Achiral fluorine-containing liquid crystals

Claim 2

A chiral fluorine-containing liquid crystal compounds comprising a fluorocarbon terminal portion represented by the formula --DC q F 2q X where X is hydrogen or fluorine, q is 1-20, and D is ##STR114## where r and r' are independently 1 to 20 and p is 0 to 4, and a hydrocarbon or another fluorocarbon terminal portion, the terminal portions being connected by a central core, the compounds having smectic mesophases or having latent smectic mesophases.

Claim 3

The compounds of claim 1 wherein said central core comprises at least two aromatic, heteroaromatic, cycloaliphatic, or substituted aromatic, heteroaromatic, or cycloaliphatic rings.

Claim 4

The compounds of claim 2 wherein rings are connected one with another by --COO--, --COS--, --HC═N--, or --COSe--.

Claim 5

The compounds of claim 2 wherein heteroatoms within the heteroaromatic ring are N, O, or S.

Claim 6

The compounds of claim 1 wherein said compounds can be represented by the general formula I: ##STR115## where M, N, and P are each independently ##STR116## a, b, and c are independently zero or an integer of from 1 to 3 with the proviso that the sum of a+b+c be at least 2; each A and B are non-directionally and each independently a covalent bond, ##STR117## each X, Y, and Z are independently --H, --Cl, --F, --Br, --I, --OH, --OCH 3 , --CH 3 , --CN, or --NO 2 ; each l, m, and n are independently zero or an integer of 1 to 4, ##STR118## where r and r' are independently 1 to 20, and p is 0 to 4; r is ##STR119## where R' is ##STR120## and q and q' are independently 1 to 20, and R can be straight chain or branched, and R f is C q F 2q -X where X is H or F, and q and q' are independently 1 to 20.

Claim 7

The compounds of claim 1 wherein said compounds exhibit birefringences in the range of 0.05-0.18.

Claim 8

The compounds of claim 1 wherein said compounds having smectic mesophases have suppressed nematic mesophases.

Claim 9

The compounds according to claim 1 wherein said compounds exhibit rise and decay times of less than 1 millisecond have been observed for an 80% change in the light intensity in smectic C Freedericksz-type liquid crystal display devices.

Claim 10

Mixtures of two or more of the compounds of claim 1, at least one of said compounds having smectic mesophases.

Claim 11

Liquid crystal mixtures comprising at least one compound according to claim 1 and at least one chiral liquid crystal compound.

Claim 12

The liquid crystal mixtures of claim 10 wherein said chiral liquid crystal compound is present in an amount sufficient to provide the mixture with ferroelectric properties.

Claim 13

The liquid crystal mixtures of claim 11 wherein said chiral liquid crystal compound is present in an amount of about 1 to 25 weight percent.

Claim 14

Liquid crystal mixtures comprising at least one compound according to claim 1 and at least one non-liquid crystal compound.

Claim 15

The liquid crystal mixtures of claim 10 wherein said non-liquid crystal compound is present in an amount sufficient to provide the mixture with ferroelectric properties.

Claim 16

A liquid crystal display device containing said compound of claim 1 wherein said compound has a smectic mesophase.

Claim 17

A liquid crystal display device containing the mixture of claim 9.

Claim 18

A liquid crystal display device containing the mixture of claim 10.

Claim 19

A liquid crystal display device containing the mixture of claim 11.