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US5089428A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming a germanium layer and a heterojunction bipolar transistor

Assignee: Raytheon Co
•
Filing: 1989-12-27
•
Granted: 1992-02-18
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Expires: 2009-12-27
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Abstract

Abstract A method for preparing a germanium layer (22) adjacent to a germanium silicon layer (20). Initially, a P-germanium silicon layer (16) is deposited on to an N-germanium silicon layer (14). The continuous germanium layer (22) is formed by heating the layers (14 and 16) in a steam oxidation step to approximately 1000 degrees Centigrade to transform the P-germanium silicon layer (16) into the P-germanium layer (18) and a SiO 2 layer (22). A method for forming a heterojunction bipolar transistor utilizing a P-germanium layer (50) is also disclosed.

Inventors

  • 👤 Douglas P. Verret
  • 👤 Kenneth E. Bean

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 06:57
CPC Classifications
H; H10; H10D; H10D10/00; H10D10/80; H10D10/821; H10D10/891; H10D10/01; H10D10/021; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6308; H10P14/6322; H10P14/69; H10P14/692; H10P14/6921; H10P14/69215; H10P14/20; H10P14/29; H10P14/2901; H10P14/2902; H10P14/2905; H10P14/32; H10P14/3202; H10P14/3204; H10P14/3211; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/38; Y; Y10; Y10S; Y10S148/00; Y10S148/011; Y10S148/059

