A multi-layer assembly according to claim 2, wherein one composite positive electrode layer, one solid polymer electrolyte layer and the layer of lithium or ductile lithium-base alloy are arranged on the same side of the layer of metal with low ductility, while one composite positive electrode layer and one solid polymer electrolyte layer are arranged on the other side of the layer of metal with low ductility.
Claim 5
Dependent Claim
111 words
A multi-layer assembly for carrying out assembly, by coiling, stacking or folding, of thin-film electrochemical generators with solid polymer electrolyte, comprising a layer of metal with low ductility and another three layers, said three layers comprising a composite positive electrode layer, a solid polymer electrolyte layer and a layer of lithium or ductile lithium-base alloy, wherein said solid polymer electrolyte is sandwiched between the composite positive electrode layer and the layer of lithium or ductile lithium-base alloy, and wherein the layer of metal with low ductility is in contact with the layer of lithium or ductile lithium-base alloy, the metal with low ductility being one which does not react with lithium.
Claim 6
Dependent Claim
111 words
A multi-layer assembly for carrying out assembly, by coiling, stacking or folding, of thin-film electrochemical generators with solid polymer electrolyte, comprising a layer of metal with low ductility and another three layers, said three layers comprising a composite positive electrode layer, a solid polymer electrolyte layer and a layer of lithium or ductile lithium-base alloy, wherein said solid polymer electrolyte is sandwiched between the composite positive electrode layer and the layer of lithium or ductile lithium-base alloy, and wherein the layer of metal with low ductility is in contact with the layer of lithium or ductile lithium-base alloy, the metal with low ductility being one which does not react with lithium.
Claim 7
Dependent Claim
31 words
A thin-film lithium electrochemical generator produced by a technique of coiling, stacking or folding, based on at least one of the multi-layer assemblies according to one of claims 1 to 4.
Claim 8
Dependent Claim
23 words
A generator according to claim 5, obtained by coiling or folding a multi-layer assembly or by stacking a plurality of such multi-layer assemblies.
Claim 9
Dependent Claim
48 words
A generator according to claim 5, obtained by stacking a plurality of multi-layer assemblies, with the layer of metal with low ductility on top of the electrode layer of the adjacent assembly, and by applying a positive electrode collector tot he last free layer of a positive electrode.
Claim 10
Dependent Claim
56 words
A generator according to claim 5, obtained by applying a multi-layer assembly to each of the sides of a layer of metal with low ductility, working in such a way that the positive electrode layer of each of the assemblies applied to the layer of metal with low ductility comes into contact with the said metal.
Claim 11
Dependent Claim
138 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) producing an electrolyte/electrode sub-assembly, which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer and which is supported, on the electrode side, on a carrier consisting of peel-away plastic film made of an inert plastic material and having good mechanical resistance, b) applying a layer of lithium or of a ductile alloy based on lithium to the electrolyte layer of the supported electrode/electrolyte sub-assembly, c) removing the plastic film which covers the electrode layer of the said sub-assembly, and d) applying the layer of metal with low ductility to the said electrode layer.
Claim 12
Dependent Claim
138 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) producing an electrolyte/electrode sub-assembly, which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer and which is supported, on the electrode side, on a carrier consisting of peel-away plastic film made of an inert plastic material and having good mechanical resistance, b) applying a layer of lithium or of a ductile alloy based on lithium to the electrolyte layer of the supported electrode/electrolyte sub-assembly, c) removing the plastic film which covers the electrode layer of the said sub-assembly, and d) applying the layer of metal with low ductility to the said electrode layer.
Claim 13
Dependent Claim
47 words
A process according to claim 9 wherein the layer of lithium or ductile lithium-base alloy which is applied to the supported electrolyte/electrode sub-assembly is also supported by a peel-away plastic film which covers the side of the layer which does not come into contact with the sub-assembly.
Claim 14
Dependent Claim
26 words
A process according to claim 9 wherein the electrolyte side of a second electrolyte/electrode sub-assembly is applied to the layer of lithium or ductile lithium-base alloy.
Claim 15
Dependent Claim
29 words
A process according to claim 9 wherein the electrode side of a second electrolyte/electrode sub-assembly is applied to the free side of the layer of metal with low ductility.
Claim 16
Dependent Claim
55 words
A process according to one of claims 11, 12 or 9 wherein application one on the other of the electrolyte/electrode sub-assembly or sub-assemblies, of the layer of lithium or ductile lithium-based alloy, and of the layer of metal with low ductility, is carried out by lamination between rollers of at least one pair of rollers.
Claim 17
Dependent Claim
46 words
A process according to claim 12, wherein the second sub-assembly which is applied to the free side of the layer of metal with low ductility is also covered by a peel-away plastic film on the electrode side, which is removed before this application is carried out.
Claim 18
Dependent Claim
36 words
A process according to claim 10, wherein the electrolyte side of a second electrolyte/electrode sub-assembly is applied to the layer of lithium or ductile lithium-based alloy, after having removed the plastic film covering the said layer.
