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US5089537A Expired / Lapsed US ⏱️ 0.0 years remaining

UV curable silicone emulsions

Assignee: Dow Silicones Corp
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Filing: 1989-05-22
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Granted: 1992-02-18
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Expires: 2009-05-22
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Abstract

Abstract A silicone emulsion is prepared by emulsion polymerizing a hydroxyl endblocked polydiorganosiloxane oligomer with a combination of a siloxane or siloxane precursor containing unsaturated hydrocarbon groups and a functional silicone selected from the group consisting of organosilicon hydrides and mercaptoalkylsilanes or siloxanes, or with an acryl or methacryl functional siloxane. When the emulsion of the copolymer produced is combined with a photoinitiator, the copolymer can be crosslinked by exposure to ultraviolet radiation. When the water is removed, an elastomer results. The emulsion can be used to produce coatings and sealants.

Inventors

  • 👤 Donald T. Liles

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:16
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/24; C08J3/26; C08G; C08G77/00; C08G77/04; C08G77/06; C08G77/20; C08G77/22; C08G77/28; C08L; C08L83/00; C08L83/04; C08L83/08; C08G77/12; C08G77/14; C08G77/16; C08J2383/00; C08J2383/04

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 110 words
An aqueous silicone emulsion comprising a continuous water phase, a dispersed phase, and sufficient surfactant to form a stable emulsion; the dispersed phase consisting essentially of a hydroxyl endblocked polydiorganosiloxane having a molecular weight above 50,000 and containing both non-conjugated unsaturated hydrocarbon group substituted siloxane units, in which said unsaturated hydrocarbon groups there are from 2 to 6 carbon atoms, selected from the group consisting of vinyl, allyl, and hexenyl radicals; and either hydrogen on silicon substituted siloxane units or mercaptoalkylsiloxane units; and a photoinitiator, in the same dispersed particles; which emulsion, when crosslinked by exposure to ultraviolet light, produces an elastomer upon removal of the water at room temperature.
Claim 2
Dependent Claim 110 words
An aqueous silicone emulsion comprising a continuous water phase, a dispersed phase, and sufficient surfactant to form a stable emulsion; the dispersed phase consisting essentially of a hydroxyl endblocked polydiorganosiloxane having a molecular weight above 50,000 and containing both non-conjugated unsaturated hydrocarbon group substituted siloxane units, in which said unsaturated hydrocarbon groups there are from 2 to 6 carbon atoms, selected from the group consisting of vinyl, allyl, and hexenyl radicals; and either hydrogen on silicon substituted siloxane units or mercaptoalkylsiloxane units; and a photoinitiator, in the same dispersed particles; which emulsion, when crosslinked by exposure to ultraviolet light, produces an elastomer upon removal of the water at room temperature.
Claim 3
Dependent Claim 10 words
The emulsion of claim 1 which also includes a filler.
Claim 4
Dependent Claim 21 words
The emulsion of claim 1 which has been exposed to sufficient ultraviolet light to cause the dispersed phase to become crosslinked.

References Cited (Backward Citations)

US4370160A Cited
US4248751A Cited
US4273634A Cited
US4962153A Cited
US4978710A Cited
JPH01228064A Cited
US4954565A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-02-17 1995-08-19 1996-02-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-02-17 1999-08-19 2000-02-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-02-17 2003-08-19 2004-02-18 $7700.00 Window Closed / Lapsed

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