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US5067966A
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2-amino-6-chloro-4-nitro-phenol derivatives, process to their production and hair dyes containing those compounds
Assignee: Procter and Gamble Deutschland GmbH
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Filing: 1989-12-12
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Granted: 1991-11-26
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Expires: 2009-12-12
Abstract
Abstract PCT No. PCT/EP89/01523 Sec. 371 Date Aug. 17, 1990 Sec. 102(e) Date Aug. 17, 1990 PCT Filed Dec. 12, 1989 PCT Pub. No. WO90/07557 PCT Pub. Date Jul. 12, 1990.The improved hair dye compounds are 2-amino-6-chloro-4-nitrophenol derivatives of the general formula (I) <IMAGE> (I) wherein the radical R is a straight-chain or branched alkyl group with 1 to 5 carbon atoms. These hair dye compounds may be made by substitution of an amine group hydrogen of 2-amino-6-chloro-4-nitrophenol to form the amide and subsequent reduction, preferably with sodium borohydride. The hair dye compositions contain a compound of formula (I). The compounds of formula (I) dye the hair an intense red and can be favorably tolerated physiologically.
Inventors
- 👤 Herbert Mager
- 👤 Hans-Jurgen Braun
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 05:45
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/418; A61Q; A61Q5/00; A61Q5/06; A61Q5/065; A61Q5/10; C; C09; C09B; C09B51/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
38 words
2-amino-6-chloro-4-nitrophenol derivative of the general formula (I) ##STR16## wherein the radical R is selected from the group consisting of straight-chain alkyl groups with 1 to 5 carbon atoms and branched alkyl groups with 1 to 5 carbon atoms.
Claim 2
Dependent Claim
38 words
2-amino-6-chloro-4-nitrophenol derivative of the general formula (I) ##STR16## wherein the radical R is selected from the group consisting of straight-chain alkyl groups with 1 to 5 carbon atoms and branched alkyl groups with 1 to 5 carbon atoms.
Claim 3
Dependent Claim
12 words
The derivative according to claim 1, wherein said radical R is methyl.
Claim 4
Dependent Claim
12 words
The derivative according to claim 1, wherein said radical R is ethyl.
Claim 5
Dependent Claim
12 words
The derivative according to claim 1, wherein said radical R is propyl.
Claim 6
Dependent Claim
12 words
The derivative according to claim 1, wherein said radical R is 2'-methylpropyl.
Claim 7
Dependent Claim
12 words
The derivative according to claim 1, wherein said radical R is 2',2'-dimethylpropyl.
Claim 8
Dependent Claim
29 words
Composition for dyeing hair containing dye and cosmetic additives containing a member selected from the group consisting of said 2-amino-6-chloro-4-nitrophenol derivatives according to claim 1 and water-soluble salts thereof.
Claim 9
Dependent Claim
14 words
Composition according to claim 7, further comprising at least one direct dyeing hair dye.
Claim 10
Dependent Claim
41 words
Composition according to claim 8, wherein the direct dyeing hair dye is selected from 2-amino-4-nitrophenol, 1-(2'-hydroxyethyl)amino-2-amino-4-nitrobenzene, 2-nitro-4-(2'-hydroxyethyl)amino-aniline, 1-methylamino-2-nitro-4-di-(2'-hydroxyethyl)-aminobenzene, 1-(2',3'-dihydroxypropyl)-amino-2-nitro-4-(N-ethyl,N-(2"-hydroxyethyl)amino)benzene, 1-(2',3'-dihydroxy-propyl)amino-2-nitro-4-dimethylaminobenzene, 1-(2',3'-dihydroxypropyl)amino-2-nitro-4-pyrrolidinobenzene, 1-(3'-hydroxypropyl)amino-2-nitro-4-di-(2"-hydroxyethyl)-aminobenzene, 2,5-bis(2'-hydroxyethyl)aminonitrobenzene, Basic Violet 1 (C.I. 42535), Acid Brown 4 (C.I. 14805), Disperse Violet 4 (C.I. 61105), 1,4,5,8-tetraaminoanthraquinone and 1,4-diaminoanthraquinone.
Claim 11
Dependent Claim
23 words
Composition according to claim 8, further comprising at least one polymer selected from the group consisting of synthetic, natural and modified natural polymers.
Claim 12
Dependent Claim
54 words
Composition according to claim 10, wherein the polymer is selected from the group consisting of polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid, polymethacrylic acid, basic polymerizates of esters of polyacrtylic acid and polymethacrylic acid and amino alcohols and their salts and quaternization products, polyacrylonitrile, polyvinyl acetate, polyvinylpyrrolidone vinyl acetate and chitosan and chitosan derivatives.
Claim 13
Dependent Claim
24 words
Composition according to claim 9, wherein the 2-amino-6-chloro-4-nitrophenol derivative of formula (I) is contained in a quantity of 0.01 to 2.0 percent by weight.
Claim 14
Dependent Claim
13 words
Composition according to claim 10, further comprising at least one oxidizing hair dye.
Claim 15
Dependent Claim
25 words
Composition according to claim 13, wherein the oxidizing hair dye is selected from the group consisting of phenylenediamine, p-toluylene diamine, p-aminophenol, m-phenylenediamine, resorcin and m-aminophenol.
Claim 16
Dependent Claim
24 words
Composition according to claim 13, wherein the 2-amino-6-chloro-4-nitrophenol derivative of formula (I) is contained in a quantity of 0.01 to 4.0 percent by weight.
Claim 17
Dependent Claim
24 words
Composition according to claim 11, wherein the 2-amino-6-chloro-4-nitrophenol derivative of formula (I) is contained in a quantity of 0.01 to 2.0 percent by weight.
References Cited (Backward Citations)
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