US5073620A
Expired / Lapsed
US
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Thermoplastic resin composition
Assignee: Sumitomo Chemical Co Ltd
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Filing: 1989-03-03
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Granted: 1991-12-17
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Expires: 2009-03-03
Abstract
Abstract (A) 10-70 parts by weight of a polyphenylene ether, a mixture of a polyphenylene ether and a polystyrene or a polyphenylene ether-styrene graft copolymer, (B) 90-30 parts by weight of a mixture of (i) a thermoplastic aromatic copolyamide and/or an aromatic nuclear-hydrogenated copolyamide in an amount of 0.1-70% by weight of existing total polyamide and (ii) a thermoplastic aliphatic polyamide in a complementary amount of 99.9-30% by weight of existing total polyamide, and (C) 0.01-30 parts by weight, based on 100 parts by weight of the above components (A) and (B) of, at least one compound selected from the group consisting of oxazoline and a compound having, in its molecule, (a) carbon-carbon double bond or a carbon-carbon triple bond and (b) at least one functional group selected from carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate ester group, isocyanate group, methylol group, oxazolidine group and hydroxyl group. This composition may further contain an impact strength modifier, namely, rubber-like material and/or modified rubber-like material.
Inventors
- 👤 Takashi Sanada
- 👤 Kaoru Kitadono
- 👤 Yasurou Suzuki
- 👤 Taichi Nishio
- 👤 Hiroomi Abe
- 👤 Noriyasu Kagawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 23:22
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08F; C08F291/00; C08K; C08K5/00; C08K5/0008; C08L51/00; C08L51/08; C08L77/00; F; F02; F02F; F02F7/00; F02F7/006; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
170 words
A thermoplastic resin composition which comprises: (A) 10-70 parts by weight of a polyphenylene ether, a mixture of a polyphenylene ether and a polystyrene or a polyphenylene ether-styrene graft copolymer, (B) 90-30 parts by weight of a mixture of (i) at least one copolyamide selected from the group consisting of a thermoplastic aromatic copolyamide and an aromatic nuclear-hydrogenated copolyamide in an amount of 0.1-70% by weight of existing total polyamide and (ii) a thermoplastic aliphatic polyamide in a complementary amount of 99.9-30% by weight of existing total polyamide, and (C) 0.01-30 parts by weight, based on 100 parts by weight of the above components (A) and (B), of at least one compound selected from the group consisting of oxazoline and a compound having, in its molecule, (a) carbon-carbon double bond or a carbon-carbon triple bond and (b) at least one functional group selected from carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate ester group, isocyanate group, methylol group, oxazolidine group and hydroxyl group.
Claim 2
Dependent Claim
170 words
A thermoplastic resin composition which comprises: (A) 10-70 parts by weight of a polyphenylene ether, a mixture of a polyphenylene ether and a polystyrene or a polyphenylene ether-styrene graft copolymer, (B) 90-30 parts by weight of a mixture of (i) at least one copolyamide selected from the group consisting of a thermoplastic aromatic copolyamide and an aromatic nuclear-hydrogenated copolyamide in an amount of 0.1-70% by weight of existing total polyamide and (ii) a thermoplastic aliphatic polyamide in a complementary amount of 99.9-30% by weight of existing total polyamide, and (C) 0.01-30 parts by weight, based on 100 parts by weight of the above components (A) and (B), of at least one compound selected from the group consisting of oxazoline and a compound having, in its molecule, (a) carbon-carbon double bond or a carbon-carbon triple bond and (b) at least one functional group selected from carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate ester group, isocyanate group, methylol group, oxazolidine group and hydroxyl group.
Claim 3
Dependent Claim
31 words
A composition according to claim 1 wherein the polyphenylene ether (A) is at least one polymer selected from the group consisting of poly(2,6-dimethyl-1,4-phenylene ether) and a copolymer of 2,6-dimethylphenol and 2,3,6-trimethylphenol.
Claim 4
Dependent Claim
28 words
A composition according to claim 2 wherein the polyphenylene ether has a reduced viscosity (ηsp/c) of 0.25-0.65 dl/g measured at 25° C. in chloroform solution of 0.5 g/dl.
Claim 5
Dependent Claim
57 words
A composition according to claim 1 wherein the thermoplastic aliphatic polyamide in the component (B) has an average molecular weight of 10,000 or more and is prepared by self-condensation of lactam or ω-amino acid of 4-12 carbon atoms, or by bonding equimolar saturated aliphatic dicarboxylic acid containing 4-12 carbon atoms and aliphatic diamine containing 2-12 carbon atoms.
Claim 6
Dependent Claim
71 words
A composition according to claim 1 wherein the thermoplastic aromatic copolyamide in the component (B) are polyamides obtained from (1) at least one acid selected from the group consisting of the following (a) and (b) and (2) at least one amine selected from the group consisting of the following (c), (d), (e), (f) and (g): (a) terephthalic acid, (b) isophthalic acid, (c) hexamethylenediamine, (d) trimethylhexamethylenediamine, (e) bis(p-aminocyclohexyl)methane, (f) bis(p-aminocyclohexyl)propane, (g) bis(3-methyl-4-aminocyclohexyl)methane.
