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US5099044A Expired / Lapsed US ⏱️ 0.0 years remaining

Organometallic compounds

Assignee: Merck Patent GmbH
•
Filing: 1989-11-27
•
Granted: 1992-03-24
•
Expires: 2009-11-27
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Abstract

Abstract The invention relates to organometallic compounds which are intramolecularly stabilized, and also to their use for the production of thin films and epitaxial layers by gas-phase deposition.

Inventors

  • 👤 Dietrich Erdmann
  • 👤 Ludwig Pohl
  • 👤 Martin Hostalek

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:54
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/06; C23C16/18; C07; C07F; C07F5/00; C07F5/06; C07F5/061; C07F5/062; C23C16/20; C23C16/22; C23C16/30; C23C16/301

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 83 words
Organometallic compounds of the formula I: ##STR6## wherein M denotes aluminum, indium or gallium, Y denotes --NR 3 R 4 , --PR 3 R 4 , --AsR 3 R 4 , --SbR 3 R 4 , --F or a perfluorinated alkyl group containing 1-7 carbon atoms, X denotes, if Y=--F or a perfluorinated alkyl group containing 1-7 carbon atoms: --(CHR 5 ) n where n=1, 2, 3, 4 or 5, o--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --,
Claim 2
Dependent Claim 83 words
Organometallic compounds of the formula I: ##STR6## wherein M denotes aluminum, indium or gallium, Y denotes --NR 3 R 4 , --PR 3 R 4 , --AsR 3 R 4 , --SbR 3 R 4 , --F or a perfluorinated alkyl group containing 1-7 carbon atoms, X denotes, if Y=--F or a perfluorinated alkyl group containing 1-7 carbon atoms: --(CHR 5 ) n where n=1, 2, 3, 4 or 5, o--(CH 2 ) p --C 6 H 4 --(CH 2 ) q --,
Claim 3
Dependent Claim 340 words
2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --, or if Y=--NR 3 R 4 , --PR 3 R 4 , --AsR 3 R 4 or --SbR 3 R 4 : o--C 6 H 4 --, 1,2--C 6 H 10 --, o--(CH 2 ) r --C 6 H 4 --(CH 2 ) s --, 1,2--(CH 2 ) r --C 6 H 10 --(CH 2 ) s --, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q -- or 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --, r and s in each case denote, independently of each other, 1, 2 or 3, p and q in each case denote, independently of each other, 0, 1, 2 or 3, R 1 , R 2 , R 3 and R 4 in each case denote, independently of each other, an alkyl group or alkenyl group containing up to 8 carbon atoms, it being possible for these groups to be partially or completely fluorinated, a cycloalkyl group or cycloalkenyl group containing 3-8 carbon atoms or a phenyl group, and R 5 in each case denotes H or an alkyl group containing 1-4 carbon atoms, which may also be partially or completely fluorinated.
Claim 4
Dependent Claim 340 words
2--(CH 2 ) p --C 6 H 10 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --, or if Y=--NR 3 R 4 , --PR 3 R 4 , --AsR 3 R 4 or --SbR 3 R 4 : o--C 6 H 4 --, 1,2--C 6 H 10 --, o--(CH 2 ) r --C 6 H 4 --(CH 2 ) s --, 1,2--(CH 2 ) r --C 6 H 10 --(CH 2 ) s --, 1,2--(CH 2 ) p --C 6 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 6 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 8 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 6 --(CH 2 ) q --, 1,2--(CH 2 ) p --C 5 H 4 --(CH 2 ) q -- or 1,2--(CH 2 ) p --C 4 H 6 --(CH 2 ) q --, r and s in each case denote, independently of each other, 1, 2 or 3, p and q in each case denote, independently of each other, 0, 1, 2 or 3, R 1 , R 2 , R 3 and R 4 in each case denote, independently of each other, an alkyl group or alkenyl group containing up to 8 carbon atoms, it being possible for these groups to be partially or completely fluorinated, a cycloalkyl group or cycloalkenyl group containing 3-8 carbon atoms or a phenyl group, and R 5 in each case denotes H or an alkyl group containing 1-4 carbon atoms, which may also be partially or completely fluorinated.
Claim 5
Dependent Claim 33 words
The use of the organometallic compounds of the formula I according to claim 1 for the gas-phase deposition of the metal of the main group III or of a III-V combination on substrates.
Claim 6
Dependent Claim 20 words
The use of the organometallic compounds of the formula I according to claim 1 for the deposition of epitaxial layers.
Claim 7
Dependent Claim 46 words
Process for the production of thin films on substrates by gas-phase deposition of the metal of the main group III or of a III-V combination from organometallic compounds, characterized in that the compounds of the formula I according to claim 1 are used as organometallic compounds.
Claim 8
Dependent Claim 43 words
Process according to claim 4, characterized in that one or more compounds of arsenic, antimony or phosphorus which are gaseous under the reaction conditions used are supplied for the production of compound semiconductors, and of optical and opto-electronic components during the deposition process.
Claim 9
Dependent Claim 24 words
Process according to claim 4, characterized in that dopants are added additionally to the organometallic compounds of the formula I during the deposition process.
Claim 10
Dependent Claim 26 words
Process according to claim 4, characterized in that the compounds of the formula I are added as dopants during the deposition process of other organometallic compounds.

References Cited (Backward Citations)

DE3631469A1 Cited
EP0342444A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-03-24 1995-09-23 1996-03-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-03-24 1999-09-23 2000-03-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-03-24 2003-09-23 2004-03-24 $7700.00 Window Closed / Lapsed

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