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US5089531A
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US
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Compositions incorporating a salt of monoester of citric acid and a method for synthesizing the monoester
Assignee: Chesebrough Ponds Inc
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Filing: 1989-07-07
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Granted: 1992-02-18
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Expires: 2009-07-07
Abstract
Abstract A skin treatment composition comprising a physiologically acceptable carrier and 1-35% by weight of a salt of a monoester of citric acid. The skin treatment composition imparts a pleasant smoothness to the skin and may be incorporated in several products to treat skin dryness. The hydrophobic group having an ester linkage to citric acid has 10 to 18 carbon atoms. Monoester of citric acid may be synthesized with low levels of di- and triester by forming citric acid anhydride and reacting this to form the monoester.
Inventors
- 👤 Ira Weil
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:33
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/02; A61K8/0216; A61K8/0229; A61K8/18; A61K8/30; A61K8/33; A61K8/37; A61Q; A61Q19/00; A61Q19/007; C; C11; C11D; C11D1/00; C11D1/02; C11D1/04; C11D1/08; C11D17/00; C11D17/0047; C11D17/006; C11D9/00; C11D9/04; C11D9/22; C11D9/26
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
97 words
A skin treatment composition comprising from about 1% to about 35% by weight of a dication salt of a monoester of citric acid having one of the following formulae: ##STR5## where R 1 has the structure of a moiety derived from R 1 -OH, which alcohol is selected from the group consisting of alkanols, alkenols an arylalkanols having from 10 to 18 carbon atoms; each M is a cation selected from the group consisting of the alkali metals, the alkaline earth metals, ammonium, substituted ammonium and a mixture thereof; and a physiologically acceptable carrier for said monoester.
Claim 2
Dependent Claim
97 words
A skin treatment composition comprising from about 1% to about 35% by weight of a dication salt of a monoester of citric acid having one of the following formulae: ##STR5## where R 1 has the structure of a moiety derived from R 1 -OH, which alcohol is selected from the group consisting of alkanols, alkenols an arylalkanols having from 10 to 18 carbon atoms; each M is a cation selected from the group consisting of the alkali metals, the alkaline earth metals, ammonium, substituted ammonium and a mixture thereof; and a physiologically acceptable carrier for said monoester.
Claim 3
Dependent Claim
32 words
The skin treatment composition according to claim 1 wherein R 1 -OH is selected from the group consisting of straight hydrocarbon chain alkanols and alkenols having from 10 to 18 carbon atoms.
Claim 4
Dependent Claim
26 words
The skin treatment composition according to claim 1 wherein R 1 -OH is selected from the group consisting of alkanols and alkenols having 12-15 carbon atoms.
Claim 5
Dependent Claim
15 words
The skin treatment composition according to claim 1 wherein R 1 -OH is lauryl alcohol.
Claim 6
Dependent Claim
28 words
The skin treatment composition according to claim 1 wherein the monoester of citric acid is comprised of symmetrical and unsymmetrical isomers in a relative ratio of about 3:1.
Claim 7
Dependent Claim
45 words
The skin treatment composition according to claim 1 wherein the skin treatment composition comprises a pharmaceutically acceptable carrier and from about 1 to 35% by weight of a salt of an ester of citric acid, the ester consisting essentially of the monoester of citric acid.
Claim 8
Dependent Claim
40 words
The skin treatment composition according to claim 1 comprising from about 5% to about 30% by weight of a salt of a monoester of citric acid, from about 25% to about 90% by weight of soap, and the balance water.
Claim 9
Dependent Claim
17 words
The soap composition according to claim 7 wherein fatty acids of the soap are derived from tallow.
Claim 10
Dependent Claim
19 words
The soap composition according to claim 7 wherein fatty acids of the soap are derived from a vegetable oil.
Claim 11
Dependent Claim
14 words
The soap composition according to claim 9 wherein the vegetable oil is coconut oil.
Claim 12
Dependent Claim
23 words
The soap composition according to claim 7 wherein fatty acids of the soap are derived from a mixture of tallow and coconut oil.
Claim 13
Dependent Claim
36 words
The soap composition according to claim 11 wherein 10 to 70% by weight of the fatty acids are derived from coconut oil and 90 t 30% by weight of the fatty acids are derived from tallow.
Claim 14
Dependent Claim
59 words
The soap composition according to claim 7 comprising about 10% disodium salt of monododecyl citrate, about 10% water and about 80% of a soap mixture comprised of from 75% to 85% of an alkali metal salt of fatty acids derived from tallow and from 15% to 25% of an alkali metal salt of fatty acids derived from coconut oil.