Claim 7
Dependent Claim
79 words
A composition according to claim 1 wherein the thermoplastic aromatic nuclear-hydrogenated copolyamide in the component (B) are polyamides obtained from (1) at least one acid selected from the group consisting of the following (a) and (b) and (2) at least one amine selected from the group consisting of the following (c), (d), (e), (f) and (g): (a) terephthalic acid and/or its derivative, (b) isophthalic acid and/or its derivative, (c) hexamethylenediamine, (d) trimethylhexamethylenediamine, (e) bis(p-aminocyclohexyl)methane, (f) bis(p-aminocyclohexyl)propane, (g) bis(3-methyl-4-aminocyclohexyl) methane.
Claim 8
Dependent Claim
52 words
A composition according to claim 5 wherein the thermoplastic aromatic copolyamide in the component (B) further comprises a unit of a lactam, a unit of ω-amino acid of 4-12 carbon atoms or a unit derived from an aliphatic dicarboxylic acid of 4-12 carbon atoms and an aliphatic diamine of 2-12 carbon atoms.
Claim 9
Dependent Claim
52 words
A composition according to claim 6 wherein the thermoplastic aromatic nuclear-hydrogenated copolyamide in the component (B) further comprises a unit of lactam, a unit of ω-amino acid of 4-12 carbon atoms or a unit derived from an aliphatic dicarboxylic acid of 4-12 carbon atoms and an aliphatic diamine of 2-12 carbon atoms.
Claim 10
Dependent Claim
47 words
A composition according to claim 5 or 6 wherein amine (2) is a mixture of (c) with at least one of (e) (f) and (g) at a ratio of 99.5-50 mol % of the former (c) and 0.5-50 mol % of the latter, (e), (f) and (g).
Claim 11
Dependent Claim
67 words
A composition according to claim 5 wherein the acid (1) comprises 2-60 mol % of terephthalic acid (a) and 40-98 mol % of isophthalic acid (b) based on 100 mol % of total acid, and amine (2) comprises 98-50 mol % of hexamethylenediamine (c) and 2-50 mol % of at least one amine selected from (e), (f) and (g) based on 100 mol % of total amine.
Claim 12
Dependent Claim
69 words
A composition according to claim 5 wherein acid (1) comprises 20-40 mol % of terephthalic acid (a) and 60-80 mol % of isophthalic acid (b) based on 100 mol % of total acid, and amine (2) is a mixture of 94-98 mol % of hexamethylenediamine (c) with 2-6 mol % of at least one amine selected from (e), (f) and (g) based on 100 mol % of total amine.
Claim 13
Dependent Claim
42 words
A composition according to claim 5 or 6 wherein acid (1) is mainly composed of terephthalic acid or its dimethyl ester (a) and amine (2) is mainly composed of at least one diamine selected from the group consisting of 2,2,4-trimethylhexamethylenediamine and 2,4,4-trimethylhexamethylenediamine.
Claim 14
Dependent Claim
40 words
A composition according to claim 5 or 6 wherein acid (1) is mainly composed of a mixture of terephthalic acid (a) and isophthalic acid (b) at a mixing ratio of 3:7, and amine (2) is mainly composed of hexamethylenediamine (c).
Claim 15
Dependent Claim
50 words
A composition according to claim 1 which additionally contains 3-60 parts by weight of (D) at least one material selected from the group consisting of a rubber-like material and a modified rubber-like material as an impact strength modifier based on 100 parts by weight of components (A), (B) and (C).
Claim 16
Dependent Claim
43 words
A composition according to claim 1 which comprises 10-70 parts by weight of component (A), 90-30 parts by weight of component (B) and 3-60 parts by weight based on 100 parts by weight of components (A) and (B) of modified rubber-like material (D).
Claim 17
Dependent Claim
16 words
A molded article for automobile parts which is made from the composition according to claim 1.
Claim 18
Dependent Claim
27 words
A molded article according to claim 16 wherein the automobile parts are cylinder head cover, radiator head tank, spoiler, bumper, fender, wheel cover or side seal garnish.
Claim 19
Dependent Claim
63 words
A composition according to claim 1, wherein said mixture (B) is a mixture of (i) at least one copolyamide selected from the group consisting of a thermoplastic aromatic copolyamide and an aromatic nuclear-hydrogenated copolyamide in an amount of 0.5-7.5% by weight of existing total polyamide and (ii) a thermoplastic aliphatic polyamide in a complementary amount of 99.5-92.5% by weight of existing total polyamide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-12-16 | 1995-06-17 | 1995-12-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-12-16 | 1999-06-17 | 1999-12-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-12-16 | 2003-06-17 | 2003-12-17 | $7700.00 | Window Closed / Lapsed |