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US5078990A Expired / Lapsed US ⏱️ 0.0 years remaining

Shampoos and conditioning shampoos having increased capacity for incorporation of conditioning agents and removal of hair soil

Assignee: Helene Curtis Inc
•
Filing: 1990-07-13
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Granted: 1992-01-07
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Expires: 2010-07-13
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Abstract

Abstract An aqueous shampoo containing a long chain alkyl sulfate and/or long chain alkyl ether sulfate anionic surfactant, and a cationic di-long chain alkyl quaternary ammonium nitrogen-containing compound, unexpectedly increases the ability of the aqueous shampoo (1) to incorporate water-insoluble conditioning agents, particularly non-volatile silicone materials, and (2) to remove previously applied conditioning agents and other soiled conditioning agents and contaminants from the hair.

Inventors

  • 👤 Kathleen Martin
  • 👤 Priscilla L. Walling

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:07
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/416; A61K8/42; A61K8/44; A61K8/445; A61K8/46; A61K8/463; A61Q; A61Q5/00; A61Q5/02; A61K2800/00; A61K2800/40; A61K2800/59; A61K2800/596

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 93 words
A shampoo composition comprising an emulsion of water; an anionic cleaning surfactant selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates and ethoxylated alkyl sulfates; and a di-long chain alkyl quaternary nitrogen-containing compound, wherein the two long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain and wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 2
Dependent Claim 93 words
A shampoo composition comprising an emulsion of water; an anionic cleaning surfactant selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates and ethoxylated alkyl sulfates; and a di-long chain alkyl quaternary nitrogen-containing compound, wherein the two long alkyl chains bonded to the nitrogen atom have from about 12 to about 22 carbon atoms per alkyl chain and wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 3
Dependent Claim 30 words
The shampoo composition of claim 1 wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is in the range of about 100-150 to 1.
Claim 4
Dependent Claim 105 words
The shampoo composition of claim 1 wherein said quaternary nitrogen-containing conditioning agent is selected from the group consisting of (a) compounds having only two long carbon chains and two identical or different short chain alkyl groups containing one to four carbon atoms bonded to the quaternary nitrogen atom, (b) compounds having two long carbon chains, one benzyl group and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom, and (c) compounds having two long carbon chains, one hydrogen atom and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom.
Claim 5
Dependent Claim 18 words
The composition of claim 1 wherein the di-long chain quaternary nitrogen-containing compound is a dioctadecyl quaternary ammonium salt.
Claim 6
Dependent Claim 28 words
The shampoo composition of claim 1 wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is at least about 100 to 1.
Claim 7
Dependent Claim 18 words
The composition of claim 5 wherein the di-long chain quaternary nitrogen-containing compound is a dioctadecyl quaternary ammonium salt.
Claim 8
Dependent Claim 36 words
The shampoo composition of claim 1 wherein the composition is in the form of an emulsion and further includes a suspending agent in an amount of about 0.1% to about 5% by weight of the composition.
Claim 9
Dependent Claim 15 words
The composition of claim 7 wherein the suspending agent comprises a long chain phthalamic acid.
Claim 10
Dependent Claim 13 words
The composition of claim 8 wherein the suspending agent is distearyl phthalamic acid.
Claim 11
Dependent Claim 24 words
The composition of claim 9 further including a nonionic alkanolamide in an amount of about 0.1% to about 5% by weight of the composition.
Claim 12
Dependent Claim 18 words
A method of shampooing and conditioning hair which comprises applying to said hair the composition of claim 1.
Claim 13
Dependent Claim 55 words
A method of increasing the detergency action of lauryl sulfate and lauryl ether sulfate detergents in a shampoo composition at a hair washing temperature of at least about 30° C. comprising contacting the hair with the composition of claim 1 and rinsing the hair with water at a temperature of at least about 30° C.
Claim 14
Dependent Claim 38 words
