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US5066767A
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Wholly aromatic polyesters comprising isophthalic acid, terephthalic acid, p-hydroxybenzoic acid, hydroquinone and an arylene diol
Assignee: Syensqo Specialty Polymers USA LLC
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Filing: 1989-12-18
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Granted: 1991-11-19
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Expires: 2009-12-18
Abstract
Abstract Wholly aromatic polyesters based on isophthalic acid, terephthalic acid, p-hydroxybenzoic acid, hydroquinone and an arylene diol, e.g. 4,4'-biphenol are described. The materials displayed are excellent overall combination of mechanical and thermal properties. Their melting points and heat distortion temperatures (264 psi) are at least about 260 DEG C. and 260 DEG C., respectively. These novel polymers can be melt-fabricated using standard injection molding, extrusion, and melt spinning techniques and yield fabricated articles with good surface characteristics.
Inventors
- 👤 Markus Matzner
- 👤 Richard Layton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 23:35
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/605; C08K; C08K7/00; C08K7/02
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
187 words
A wholly aromatic polyester comprising the units (1)-(5) ##STR8## wherein Ar is at least one member selected from a divalent substituted mononuclear aromatic radical of the formula ##STR9## wherein X is independently hydrogen, a C 1 to C 5 alkyl group, a halide atom or an aryl group; with the proviso that when the valence bonds are para to each other at least one group X must be other than hydrogen; a divalent dinuclear aromatic radical of the formula ##STR10## wherein X is as previously defined and Q is at least one member selected from the group consisting of a chemical bond O, S, SO, S--S, SO 2 , and CO; and a divalent naphthalene radical of the formula ##STR11## or isomers thereof and wherein a+b is approximately equal to d+e; the ratio of a to b being in the range of from about 1:4:1 to about 10:1; the ratio of d to e being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7, based on the total number of moles of a+b.
Claim 2
Dependent Claim
187 words
A wholly aromatic polyester comprising the units (1)-(5) ##STR8## wherein Ar is at least one member selected from a divalent substituted mononuclear aromatic radical of the formula ##STR9## wherein X is independently hydrogen, a C 1 to C 5 alkyl group, a halide atom or an aryl group; with the proviso that when the valence bonds are para to each other at least one group X must be other than hydrogen; a divalent dinuclear aromatic radical of the formula ##STR10## wherein X is as previously defined and Q is at least one member selected from the group consisting of a chemical bond O, S, SO, S--S, SO 2 , and CO; and a divalent naphthalene radical of the formula ##STR11## or isomers thereof and wherein a+b is approximately equal to d+e; the ratio of a to b being in the range of from about 1:4:1 to about 10:1; the ratio of d to e being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7, based on the total number of moles of a+b.
Claim 3
Dependent Claim
47 words
A wholly aromatic polyester as defined in claim 1 which has a melting point of at least about 260° C., a heat distortion temperature of at least about 200° C. when measured under a load of 264 psi, and which yields molded articles having good surface characteristics.
Claim 4
Dependent Claim
50 words
A process for preparing the polyester of claim 1 which comprises reacting terephthalic acid, isophthalic acid, p-hydroxybenzoic acid, hydroquinone, and an arylene diol with an anhydride of a lower monocarboxylic acid to form a prepolymer; followed by solid state advancement of said prepolymer to the desired high molecular weight polyester.
Claim 5
Dependent Claim
17 words
A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of biphenylene.
Claim 6
Dependent Claim
31 words
A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR12## wherein Y is methyl, chlorine, t-butyl or phenyl.
Claim 7
Dependent Claim
43 words
A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR13## wherein Q is either a chemical bond or is selected from O, S, SO, S--S, So 2 --, and CO.
Claim 8
Dependent Claim
23 words
A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR14##
Claim 9
Dependent Claim
75 words
A wholly aromatic polyester comprising the units (1), (2), (3), (4) and (6) ##STR15## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
Claim 10
Dependent Claim
75 words
A wholly aromatic polyester comprising the units (1), (2), (3), (4) and (6) ##STR15## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
Claim 11
Dependent Claim
77 words
A wholly aromatic polyester consisting essentially of the units (1), (2), (3), (4), and (6) ##STR16## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1: and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
Claim 12
Dependent Claim
77 words
A wholly aromatic polyester consisting essentially of the units (1), (2), (3), (4), and (6) ##STR16## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1: and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
Claim 13
Dependent Claim
85 words
A molding compound formed from the copolyester of claim 1 by incorporating therein one or more reinforcing agents or fillers selected from the group consisting of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wool cellulose fibers, calcium silicate, silica, clays, talc, mica, polytetrafluoroethylene, carbon black, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, wollastonite and titanium dioxide.
Claim 14
Dependent Claim
11 words
Cookware fabricated from the molding compound as defined in claim 10.
References Cited (Backward Citations)
DE3629211A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1994-11-18 | 1995-05-20 | 1995-11-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-11-18 | 1999-05-20 | 1999-11-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-11-18 | 2003-05-20 | 2003-11-19 | $7700.00 | Window Closed / Lapsed |