Claim 15
Dependent Claim
16 words
The soap composition according to claim 7 where the composition is formed into a toilet bar.
Claim 16
Dependent Claim
72 words
The skin treatment composition according to claim 1 comprising 30 to 70% by weight of a detergent active compound, 2 to 20% by weight of a suds booster, 10 to 40% by weight of an aliphatic fatty acid, 2.5 to 25% by weight of a water-soluble fatty acid soap, 1 to 35% by weight of a dication salt of a monoester of citric acid, and 1 to 10% by weight of water.
Claim 17
Dependent Claim
17 words
A skin treatment composition according to claim 15 where the composition is formed into a toilet bar.
Claim 18
Dependent Claim
88 words
The composition according to claim 15 wherein the detergent active compound is selected from the group consisting of alkali metal, magnesium or ammonium salts of C 12 -C 16 hydroxyalkane sulfonates, C 8 -C 18 N-acyl taurinates, C 12 -C 18 alkyl sulfates, C 12 -C 18 alkyl ether sulfates, C 12 -C 16 alkyl phosphonates and phosphates, C 12 -C 16 mono-alkyl succinates and maleates C 6 -C 14 dialkylsulfosuccinates, C 16 -C 20 alkane disulfonates, C 8 -C 18 alkene sulfonates, alkylbenzene sulfonates and mixtures thereof.
Claim 19
Dependent Claim
31 words
The composition according to claim 15 wherein the detergent active compounds are selected from the group consisting of alkali metal, magnesium or ammonium salts of fatty acyl esters of isethionic acid.
Claim 20
Dependent Claim
27 words
The composition according to claim 15 wherein the fatty acyl portions of the fatty acyl esters is derived from fatty acids having 10 to 18 carbon atoms.
Claim 21
Dependent Claim
25 words
The composition according to claim 19 wherein the fatty acyl portion of the fatty acyl esters is derived from fatty acids derived from coconut oil.
Claim 22
Dependent Claim
62 words
The skin treatment composition according to claim 1 comprising 10 to 35% by weight of a soap or a detergent compound or a mixture of both, 1 to 35% by weight of a dication salt of a monoester of citric acid, 1 to 5% by weight of a suds-boosting agent, 0.2 to 0.5% by weight of a preservative and the balance water.
Claim 23
Dependent Claim
54 words
The skin treatment composition according to claim 1 comprising 25 to 50% by weight stearic acid, 5 to 20% by weight coconut oil, 10 to 25% by weight glycerol, 1 to 15% by weight mineral oil, 5 to 45% by weight water and 1 to 35% by weight of a monoester of citric acid.
Claim 24
Dependent Claim
16 words
The skin treatment composition according to claim 1 wherein the physiologically acceptable carrier comprises an emollient.
Claim 25
Dependent Claim
28 words
The skin treatment composition according to claim 21 wherein the physiologically acceptable carrier comprises 50 to 98% of an emollient and 1 to 15% of a thickening agent.
Claim 26
Dependent Claim
28 words
The skin treatment composition according to claim 22 wherein the salt of a monoester of citric acid and the emollient are mixed and formed into a solid stick.
Claim 27
Dependent Claim
36 words
The skin treatment composition according to claim 1 in ointment form comprising 1 to 5% by weight anhydrous wool fat, 5 to 20% by weight viscous paraffin, and 65 to 95% by weight white petroleum jelly.
Claim 28
Dependent Claim
39 words
The skin treatment composition according to claim 1 in cream form comprising 1 to 35% by weight of a salt of a monoester of citric acid, 5 to 50% of an emollient and 50 to 95% by weight water.
Claim 29
Dependent Claim
37 words
The composition according to claim 1 in solution form comprising 1 to 35% by weight of a salt of a monoester of citric acid and 65 to 99% by weight of an organic solvent suitable for solutions.
Claim 30
Dependent Claim
37 words
The skin treatment composition according to claim 26 where the composition is incorporated in a closed metal container fitted with an aerosol cap and pressurized at from 25 psi up to 100 psi pressure with a propellant.
Claim 31
Dependent Claim
49 words
The composition according to claim 1 in gel form comprising 1 to 35% by weight of a salt of a monoester of citric acid, 5 to 64.5% by weight of an organic solvent suitable for gels, 0.5 to 5% by weight of a thickening agent, and the balance water.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-02-17 | 1995-08-19 | 1996-02-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-02-17 | 1999-08-19 | 2000-02-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-02-17 | 2003-08-19 | 2004-02-18 | $7700.00 | Window Closed / Lapsed |