The method of claim 12 wherein the hair is rinsed with water at a temperature of about 30° C. to about 45° C. to increase the capacity of the lauryl sulfate detergents to remove soil from the hair.
Claim 15
Dependent Claim 93 words
In a hair shampoo composition containing water, a long chain alkyl sulfate selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates, and ethoxylated alkyl sulfates, a water-insoluble conditioning agent and a quaternary nitrogen-containing compound, the improvement comprising the quaternary nitrogen-containing compound having only two long chain alkyl groups bonded to the quaternary nitrogen atom, and in an amount such that the molar ratio of long chain alkyl sulfate to quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 16
Dependent Claim 93 words
In a hair shampoo composition containing water, a long chain alkyl sulfate selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates, and ethoxylated alkyl sulfates, a water-insoluble conditioning agent and a quaternary nitrogen-containing compound, the improvement comprising the quaternary nitrogen-containing compound having only two long chain alkyl groups bonded to the quaternary nitrogen atom, and in an amount such that the molar ratio of long chain alkyl sulfate to quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 17
Dependent Claim 19 words
A method of shampooing and conditioning hair simultaneously which comprises applying to said hair the composition of claim 14.
Claim 18
Dependent Claim 105 words
A method of manufacturing the conditioning shampoo composition of claim 14, comprising: mixing water; a long chain alkyl sulfate selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates and ethoxylated alkyl sulfates, and a di-long chain alkyl quaternary ammonium nitrogen-containing compound in a molar ratio of long chain alkyl sulfate to quaternary nitrogen-containing compound of between about 85 to 1 and about 1000 to 1; adding the water-insoluble conditioning agent to the mixture and heating the mixture to a temperature of at least 30° C.; and vigorously agitating the mixture to emulsify the conditioning agent in the composition.
Claim 19
Dependent Claim 106 words
A conditioning shampoo composition comprising an emulsion of water; about 0.5% to about 10% by weight of a water-insoluble conditioning agent; an anionic cleaning surfactant selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates, and ethoxylated alkyl sulfates and a di-long chain alkyl quaternary nitrogen-containing compound containing only two long alkyl chains bonded to the nitrogen atom having from about 12 to about 22 carbon atoms per alkyl chain and wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 20
Dependent Claim 106 words
A conditioning shampoo composition comprising an emulsion of water; about 0.5% to about 10% by weight of a water-insoluble conditioning agent; an anionic cleaning surfactant selected from the group consisting of long chain (C 8-30 ) alkyl sulfates, alkyl ether sulfates, and ethoxylated alkyl sulfates and a di-long chain alkyl quaternary nitrogen-containing compound containing only two long alkyl chains bonded to the nitrogen atom having from about 12 to about 22 carbon atoms per alkyl chain and wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is in the range of about 85 to 1 to about 1000 to 1.
Claim 21
Dependent Claim 29 words
The conditioning shampoo composition of claim 17 wherein the molar ratio of anionic cleaning surfactant to di-long chain alkyl quaternary nitrogen-containing compound is at least about 100 to 1.
Claim 22
Dependent Claim 106 words
The conditioning shampoo composition of claim 17 wherein said quaternary nitrogen-containing conditioning agent is selected from the group consisting of (a) compounds having only two long carbon chains and two identical or different short chain alkyl groups containing one to four carbon atoms bonded to the quaternary nitrogen atom, (b) compounds having two long carbon chains, one benzyl group and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom, and (c) compounds having two long carbon chains, one hydrogen atom and one short chain alkyl group having one to four carbon atoms bonded to the quaternary nitrogen atom.
Claim 23
Dependent Claim 29 words
The conditioning shampoo composition of claim 17 wherein the composition further includes an emulsifying agent in an amount of about 0.1% to about 5% by weight of the composition.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-01-06 1995-07-08 1996-01-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-01-06 1999-07-08 2000-01-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-01-06 2003-07-08 2004-01-07 $7700.00 Window Closed / Lapsed

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