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US5087430A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for purifying exhaust gas

Assignee: Mitsubishi Chemical Corp
•
Filing: 1990-03-27
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Granted: 1992-02-11
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Expires: 2010-03-27
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Abstract

Abstract An exhaust gas containing a nitrogen oxides is passed at a temperature of 250 to 550 DEG C in the presence of a reducing agent through a catalyst bed filled with a molded denitration catalyst comprising at least the following three catalyst components (A) an oxide of at least one metallic element selected from the group consisting of Ti, Si and Zr, (B) an oxide of at least one metallic element selected from the group consisting of Mo and W, and (C) an oxide of V such that the concentrations of the oxide (B) and/or the oxide (C) in the exhaust gas inlet site of the catalyst bed are higher than in the other site thereof. The molded denitration catalyst is also described.

Inventors

  • 👤 Masayuki Hanada
  • 👤 Morio Fukuda
  • 👤 Takeo Koshikawa
  • 👤 Akihiro Yamauchi
  • 👤 Hiroshi Ogura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:23
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9418; B01J23/20; B01J23/22; B01D2251/00; B01D2251/20; B01D2251/206; B01D2251/2062; B01D2255/00; B01D2255/20; B01D2255/204; B01D2255/2047; B01D2255/207; B01D2255/20707; B01D2255/20723; B01D2255/20776; B01D2258/00; B01D2258/01; B01D2258/012

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 305 words
A process for purifying an exhaust gas containing nitrogen oxides, sulfur oxides, and soot and hydrocarbons, by passing it through a catalyst bed filled with a denitration catalyst in the presence of ammonia, characterized in that the exhaust gas is passed at a temperature of 250° to 550° C. in the presence of ammonia through a catalyst bed filed with at least one honeycomb-type denitration catalyst having flow channels for the exhaust gas, said catalyst comprising at least the following three catalyst components (A) an oxide of at least one metallic element selected from the group consisting of Ti, Si and Zr, (B) an oxide of at least one metallic element selected from the group consisting of Mo and W, and (C) an oxide of V such that the concentrations of either the oxide (B) or the oxide (C) or both in the exhaust gas inlet site of the catalyst bed are higher than in the other end site thereof, wherein the catalyst in the end site other than the exhaust gas inlet site of the cataylst bed comprises 55 to 98.9% by weight of the component (A), 1 to 44.9% by weight of the component (B) and 0.1 to 5% by weight of the component (C), and wherein the weights of either component (B) or the component (C) or both in the catalyst filled in the exhaust gas inlet site of the catalyst bed are about 1.1 to 10 times the weights of either component (B) or the component (C) or both in the catalyst filled in the end site other than the exhaust gas inlet site of the catalyst bed, said honeycomb-type catalyst having flow channels of a diameter of 2 to 10 mm, a sectional area of about 200 to 600 cm 2 and a length of about 50 to 200 cm.
Claim 2
Dependent Claim 305 words
A process for purifying an exhaust gas containing nitrogen oxides, sulfur oxides, and soot and hydrocarbons, by passing it through a catalyst bed filled with a denitration catalyst in the presence of ammonia, characterized in that the exhaust gas is passed at a temperature of 250° to 550° C. in the presence of ammonia through a catalyst bed filed with at least one honeycomb-type denitration catalyst having flow channels for the exhaust gas, said catalyst comprising at least the following three catalyst components (A) an oxide of at least one metallic element selected from the group consisting of Ti, Si and Zr, (B) an oxide of at least one metallic element selected from the group consisting of Mo and W, and (C) an oxide of V such that the concentrations of either the oxide (B) or the oxide (C) or both in the exhaust gas inlet site of the catalyst bed are higher than in the other end site thereof, wherein the catalyst in the end site other than the exhaust gas inlet site of the cataylst bed comprises 55 to 98.9% by weight of the component (A), 1 to 44.9% by weight of the component (B) and 0.1 to 5% by weight of the component (C), and wherein the weights of either component (B) or the component (C) or both in the catalyst filled in the exhaust gas inlet site of the catalyst bed are about 1.1 to 10 times the weights of either component (B) or the component (C) or both in the catalyst filled in the end site other than the exhaust gas inlet site of the catalyst bed, said honeycomb-type catalyst having flow channels of a diameter of 2 to 10 mm, a sectional area of about 200 to 600 cm 2 and a length of about 50 to 200 cm.
Claim 3
Dependent Claim 50 words
The process of claim 1 wherein the catalyst bed is filled with one honeycomb-type catalyst having exhaust as flow channels, the concentrations either oxide (B) or the oxide (C) or both in the exhaust gas inlet site of the honeycomb-type catalyst being higher than in the other end site thereof.
Claim 4
Dependent Claim 136 words
The process of claim 1 wherein the catalyst bed is filled with at least two honeycomb-type catalysts having exhaust gas flow channels, wherein in each of the honeycomb-type catalyst, the concentrations of either the oxide (B) or the oxide (C) or both are substantially uniform in all sites, said at least two honeycomb-type catalysts having different concentrations of either the oxide (B) or the oxide (C) or both relative to each other, and wherein the honeycomb-type catalyst having the higher concentrations of either the oxide (B) or the oxide (C) or both is located in the exhaust gas inlet site of the catalyst bed and the honeycomb-type catalyst having the lower concentrations of either the oxide (B) or the oxide (C) or both is located in the exhaust gas outlet site of the catalyst bed, respectively.

References Cited (Backward Citations)

US3025133A Cited
US4221768A Cited
US4188364A Cited
JPS5469587A Cited
JPS56126437A Cited
US4466947A Cited
US4374103A Cited
EP0161743A2 Cited
US4828807A Cited
JPS634853A Cited
US4855115A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-02-10 1995-08-12 1996-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-02-10 1999-08-12 2000-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-02-10 2003-08-12 2004-02-11 $7700.00 Window Closed / Lapsed

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