Claim 19
Dependent Claim
26 words
A process according to claim 11, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 20
Dependent Claim
26 words
A process according to claim 12, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 21
Dependent Claim
26 words
A process according to claim 15, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 22
Dependent Claim
46 words
A process according to claim 17, wherein the second sub-assembly which is applied to the free side of the layer of metal with low ductility is also covered by a peel-away plastic film on the electrode side, which is removed before this application is carried out.
Claim 23
Dependent Claim
21 words
A process according to claim 9 or 10 or 14, wherein each peel-away plastic film is made of polyethylene or polypropylene.
Claim 24
Dependent Claim
23 words
A process according to claim 16 or 18 or 17 or 19, wherein each peel-away plastic film is made of polyethylene or polypropylene.
Claim 25
Dependent Claim
35 words
A process according to claim 9 or 11 or 14, wherein the layer of metal with low ductility is made of a metal selected from the group consisting of nickel, copper, aluminum and stainless steel.
Claim 26
Dependent Claim
14 words
A multi-layer assembly obtained by the process of claim 9 or 11 or 12.
Claim 27
Dependent Claim
31 words
A thin-film lithium electrochemical generator obtained by coiling or folding a multi-layer assembly obtained by the process of claim 11 or 12 or by stacking a plurality of such multi-layer assemblies.
Claim 28
Dependent Claim
108 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) producing an electrolyte/electrode sub-assembly, which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer and which is supported, on the electrode side, on a carrier made of a metal with low ductility, and b) applying by lamination between at least two rollers a layer of lithium or of a ductile alloy based on lithium to the electrolyte layer of the supported electrode/electrolyte sub-assembly.
Claim 29
Dependent Claim
108 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) producing an electrolyte/electrode sub-assembly, which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer and which is supported, on the electrode side, on a carrier made of a metal with low ductility, and b) applying by lamination between at least two rollers a layer of lithium or of a ductile alloy based on lithium to the electrolyte layer of the supported electrode/electrolyte sub-assembly.
Claim 30
Dependent Claim
47 words
A process according to claim 25 wherein the layer of lithium or ductile lithium-base alloy which is applied to the supported electrolyte/electrode sub-assembly is also supported by a peel-away plastic film which covers the side of the layer which does not come into contact with the sub-assembly.
Claim 31
Dependent Claim
26 words
A process according to claim 25 wherein the electrolyte side of a second electrolyte/electrode sub-assembly is applied to the layer of lithium or ductile lithium-base alloy.
Claim 32
Dependent Claim
30 words
A process according to claim 25 wherein the electrode side of a second electrolyte/ electrode sub-assembly is applied to the free side of the layer of metal with low ductility.
Claim 33
Dependent Claim
46 words
A process according to claim 28, wherein the second sub-assembly which is applied to the free side of the layer of metal with low ductility is also covered by a peel-away plastic film on the electrode side, which is removed before this application is carried out.
Claim 34
Dependent Claim
36 words
A process according to claim 26, wherein the electrolyte side of a second electrolyte/electrode sub-assembly is applied to the layer of lithium or ductile lithium-based alloy, after having removed the plastic film covering the said layer.
Claim 35
Dependent Claim
26 words
A process according to claim 27, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 36
Dependent Claim
26 words
A process according to claim 30, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 37
Dependent Claim
26 words
A process according to claim 28, wherein said second sub-assembly is supported on a peel-away plastic film, which is removed at the end of the operation.
Claim 38
Dependent Claim
46 words
A process according to claim 33 wherein the second sub-assembly which is applied to the free side of the layer of metal with low ductility is also covered by a peel-away plastic film on the electrode side, which is removed before this application is carried out.
Claim 39
Dependent Claim
21 words
A process according to claim 25 or 26 or 29, wherein each peel-away plastic film is made of polyethylene or polypropylene.
Claim 40
Dependent Claim
23 words
A process according to claim 30 or 31 or 32 or 33, wherein each peel-away plastic film is made of polyethylene or polypropylene.
Claim 41
Dependent Claim
35 words
A process according to claim 25 or 26 or 28, wherein the layer of metal with low ductility is made of a metal selected from the group consisting of nickel, copper, aluminum and stainless steel.
Claim 42
Dependent Claim
14 words
A multi-layer assembly obtained by the process of claim 25, or 27 or 28.
Claim 43
Dependent Claim
30 words
A thin-film lithium electrochemical generator obtained by coiling or folding a multi-layer assembly obtained by the process of claim 27 or 28 or by stacking plurality of such multi-layer assemblies.
Claim 44
Dependent Claim
110 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) applying on both sides of a carrier consisting of a layer of a metal with low ductility the electrode side of an electrolyte/electrode sub-assembly, said sub-assembly having the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer, and b) applying a layer of lithium or of a ductile alloy based on lithium to one of the electrolyte/electrode sub-assemblies associated with the layer of metal with low ductility.