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 58 words
A process for forming a P-germanium layer on a layer of silicon: depositing a first N-germanium silicon layer on the silicon layer; depositing a P-germanium silicon layer on the first N-germanium silicon layer; and heating the wafer in an oxidizing ambient until said P-germanium silicon layer transforms into the P-germanium layer under a layer of formed silicon dioxide.
Claim 2
Dependent Claim 58 words
A process for forming a P-germanium layer on a layer of silicon: depositing a first N-germanium silicon layer on the silicon layer; depositing a P-germanium silicon layer on the first N-germanium silicon layer; and heating the wafer in an oxidizing ambient until said P-germanium silicon layer transforms into the P-germanium layer under a layer of formed silicon dioxide.
Claim 3
Dependent Claim 19 words
The process of claim 1, wherein the deposition of the first N-germanium silicon layer is by chemical vapor deposition.
Claim 4
Dependent Claim 18 words
The process of claim 1, where the deposition of the P-germanium silicon layer is by chemical vapor deposition.
Claim 5
Dependent Claim 19 words
The process of claim 1, wherein the deposition of the first N-germanium silicon is expitaxial to the silicon substrate.
Claim 6
Dependent Claim 18 words
The process of claim 1, wherein the deposition of the P-germanium silicon is expitaxial to said N-germanium silicon.
Claim 7
Dependent Claim 37 words
The process of claim 1, wherein the thickness of said N-germanium silicon layer is such that the lattice is relaxed and free from stress due to the formation of dislocations at its interface with the silicon substrate.
Claim 8
Dependent Claim 20 words
The process of claim 1, wherein the P-germanium silicon is in compressive stress and commensurate with said N-germanium silicon layer.
Claim 9
Dependent Claim 22 words
The process of claim 1, wherein said heating step comprises the step of steam oxidizing the wafer to approximately 1000 degrees Centigrade.
Claim 10
Dependent Claim 55 words
A process for forming a germanium layer on a wafer, comprising the steps of: depositing a first layer of N-germanium silicon on said wafer; depositing a second layer of P-germanium silicon on said first layer of N-germanium silicon; and oxidizing the wafer until the second layer of P-germanium silicon forms a separate layer of P-germanium.
Claim 11
Dependent Claim 55 words
A process for forming a germanium layer on a wafer, comprising the steps of: depositing a first layer of N-germanium silicon on said wafer; depositing a second layer of P-germanium silicon on said first layer of N-germanium silicon; and oxidizing the wafer until the second layer of P-germanium silicon forms a separate layer of P-germanium.
Claim 12
Dependent Claim 31 words
The process of claim 9, wherein the step of depositing the second P-germanium silicon layer comprises the process of depositing the P-germanium silicon layer having a thickness of approximately 2300 angstroms.
Claim 13
Dependent Claim 22 words
The process of claim 10, wherein the forming of said P-germanium layer produces a layer having a thickness of approximately 750 angstroms.
Claim 14
Dependent Claim 31 words
The process of claim 9, further comprising the step of growing an N-germanium silicon layer on the wafer to approximately 1 micron before depositing said P-germanium silicon layer to the wafer.
Claim 15
Dependent Claim 23 words
The process of claim 9, further comprising the step of depositing tetraethylorthosilane (TEOS) to said P-germanium silicon layer to form an oxide layer.
Claim 16
Dependent Claim 18 words
The process of claim 13, further comprising the step of forming a photoresist pattern onto said oxide layer.
Claim 17
Dependent Claim 16 words
The process of claim 14, further comprising the step of implanting boron ions into the wafer.
Claim 18
Dependent Claim 17 words
The process of claim 15, further comprising the step of selectively stripping the photoresist from the wafer.
Claim 19
Dependent Claim 18 words
The process of claim 16, further comprising the step of implanting phosphorous dopant to create N+ isolation regions.
Claim 20
Dependent Claim 20 words
The process of claim 17, further comprising the step of stripping said TEOS layer from the wafer with hydrofluoric acid.
Claim 21
Dependent Claim 19 words
The process of claim 18, further comprising the step of growing an oxide film on said P-germanium silicon layer.
Claim 22
Dependent Claim 14 words
The process of claim 19, further comprising the step of exposing said P-germanium layer.
Claim 23
Dependent Claim 19 words
The process of claim 20, further comprising the step of depositing a first conducting layer to said exposed region.
Claim 24
Dependent Claim 17 words
The process of claim 21, further comprising the step of exposing the wafer having boron implanted therein.
Claim 25
Dependent Claim 19 words
The process of claim 22, further comprising the step of depositing a second conducting layer to said exposed wafer.
Claim 26
Dependent Claim 19 words
The process of claim 9, wherein the deposition of the first N-germanium silicon layer is by chemical vapor deposition.
Claim 27
Dependent Claim 18 words
The process of claim 9, wherein the deposition of the P-germanium silicon layer is by chemical vapor deposition.
Claim 28
Dependent Claim 18 words
The process of claim 9, wherein the deposition of the first N-germanium silicon is expitaxial to the wafer.
Claim 29
Dependent Claim 18 words
The process of claim 9, wherein the deposition of the P-germanium silicon is expitaxial to said N-germanium silicon.
Claim 30
Dependent Claim 36 words
The process of claim 9, wherein the thickness of said N-germanium silicon layer is such that the lattice is relaxed and free from stress due to the formation of dislocations at its interface with the wafer.
Claim 31
Dependent Claim 20 words
The process of claim 9, wherein the P-germanium silicon is in compressive stress and commensurate with said N-germanium silicon layer.
Claim 32
Dependent Claim 180 words
A process for forming a P-germanium base for use in a heterojunction bipolar transistor (HBT) on a wafer which comprises the steps of: forming an N-germanium silicon buffer layer onto a silicon N-substrate; depositing a first P-germanium silicon on said buffer layer; depositing an oxide layer on said P-germanium silicon layer; depositing a photoresist layer on said oxide layer; selectively implanting boron into said deposited layers to form P+ contacts; depositing a second photoresist layer; implanting phosphorous to form N+ contacts; selectively stripping said second photoresist and said oxide layer from said P-germanium silicon layer; heating the wafer by steam oxidation to approximately 1000 degrees Centigrade to cause said P-germanium silicon layer to form a P-germanium layer selectively isolated from said N-germanium silicon layer, said heating forms a silicon dioxide layer on said P-germanium layer; selectively depositing a third photoresist layer; etching the wafer to form an exposed region; depositing a conductive layer in said exposed region; selectively etching the wafer to expose said P+ region; depositing aluminum over the P+ region to form the transistor of the present invention.
Claim 33
Dependent Claim 180 words
A process for forming a P-germanium base for use in a heterojunction bipolar transistor (HBT) on a wafer which comprises the steps of: forming an N-germanium silicon buffer layer onto a silicon N-substrate; depositing a first P-germanium silicon on said buffer layer; depositing an oxide layer on said P-germanium silicon layer; depositing a photoresist layer on said oxide layer; selectively implanting boron into said deposited layers to form P+ contacts; depositing a second photoresist layer; implanting phosphorous to form N+ contacts; selectively stripping said second photoresist and said oxide layer from said P-germanium silicon layer; heating the wafer by steam oxidation to approximately 1000 degrees Centigrade to cause said P-germanium silicon layer to form a P-germanium layer selectively isolated from said N-germanium silicon layer, said heating forms a silicon dioxide layer on said P-germanium layer; selectively depositing a third photoresist layer; etching the wafer to form an exposed region; depositing a conductive layer in said exposed region; selectively etching the wafer to expose said P+ region; depositing aluminum over the P+ region to form the transistor of the present invention.

References Cited (Backward Citations)

US3725161A Cited
JPS6159836A Cited
JPS6218719A Cited
JPS6243163A Cited
JPS62136036A Cited
US4920076A Cited
US4891329A Cited
US4975387A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-02-17 1995-08-19 1996-02-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-02-17 1999-08-19 2000-02-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-02-17 2003-08-19 2004-02-18 $7700.00 Window Closed / Lapsed

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