US5068277A
Expired / Lapsed
US
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Hydrolyzable silicone polymers
Assignee: Rhone Poulenc Surfactants and Specialties LP
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Filing: 1989-05-03
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Granted: 1991-11-26
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Expires: 2009-05-03
Abstract
Abstract This invention relates to polyfunctional silicone polymers containing one or more alkylene polyfunctional hydrolyzable silyl radicals extended from the siloxy polymer chain, said polymer having the structure ##STR1## wherein R 2 and R 3 are each independently alkyl or aryl optionally substituted with lower alkyl; R 4 is hydrogen or R 2 ; R 7 is R 2 or Z 1 ; Z 1 is --CH 2 CHA--(CH 2 ) r Si(R 1 ) 3 ; Z and Z 2 are each independently --CH 2 CHA--(CH 2 ) r Si(R 1 ) 3 or (R 9 ) n Si(H) 3-n ; R 9 is alkyl, alkoxy, phenoxy or aryl optionally substituted with lower alkyl; n has a value of from 0 to 3; x has a value of from 2 to 1000; y has a value of from 1 to 200; p' has a value of from 0 to about 50% of y; A is hydrogen, alkyl or phenyl; r has a value of from 0 to 12; and R 1 is hydroxy, acyloxy, halogen, amino, alkoxy, aryloxy or aryloxy substituted with lower alkyl, halogen or acyloxy. The invention also relates to the use of said polymers as surface modifiers, reinforcing coatings and fillers for thermoplastics.
Inventors
- 👤 Rastko Vukov
- 👤 Basil A. Behnam
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 13:28
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/50; C08L; C08L83/00; C08L83/14
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
134 words
A hydrolyzable silicon containing polymer having the formula ##STR15## wherein R 2 and R 3 are each independently alkyl or aryl optionally substituted with lower alkyl; Z 1 is --CH 2 CHA--(CH 2 ) r Si(R 1 ) 3 ; Z and Z 2 are each independently (R 9 ) n Si(H) 3-n ; n has a value of from 0 to 3; R 9 is slkyl, alkoxy, phenoxy, or aryl optionally substituted with lower alkyl; R 7 is R 2 ; x has a value of from 2 to 1000; y has a value of from 1 to 200; A is hydrogen, alkyl or phenyl; r has a value of from 0 to 12; and R 1 is hydroxy, acyloxy, halogen, amino, alkoxy, aryloxy or aryloxy substituted with lower alkyl, halogen or acyloxy.
Claim 2
Dependent Claim
134 words
A hydrolyzable silicon containing polymer having the formula ##STR15## wherein R 2 and R 3 are each independently alkyl or aryl optionally substituted with lower alkyl; Z 1 is --CH 2 CHA--(CH 2 ) r Si(R 1 ) 3 ; Z and Z 2 are each independently (R 9 ) n Si(H) 3-n ; n has a value of from 0 to 3; R 9 is slkyl, alkoxy, phenoxy, or aryl optionally substituted with lower alkyl; R 7 is R 2 ; x has a value of from 2 to 1000; y has a value of from 1 to 200; A is hydrogen, alkyl or phenyl; r has a value of from 0 to 12; and R 1 is hydroxy, acyloxy, halogen, amino, alkoxy, aryloxy or aryloxy substituted with lower alkyl, halogen or acyloxy.
Claim 3
Dependent Claim
11 words
The polymer of claim 1 wherein A is alkyl or phenyl.
Claim 4
Dependent Claim
24 words
The polymer of claim 1 wherein R 2 , R 3 and R 7 are each C 1 to C 2 alkyl or phenyl.
Claim 5
Dependent Claim
24 words
The polymer of claim 1 wherein Z and Z 2 are each (alkyl) 3 Si-- and the A member of Z 1 is hydrogen.
Claim 6
Dependent Claim
9 words
The polymer of claim 4 having the formula ##STR16##
Claim 7
Dependent Claim
10 words
The polymer of claim 1 wherein R 1 is hydroxy.
Claim 8
Dependent Claim
15 words
The polymer of claim 6 wherein Z and Z 2 are each (alkyl) 3 Si--.
Claim 9
Dependent Claim
9 words
The polymer of claim 7 having the formula ##STR17##
Claim 10
Dependent Claim
69 words
The polymer of claim 1 wherein R 2 , R 3 and R 7 are C 1 to C 2 alkyl or phenyl, x has a value of from 20 to 200 and y has a value of from 1 to 15, R 2 is alkyl, n has a value of 2 or 3, and wherein A is hydrogen and r has a value of from 0 to 2.
Claim 11
Dependent Claim
20 words
A process of applying an effective coating amount of the polymer of claim 1 to the surface of a substrate.
Claim 12
Dependent Claim
20 words
A process of mixing an effective reinforcing amount of the polymer of claim 1 with a natural or synthetic material.
Claim 13
Dependent Claim
17 words
A process of contacting a mold with a mold releasing amount of the compound of claim 1.
Claim 14
Dependent Claim
19 words
A process of incorporating an effective surface polishing amount of the compound of claim 1 in a polish formulation.
Claim 15
Dependent Claim
8 words
A product of the process of claim 10.
Claim 16
Dependent Claim
8 words
A product of the process of claim 11.
Claim 17
Dependent Claim
34 words
A product made by a comprising the steps of: contacting a mold with a mold releasing amount of the compound of claim 1; and molding thermoplastic material in the mold to make the product.
Claim 18
Dependent Claim
8 words
A product of the process of claim 13.
Claim 19
Dependent Claim
9 words
the polmymer of claim 1 wherein n is 3.
Claim 20
Dependent Claim
18 words
The polymer of claim 18 wherein R 9 is alkyl, phenoxy, or aryl optionally substituted with lower alkyl.
Claim 21
Dependent Claim
23 words
The polymer of claim 18 wherein R 1 is hydroxy, acyloxy, halogen, amino, aryloxy or aryloxy substituted with lower alkyl, halogen or acyloxy.
Claim 22
Dependent Claim
20 words
The process of claim 10 wherein the substrate is selected from textile, wherein the coating chemically bonds to the substrate.
Claim 23
Dependent Claim
19 words
The process of claim 10 wherein the substrate is selected from roofing granules, glass, metal or a cementitious surface.
Claim 24
Dependent Claim
29 words
The process of claim 11 wherein the material is selected from a thermoplastic, cement or fiberglass and the polymer has a molecular weight between about 400 and about 5000.
Claim 25
Dependent Claim
19 words
The process of incorporating an effective surface polishing amount of the compound of claim 8 in a polish formulation.
Claim 26
Dependent Claim
17 words
A composition comprising an effective mold release amount of the polymer of claim 1 and a surfactant.
Claim 27
Dependent Claim
24 words
A paint or printing ink composition comprising an effective abherent amount of the polymer of claim 1, powdered aluminum pigment, and a thixotropic agent.
Claim 28
Dependent Claim
20 words
The process of claim 10 wherein the substrate is selected from plastic, wherein the coating chemically bonds to the substrate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-11-25 | 1995-05-27 | 1995-11-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-11-25 | 1999-05-27 | 1999-11-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-11-25 | 2003-05-27 | 2003-11-26 | $7700.00 | Window Closed / Lapsed |