Claim 45
Dependent Claim
110 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) applying on both sides of a carrier consisting of a layer of a metal with low ductility the electrode side of an electrolyte/electrode sub-assembly, said sub-assembly having the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite positive electrode layer, and b) applying a layer of lithium or of a ductile alloy based on lithium to one of the electrolyte/electrode sub-assemblies associated with the layer of metal with low ductility.
Claim 46
Dependent Claim
48 words
A process according to claim 40, wherein the layer of lithium or ductile lithium-based alloy is supported by a peel-away plastic film, which covers that side of said layer which does not come into contact with the electrolyte, and which is removed at the end of the operation.
Claim 47
Dependent Claim
30 words
A process according to claim 40, wherein each electrode/electrolyte sub-assembly is supported on the electrolyte side by a peel-away plastic film, which is removed at the end of the operation.
Claim 48
Dependent Claim
60 words
A process according to claim 41, wherein the application of the electrolyte/electrode sub-assemblies to the layer of metal with low ductility and the application of the layer of lithium or of ductile lithium-based alloy to one of the electrode/electrolyte sub-assemblies associated with the layer of metal with low ductility are each carried out by lamination between at least two rollers.
Claim 49
Dependent Claim
31 words
A process according to claim 42, wherein the layer of metal with low ductility is made of a metal selected from the group consisting of nickel, copper, aluminum and stainless steel.
Claim 50
Dependent Claim
19 words
A process according to claim 41 or 42, wherein the peel-away plastic film is made of polyethylene or polypropylene.
Claim 51
Dependent Claim
10 words
A multi-layer assembly obtained by the process of claim 45.
Claim 52
Dependent Claim
51 words
A thin-film lithium electrochemical generator obtained by stacking a plurality of multi-layer assemblies according to claim 46, with the layer of metal with low ductility on top of the electrode layer of the adjacent assembly, and by applying a positive electrode collector to the last free layer of a positive electrode.
Claim 53
Dependent Claim
58 words
A thin-film lithium electrochemical generator obtained by applying a multi-layer assembly according to claim 46, to each of the sides of a layer of metal with low ductility, working in such a way that the positive electrode layer of each of the assemblies applied to the layer of metal with low ductility comes into contact with said metal.
Claim 54
Dependent Claim
10 words
A multi-layer assembly obtained by the process of claim 40.
Claim 55
Dependent Claim
26 words
A thin-film lithium electrochemical generator obtained by coiling or folding a multi-layer assembly according to claim 49 or by stacking a plurality of such multi-layer assemblies.
Claim 56
Dependent Claim
106 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) applying a layer of lithium or of a ductile alloy based on lithium to one of the sides of a layer of a metal with low ductility which does not react with lithium, and b) applying to said layer of lithium or ductile lithium-based alloy the electrolyte side of an electrolyte/electrode sub-assembly which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite electrode layer.
Claim 57
Dependent Claim
106 words
A process for the production of a multi-layer assembly which can be used for the assembly, by stacking, coiling or folding, of thin-film lithium electrochemical generators having a solid polymer electrolyte, which comprises: a) applying a layer of lithium or of a ductile alloy based on lithium to one of the sides of a layer of a metal with low ductility which does not react with lithium, and b) applying to said layer of lithium or ductile lithium-based alloy the electrolyte side of an electrolyte/electrode sub-assembly which has the form of a two-layer assembly comprising a solid polymer electrolyte layer adhered to a composite electrode layer.
Claim 58
Dependent Claim
51 words
A process according to claim 51, wherein the layer of lithium or ductile lithium-based alloy is supported by a peel-away plastic film which covers the side of said layer which does not come into contact with the metal with low ductility, said film being removed before application of the electrolyte/electrode sub-assembly.
Claim 59
Dependent Claim
32 words
A process according to claim 51, wherein the electrolyte/electrode sub-assembly is supported on the electrode side by a peel-away plastic film, which is removed, or not, at the end of the operation.
Claim 60
Dependent Claim
50 words
A process according to claim 51, wherein the application of the lithium or ductile lithium-based alloy to the layer of metal with low ductility and the application of the electrolyte/electrode sub-assembly to the layer of lithium or ductile lithium-based alloy are each performed by lamination between at least two rollers.
Claim 61
Dependent Claim
30 words
A process according to claim 51, wherein the layer of metal with low ductility is made of a metal selected from the group consisting of nickel, copper and stainless steel.
Claim 62
Dependent Claim
19 words
A process according to claim 52 or 53, wherein the peel-away plastic film is made of polyethylene or polypropylene.
References Cited (Backward Citations)
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US4345954A
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GB2148586A
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EP0146245A1
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EP0147929A1
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-03-31 | 1995-09-30 | 1996-03-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-03-31 | 1999-09-30 | 2000-03-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-03-31 | 2003-09-30 | 2004-03-31 | $7700.00 | Window Closed / Lapsed |